高效桐油催干剂的制备及其催干性能研究

doi:10.3969/j.issn.0253-2417.2019.03.014

Abstract

Abstract:

The effects of four kinds of driers, namely rare earth isooctanoate(REI), cobalt isooctanoate(CI), high-efficient drier M2203 and CQ-150B alone or in combination on the drying performance of tung oil and polymerized tung oil were investigated. The experimental results showed that the viscosity of polymerized tung oil at 10℃ was 15 520 mPa·s and higher than that of tung oil(160 mPa·s). The drying time of polymerized tung oil at 20℃ was 72 h and shorter than that of tung oil(168 h). When 0.6% of REI was used together with 0.010% of CI, the surface drying time and hard drying time of raw tung oil were 2 and 2.5 h, respectively, the hardness grade was 4 H, and the adhesion grade was 1; the surface drying time and hard drying time of polymerized tung oil were 0.67 and 1 h, hardness grade was 5 H, adhesion was grade 1. Compared with the high-efficient drier M2203 and CQ-150B drier, the composite drier had light color and good compatibility with tung oil. FI-IR and TGA analysis showed that the tung oil paint film prepared by drying with compound drier had high cross-linking degree and good heat stability. So the compound drier was proved to be an excellent tung oil drier.

Key words: tung oil, rare earth isooctanoate, cobalt isooctanoate, curing

CLC Number:

TQ35

Yun YU,Ningning YANG,Bin HUANG,Yan YANG,Youwei LIAO. Preparation of High-efficient Tung Oil Drier and Its Drying Performance[J]. Chemistry and Industry of Forest Products, 2019, 39(3): 101-107.

Figures/Tables 9

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References 16

1	LU YS , LAROCK R C . Novel polymeric materials from vegetable oils and vinyl monomers:Preparation, properties, and applications[J]. Chemsuschem, 2009, 2 (2): 136- 147. doi: 10.1002/cssc.v2:2
2	GÜNER F S , YAĞCI Y , ERCIYES A T . Polymers from triglyceride oils[J]. Progress in Polymer Science, 2006, 31 (7): 633- 670. doi: 10.1016/j.progpolymsci.2006.07.001
3	ALAM M , AKRAM D , SHARMIN E , et al. Vegetable oil based eco-friendly coating materials:A review article[J]. Arabian Journal of Chemistry, 2014, 7 (4): 469- 479. doi: 10.1016/j.arabjc.2013.12.023
4	李鹏, 马松琪, 焦纬洲, 等. 植物油基紫外光固化涂料研究进展[J]. 涂料工业, 2016, 46 (5): 81- 87.
	LI P , MA S Q , JIAO W Z , et al. Research progress in vegetable oil-based UV curable coatings[J]. Paint & Coatings Industry, 2016, 46 (5): 81- 87.
5	何鑫, 吴桂英, 闫云君. 植物油基平台化合物及高分子材料研究进展[J]. 生物工程学报, 2017, 33 (5): 701- 719.
	HE X , WU G Y , YAN Y J . Advances in platform compounds and polymers from vegetable oils[J]. Chinese Journal of Biotechnology, 2017, 33 (5): 701- 719.
6	郑敏睿, 张猛, 胡立红, 等. 磷钨酸季铵盐催化制备环氧化桐油甲酯及其性能研究[J]. 林产化学与工业, 2017, 37 (3): 61- 66. doi: 10.3969/j.issn.0253-2417.2017.03.008
	ZENG M R , ZHANG M , HU L H , et al. Synthesis and properties of epoxidized tung oil methyl ester from tung oil methyl ester with quaternary ammonium phosphotungstate as catalyst[J]. Chemistry and Industry of Forest Products, 2017, 37 (3): 61- 66. doi: 10.3969/j.issn.0253-2417.2017.03.008
7	SAMADZADEH M , BOURA S H , PEIKARI M , et al. Tung oil:An autonomous repairing agent for self-healing epoxy coatings[J]. Progress in Organic Coatings, 2011, 70 (4): 383- 387. doi: 10.1016/j.porgcoat.2010.08.017
8	YANG X H , ZHANG S X , LI W Y . The performance of biodegradable tung oil coatings[J]. Progress in Organic Coatings, 2015, 85 (8): 216- 220.
9	黄丽, 刘石彩, 杨华. 水蒸气活化法制备松子壳活性炭的研究[J]. 中南林业科技大学学报, 2017, 37 (3): 111- 115.
	HUANG L , LIU S C , YANG H . Preparation and activated carbon from pine nut shells by steam activation[J]. Journal of Central South University of Forestry & Technology, 2017, 37 (3): 111- 115.
10	谭湘璐.桐油在水性光固化树脂和水性聚氨酯树脂的应用研究[D].长沙:湖南大学, 2016.
	TAN X L, Study on application of tung oil in waterborne photocurable resin and waterborne polyurethane resin[D]. Changsha: Hunan University, 2016.
11	丁奋.水性醇酸树脂用催干剂的制备与性能研究[D].上海:华东理工大学, 2014.
	DING F. Preparation and properties of water-based alkyd resin drier[D]. Shanghai: East China University of Science and Technology, 2014.
12	袁学会, 刘方方. 过氧化甲乙酮/异辛酸钴引发固化UPR的研究[J]. 热固性树脂, 2014, 29 (5): 43- 45.
	YUAN X H , LIU F F . Research on the curing UPR with methyl ethyl ketone peroxide/cobalt iso-octoate initiator[J]. Thermosetting Resin, 2014, 39 (5): 43- 45.
13	GUO L P , ZHU X C , ZHANG G C , et al. Synthesis and characterization of organo-rare-earth metal monoalkyl complexes supported by carbon σ-bonded indolyl ligands:High specific isoprene 1, 4-cis polymerization catalysts[J]. Inorganic Chemistry, 2015, 54 (12): 5725- 5731. doi: 10.1021/acs.inorgchem.5b00308
14	RUSSBUELDT B M E , HOELDERICH W F . New rare earth oxide catalysts for the transesterification of triglycerides with methanol resulting in biodiesel and pure glycerol[J]. Journal of Catalysis, 2010, 271 (2): 290- 304. doi: 10.1016/j.jcat.2010.02.005
15	耿曼璐, 赵贝贝, 兰韬, 等. 食用油甘油三酯及其氧化聚合物分析方法研究进展[J]. 中国油脂, 2017, 42 (1): 134- 138. doi: 10.3969/j.issn.1003-7969.2017.01.032
	GEN M L , ZHAO B B , LAN T , et al. Advance in analysis methods for triacylglycerols and its oxidized polymers in edible oil[J]. China Oils and Fats, 2017, 42 (1): 134- 138. doi: 10.3969/j.issn.1003-7969.2017.01.032
16	万长鑫.天然生漆改性及其导静电性能的研究[D].长沙:中南林业科技大学, 2016.
	WAN C X. Study on modification of natural raw paint and its electrostatic conductivity[D]. Changsha: Central South University of Forestry & Technology, 2016.

