5-羟甲基糠醛催化氢化制备2, 5-二羟甲基呋喃

doi:10.3969/j.issn.0253-2417.2022.06.004

Abstract

Abstract:

The catalytic hydrogenation of 5-hydroxymethylfurfural(HMF) for preparation of 2, 5-bishydroxymethylfuran(BHMF) was studied, using ethanol as hydrogen donor and solvent, and copper and zinc nanoparticles(Cu-Zn/CBD) supported by carbonized sugarcane bagasse(CBD) was used as catalyst. The effects of reaction parameters such as catalyst metal proportion, reaction temperature and reaction time on the reaction of HMF hydrogenation were investigated. The surface morphology and structure of the catalyst were characterized by XRD, SEM and TEM. The elemental valence and content of the catalyst were analyzed by XPS and ICP-OES, and mixture after reaction was analyzed by HPLC. The results showed that the bimetallic Cu-Zn/CBD catalyst exhibited higher catalytic activity than those of single metal catalyst Cu/CBD and Zn/CBD. Under the optimal conditions of the Cu/Zn mass ratio of 2∶1, the reaction temperature of 160 ℃, and the reaction time of 1.5 h, the conversion rate of HMF was 86.5%, and the yield of BHMF was 82.5%. The reusability of catalysts was excellent. After recycling for 5 times, owing to the loss of a small amount of Cu and Zn nanoparticles, the conversion rate HMF and yield of BHMF decreased to 77.3% and 76.8%, respectively.

Key words: HMF, BHMF, hydrogen donor, Cu-Zn/CBD

CLC Number:

TQ35

Tian GAN, Kaili ZHANG, Ke YE, Ying LIU, Shubin WU, Junping ZHUANG. Catalytic Hydrogenation of 5-Hydroxymethyl-furfural into 2, 5-Bishydroxymethylfuran[J]. Chemistry and Industry of Forest Products, 2022, 42(6): 24-30.

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References 25

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样品¹⁾ samples	质量分数mass fraction/%							S_BET/(m²·g^-1)
样品¹⁾ samples	C	H	O	N	S	Cu	Zn	S_BET/(m²·g^-1)
蔗渣bagasse	38.60	6.47	54.49	0.40	0.04	—	—	9.65
CBD	67.25	3.27	28.68	0.78	0.02	—	—	11.30
Cu-Zn/CBD-0	65.92	3.27	25.87	0.84	0.02	2.52	1.56	10.90
Cu-Zn/CBD-5	65.11	3.15	27.23	0.85	0.02	2.35	1.29	9.78

编号 No.	催化剂 catalyst	HMF转化率/% HMF conversion	BHMF产率/% BHMF yield
1	CBD	—	—
2	Cu/CBD	70.6	36.2
3	Zn/CBD	21.0	—
4	Cu-Zn(1∶1)/CBD	79.1	63.7
5	Cu-Zn(2∶1)/CBD	89.0	83.0
6	Cu-Zn(1∶2)/CBD	16.9	—

使用次数 using number	HMF转化率/% HMF conversion	BHMF产率/% BHMF yield
1	86.5	82.5
2	84.0	81.9
3	83.8	81.7
4	82.1	81.6
5	77.3	76.8

[1]	Bo CHEN,Bo LIU,Zhangming SHI. Theoretical Study on Pyrolysis Behavior of 5-HMF [J]. Chemistry and Industry of Forest Products, 2020, 40(5): 27-33.
[2]	LU Qiang, GUO Haoqiang, YE Xiaoning, WANG Xin, ZHOU Mingxing. Research Progress of Hydrogen Donor Assisted Fast Pyrolysis of Biomass [J]. Chemistry and Industry of Forest Products, 2017, 37(6): 1-9.
[3]	HU Lei, WU Zhen, XU Jia-xing, SUN Yong, LIN Lu, XU Ning, DAI Ben-lin. Advances in Selective Hydrogenation of 5-Hydroxymethylfurfural into 2,5-Dimethylfuran [J]. Chemistry and Industry of Forest Products, 2015, 35(3): 133-138.

Catalytic Hydrogenation of 5-Hydroxymethyl-furfural into 2, 5-Bishydroxymethylfuran

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