多元羧酸预处理制备木质纳米纤维素及其性能研究

doi:10.3969/j.issn.0253-2417.2022.06.002

Abstract

Abstract:

Three kinds of lignocellulosic nanofibrils(LCNF) were prepared from miscanthus straw fiber with the treatment using oxalic acid, maleic acid and citric acid under the condition of high-pressure homogenization. The performances of LCNF were characterized by cold field emission scanning electron microscope(FE-SEM), transmission scanning electron microscope(TEM), X-ray diffraction(XRD) analyzer and thermogravimetric(TG) analyzer. The results showed that polycarboxylic acid pretreatment effectively promoted fiber swelling and weaken the bonding force between fibrils, which was beneficial for the dissociation of microfibrils during the high-pressure homogenization process. The acidity became stronger and the fiber hydrolyzed in the pretreatment process was more intensive when the pKa value of carboxylic acid was smaller, resulting in more uniform size of LCNF. Oxalic acid had the minimum pKa value of 1.25 among there polycarboxylic acids, and the minimum average width of the corresponding prepared LCNF was approximately 15.3 nm. Compared with the raw material of miscanthus straw fiber, high-pressure homogenization could weaken the hydrogen bond occurring in microfibrils, which destroyed partial crystalline area and decreased the crystallinity of LCNF. The crystallinity of O-LCNF, M-LCNF and C-LCNF prepared from oxalic acid, maleic acid and citric acid system was 50.4%, 48.2% and 50.0%, respectively. Under the oxalic acid pretreatment system, the obtained(O-LCNF) exhibited the best thermal stability with the maximum weight loss rate temperature of 353.2 ℃.

Key words: lignocellulosic nanofibrils, polycarboxylic acid, pretreatment, property

CLC Number:

TQ352.6

Huiyang BIAN, Sheng DUAN, Jin WU, Liulian HUANG, Shuangquan YAO, Hongqi DAI. Preparation and Properties of Lignocellulosic Nanofibrils Obtained by Polycarboxylic Acid Pretreatments[J]. Chemistry and Industry of Forest Products, 2022, 42(6): 11-16.

