木质素样品的羟值测定方法

›› 2012, Vol. 32 ›› Issue (3): 51-55.

• 研究报告 • Previous Articles Next Articles

The Improvement in the Determination Method of Hydroxyl Value for Lignin

SUN Ge-liang¹, WAN Ping-yu¹, ZHAO Lei¹, CHEN Yong-mei¹, LI Gai-yun², QIN Te-fu²

1. College of Science, Beijing University of Chemical Technology, Beijing 100029, China;2. Research Institute of Wood Industry, Chinese Academy of Forestry, Beijing 100091, China

Received:2011-06-27 Revised:1900-01-01 Online:2012-06-30 Published:2012-06-30

Abstract

Abstract: Hydroxyl value of lignin was determined by the phthalic anhydride-pyridine method which is the standard method for determination of hydroxyl value for polyether glycol. The accuracy of hydroxyl value via acid value and base value measurement was improved, while this novel method employed for sodium ligninsulfonate and enzymatic hydrolysis lignin from cornstalks. Replacing pyridine with ethanol as solvent and HCl with potassium hydrogen phthalate for measuring base value, enhanced the accuracy and precision of the measured results. The deviation of base value is less 1%. In addition, the cost of determination decreased, compared with the traditional method.

Key words: lignin, hydroxyl value, acid value, base value

CLC Number:

TQ351
O652.3

SUN Ge-liang;WAN Ping-yu;ZHAO Lei;CHEN Yong-mei;LI Gai-yun;QIN Te-fu. The Improvement in the Determination Method of Hydroxyl Value for Lignin[J]. , 2012, 32(3): 51-55.

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The Improvement in the Determination Method of Hydroxyl Value for Lignin

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