生物质催化转化制备生物基航空燃料的研究进展

doi:10.3969/j.issn.0253-2417.2023.01.018

Abstract

Abstract:

Catalytic conversion of biomass was the main route to produce high quality bio-based aviation fuel and solve energy crisis. In this paper, according to the perspective of the existing preparation methods of bio-aviation fuel, the technical routes and catalytic systems required by different feedstocks and the catalysts used in different technical routes were summarized from the perspective of raw materials adapted to the demand(oil, lignocellulose biomass and sugar raw materials) and technical routes(hydrodeoxygenation, Fischer-Tropsch synthesis, aldol condensation and olefin oligomerization). At the same time, the reaction conditions and reaction mechanism were also reported. It was pointed out that the critical problems in catalytic conversion process, including higher cost, complex process and conversion mechanism(high temperature and high pressure), higher H₂ consumption, poor selectivity of desired target products and deactivation of catalyst. Finally, according to the advantages and disadvantages of various raw materials and technical routes as well as the problems faced, some suggestions were proposed and the future development direction was prospected.

Key words: biomass, bio-aviation fuel, hydrodeoxygenation, catalysts, catalytic mechanism

CLC Number:

TQ35

Yunwu ZHENG, Jida WANG, Donghua LI, Can LIU, Zhangshuai DING, Zhifeng ZHENG. A Review on Recent Advances in Catalytic Conversion of Biomass for Selective Production of Bio-aviation Fuels[J]. Chemistry and Industry of Forest Products, 2023, 43(1): 140-154.

Figures/Tables 6

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性能指标 properties index	化石基 fossil-based			生物基 bio-based
性能指标 properties index	Jet A	JP-8	RP-3	FT-SPK	HEFA-SPK	ATJ
烷烃 alkane/%	68.2	60.0	53.0	98.74	88.95	99.62
环烷烃 cycloalkanes/%	6.3	20.0	37.7	0.62	11.05	0.05
芳香烃 aromatic hydrocarbon/%	25.5	18.0	4.6	0.64	0	＜0.01
烯烃 olefin/%	—	2.0	2.0	—	—
其他烃类 other hydrocarbons/%	—	—	2.7	0.5	0.5	—
自燃温度 autoignition temperature/℃	＞425	—	380-425	—	—
闪点 flash point/℃	48	42	47	42	43	50
沸点 boiling point/℃	—	—	185	—	—
凝固点 freezing point/℃	-40	-48.5	-60	40	40	—
烟点 smoke point/mm	22.0	28.5	24.6	38.0	50.0	34.5
15 ℃下密度 density at 15 ℃/(kg·m^-3)	803	780	790	761	751	760
-20 ℃下的黏度 viscosity at -20 ℃/(mm²·s^-1)	4.5	3.5	1.814	3.4	3.3	5.0
热值 calorific value/(MJ·kg^-1)	43.0	43.1	43.2	43.9	44.3	43.88
理想空燃比 ideal air-fuel ratio	—	—	16	—	—
十六烷值 cetane number	48.3	48.8	43.0	31.3	53.9	17.1

原料 raw material	温度/℃ temp.	催化剂 catalyst	主要产物¹⁾ product composition	转化率/% conversion ratio	产率/% yield	文献 ref.
大豆油 soybean oil	390	Ni-Mo/HY	烷烃和芳烃 alkanes and aromatics	95	48.2	[17]
麻风树油 jatropha oil	300	W-Pt/TiO₂	C₁₅，C₁₇ AH	86	86.0	[18]
棕榈油 palm oil	330	Ni-MoS₂/γ-Al₂O₃	C₁₀-C₁₂ AH	＞95	92.0	[19]
椰子油 coconut oil	350	Mo-Ni/γ-Al₂O₃	C₁₁-C₁₂ AH	97	94.0	[20]
蓖麻油 castor oil	360	NiAg/SAPO-11	C₈-C₁₅ AH	98	91.6	[21]
微藻油 microalgae oil	330	Pt-Re/SiO₂-Al₂O₃	C₁₀-C₂₀ AH	100	—	[22]
海藻油 algal oil	400	NiO-CoO-MoO	烷烃和烯烃 alkanes and aromatics	＞99	100	[14]
废旧油脂 waste oil	400	Ni/Meso-Y	C₁₅，C₁₇ AH	89.6	51.8	[23]
废食用油 waste cooking oil	300	Ni₂P/AC	C₁₅-C₁₉ AH	—	77.4	[24]
硬脂酸 stearic acid	325	Pd/HZSM-5	C₅-C₁₂碳氢化合物 hydrocarbon	100	—	[25]
油酸 oleic acid	330	NiMo/γ-Al₂O₃	C₈-C₁₈烷烃和烯烃 alkanes and aromatics	71.0	—	[26]

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A Review on Recent Advances in Catalytic Conversion of Biomass for Selective Production of Bio-aviation Fuels

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