Figures/Tables 6

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

References 18

1	JIANG J G, ZHU Y L, JIANG F. Sustainable isolation of nanocellulose from cellulose and lignocellulosic feedstocks: Recent progress and perspectives[J/OL]. Carbohydrate Polymers, 2021, 267: 118188[2021-11-05]. https://doi.org/10.1016/j.carbpol.2021.118188.
2	PIRICH C L , PICHETH G F , FONTES A M , et al. Disruptive enzyme-based strategies to isolate nanocelluloses: A review[J]. Cellulose, 2020, 27 (10): 5457- 5475. doi: 10.1007/s10570-020-03185-8
3	LIU K , DUN H S , ZHENG T , et al. Lignin-containing cellulose nanomaterials: Preparation and applications[J]. Green Chemistry, 2021, 23 (24): 9723- 9746. doi: 10.1039/D1GC02841C
4	SOLALA I , IGLESIAS M C , PERESIN M S . On the potential of lignin-containing cellulose nanofibrils(LCNFs): A review on properties and applications[J]. Cellulose, 2019, 27 (4): 1853- 1877.
5	ZHANG Q, MA R T, MA L S, et al. Contribution of lignin in esterified lignocellulose nanofibers(LCNFs) prepared by deep eutectic solvent treatment to the interface compatibility of LCNF/PLA composites[J/OL]. Industrial Crops and Products, 2021, 166: 113460[2021-11-05]. https://doi.org/10.1016/j.indcrop.2021.113460.
6	卞辉洋. 顺丁烯二酸预处理制备木质纳米纤维及其膜和水凝胶特性研究[D]. 南京: 南京林业大学, 2019.
	BIAN H Y. Preparation of lignocellulosic nanofibers using maleic acid pretreatment and their film and hydrogel properties[D]. Nanjing: Nanjing Forestry University, 2019.
7	CAI C , HIRTH K , GLEISNER R , et al. Maleic acid as a dicarboxylic acid hydrotrope for sustainable fractionation of wood at atmospheric pressure and ≤100 ℃: Mode and utility of lignin esterification[J]. Green Chemistry, 2020, 22 (5): 1605- 1617. doi: 10.1039/C9GC04267A
8	陈理恒. 基于酸处理的木质纤维酶水解及纳米纤维素特性的研究[D]. 广州: 华南理工大学, 2016.
	CHEN L H. Study on enzymatic hydrolysis of lignocellulose and characteristic of nanocellulose based on acid treatment[D]. Guangzhou: South China University of Technology, 2016.
9	JIA C , CHEN L H , SHAO Z Q , et al. Using a fully recyclable dicarboxylic acid for producing dispersible and thermally stable cellulose nanomaterials from different cellulosic sources[J]. Cellulose, 2017, 24 (6): 2483- 2498. doi: 10.1007/s10570-017-1277-y
10	XU W Y , GRÉNMAN H , LIU J , et al. Mild oxalic-acid-catalyzed hydrolysis as a novel approach to prepare cellulose nanocrystals[J]. ChemNanoMat, 2017, 3 (2): 109- 119. doi: 10.1002/cnma.201600347
11	SETA F T, AN X Y, LIU L Q, et al. Preparation and characterization of high yield cellulose nanocrystals(CNC) derived from ball mill pretreatment and maleic acid hydrolysis[J/OL]. Carbohydrate Polymers, 2020, 234: 115942[2021-11-06]. https://doi.org/10.1016/j.carbpol.2020.115942.
12	CHEN L H , ZHU J Y , BAEZ C , et al. Highly thermal-stable and functional cellulose nanocrystals and nanofibrils produced using fully recyclable organic acids[J]. Green Chemistry, 2016, 18 (13): 3835- 3843. doi: 10.1039/C6GC00687F
13	JI H , XIANG Z Y , QI H S , et al. Strategy towards one-step preparation of carboxylic cellulose nanocrystals and nanofibrils with high yield, carboxylation and highly stable dispersibility using innocuous citric acid[J]. Green Chemistry, 2019, 21 (8): 1956- 1964. doi: 10.1039/C8GC03493A
14	BIAN H Y , CHEN L H , DAI H Q , et al. Integrated production of lignin containing cellulose nanocrystals(LCNC) and nanofibrils(LCNF) using an easily recyclable di-carboxylic acid[J]. Carbohydrate Polymers, 2017, 167, 167- 176. doi: 10.1016/j.carbpol.2017.03.050
15	TIBOLLA H , PELISSARI F M , MENEGALLI F C . Cellulose nanofibers produced from banana peel by chemical and enzymatic treatment[J]. LWT-Food Science and Technology, 2014, 59 (2): 1311- 1318. doi: 10.1016/j.lwt.2014.04.011
16	WANG R B , CHEN L H , ZHU J Y , et al. Tailored and integrated production of carboxylated cellulose nanocrystals(CNC) with nanofibrils(CNF) through maleic acid hydrolysis[J]. ChemNanoMat, 2017, 3 (5): 328- 335. doi: 10.1002/cnma.201700015
17	马光瑞, 和铭, 杨桂花, 等. 低共熔溶剂体系预处理制备纤维素纳米纤丝及其性能研究[J]. 林产化学与工业, 2021, 41 (4): 69- 76.
	MA G R , HE M , YANG G H , et al. Preparation of cellulose nanofibril by the pretreatment with deep eutectic solvent system[J]. Chemistry and Industry of Forest Products, 2021, 41 (4): 69- 76.
18	YU H Y , ZHANG D Z , LU F F , et al. New approach for single-step extraction of carboxylated cellulose nanocrystals for their use as adsorbents and flocculants[J]. ACS Sustainable Chemistry & Engineering, 2016, 4 (5): 2632- 2643.

[1]	Tengfei MA, Yawei ZHAN, Yue LIU, Zhiqiang LI. Formaldehyde/Dioxane Pretreatment on Bamboo for Producing Monosaccharide and Lactic Acid [J]. Chemistry and Industry of Forest Products, 2022, 42(4): 101-106.
[2]	Fang WANG, Hongdan ZHANG. Application of Aspen Plus in Lignocellulosic Biomass Pretreatment for Ethanol Production: A Review [J]. Chemistry and Industry of Forest Products, 2022, 42(4): 119-130.
[3]	Yifei DU, Yue PU, Liping ZHANG, Qiang ZHAO, Xianliang SONG. Power Generation Performance of Lignin in Direct Biomass Fuel Cell [J]. Chemistry and Industry of Forest Products, 2022, 42(3): 75-82.
[4]	Xiaoyan YIN, Tingting CAI, Chao LIU, Jianchun JIANG, Kui WANG. Directional Decomposition of Bamboo Powder in Bio-based Polar Aprotic Solvent/Aqueous p-Toluenesulfonic Acid Coupling Systems [J]. Chemistry and Industry of Forest Products, 2022, 42(1): 1-9.
[5]	Yan WU, Zhongjian TIAN, Jiachuan CHEN, Fengshan ZHANG, Guigan FANG, Xingxiang JI. Hydrolysis Kinetics of Poplar During Thermal Hydrolysis [J]. Chemistry and Industry of Forest Products, 2022, 42(1): 21-28.
[6]	Shujie WANG, Xianfeng HOU, Yingshi HUANG, Xiaofeng CHEN, Jin SUN, Zhenzhong GAO. Effect of Alkaline Ionic Liquid TBAH Pretreatment on Structure and Enzymatic Properties of Eucalyptus [J]. Chemistry and Industry of Forest Products, 2022, 42(1): 57-63.
[7]	Xinxin YANG, Wei GUO, Zhaosheng CAI, Xujuan HUANG, Ting WANG, Zhengqing DING. Preparation and Properties of Glycidyl Dehydroabietate Grafted Hydroxypropyl Chitosan [J]. Chemistry and Industry of Forest Products, 2021, 41(6): 51-56.
[8]	Peiyao WEN, Jiaxin YOU, Yong XU, Junhua ZHANG. Co-production of Xylooligosaccharides and Bacillus subtilis from Poplar [J]. Chemistry and Industry of Forest Products, 2021, 41(5): 1-7.
[9]	Huiyang BIAN, Yanqiao FU, Lidong CHEN, Weisheng YANG, Shuangquan YAO, Hongqi DAI. Preparation and Characterization of Hydrophobic and Lipophilic Lignocellulosic Nanofibrils-based Aerogel [J]. Chemistry and Industry of Forest Products, 2021, 41(5): 45-50.
[10]	Guangrui MA, Ming HE, Guihua YANG, Weidong LI, Xingxiang JI, Jiachuan CHEN. Preparation of Cellulose Nanofibril by the Pretreatment with Deep Eutectic Solvent System [J]. Chemistry and Industry of Forest Products, 2021, 41(4): 69-76.
[11]	Hui ZHANG, Dakun LIU, Yanling GUO, Jian LI. Forming Properties of Boxwood/Thermoplastic Polyurethane Fabricated by Selective Laser Sintering [J]. Chemistry and Industry of Forest Products, 2021, 41(2): 17-23.
[12]	Shan XU, Shanqi WAN, Shufang WU, Chaoguang YU, Yunlong YIN. Wood and Fiber Properties, and Pulping Performance of Four Taxodium Hybrid 'Zhongshanshan' [J]. Chemistry and Industry of Forest Products, 2021, 41(2): 93-102.
[13]	Tingzhou LEI, Xiaofei XIN, Zaifeng LI, Jinping LI, Liya ZHANG. A Review of Torrefaction Pretreatment for Preparation Biomass Clean Briquette Fuels [J]. Chemistry and Industry of Forest Products, 2021, 41(2): 110-118.
[14]	Wenwen ZHANG, Kun LI, Baoshan TANG, Pinde ZHANG, Yiwen LIU, Hong ZHANG. Effect of Post-harvest Treatment on the Product Quality of Chinese Gallnut [J]. Chemistry and Industry of Forest Products, 2021, 41(1): 29-37.
[15]	Yunni ZHAN, Chen HUANG, Xin HAO, Zimeng WANG, Yongjun DENG, Guigan FANG. Preparation of Xylooligosaccharides and Monosaccharides from Bamboo Chips by Liquid Hot Water Pretreatment [J]. Chemistry and Industry of Forest Products, 2021, 41(1): 77-84.

Preparation and Properties of Lignocellulosic Nanofibrils Obtained by Polycarboxylic Acid Pretreatments

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 6

References 18

Related Articles 15

Recommended Articles

Metrics

Comments