用量/% dosage	桐油tung oil				聚合桐油polymerized tung oil
用量/% dosage	表干时间/h surface drying time	实干时间/h hard drying time	硬度 hardness	附着力 adhesion	表干时间/h surface drying time	实干时间/h hard drying time	硬度 hardness	附着力 adhesion
0.1	7.50	8.00	4H	1	4.33	4.67	4H	1
0.2	7.00	7.50	5H	1	4.00	4.33	5H	1
0.3	5.00	5.16	4H	1	3.83	4.00	4H	1
0.4	5.00	5.16	4H	1	3.67	4.00	4H	1
0.5	4.33	4.58	4H	1	3.67	4.00	4H	1
0.6	4.25	4.50	3H	1	3.50	4.00	4H	1

用量/% dosage	桐油tung oil				聚合桐油polymerized tung oil
用量/% dosage	表干时间/h surface drying time	实干时间/h hard drying time	硬度 hardness	附着力 adhesion	表干时间/h surface drying time	实干时间/h hard drying time	硬度 hardness	附着力 adhesion
0.02	5.00	6.0	4H	1	4.00	4.5	4H	1
0.03	5.00	5.5	4H	1	2.50	3.0	4H	1
0.04	4.50	5.0	3H	1	1.83	2.0	4H	1
0.05	4.50	5.0	3H	1	0.83	1.0	3H	1
0.06	4.50	5.0	3H	1	0.83	1.0	3H	1
0.07	3.83	4.5	3H	1	0.83	1.0	3H	1

用量/% dosage	桐油tung oil				聚合桐油polymerized tung oil
用量/% dosage	表干时间/h surface drying time	实干时间/h hard drying time	硬度 hardness	附着力 adhesion	表干时间/h surface drying time	实干时间/h hard drying time	硬度 hardness	附着力 adhesion
0.4	1.5	2.00	5H	1	1.00	1.33	4H	1
0.5	1.0	1.67	4H	1	0.83	1.17	5H	1
0.6	1.0	1.67	4H	1	0.67	0.83	4H	1
0.7	1.0	1.50	4H	1	0.67	0.83	4H	1
0.8	1.0	1.50	4H	1	0.67	0.83	3H	1
0.9	1.0	1.50	4H	1	0.50	0.67	3H	1
1.0	1.0	1.33	3H	1	0.50	0.67	3H	2
1.1	1.0	1.33	4H	1	0.50	0.67	3H	2

用量/% dosage	桐油tung oil				聚合桐油polymerized tung oil
用量/% dosage	表干时间/h surface drying time	实干时间/h hard drying time	硬度 hardness	附着力 adhesion	表干时间/h surface drying time	实干时间/h hard drying time	硬度 hardness	附着力 adhesion
0.3	1.00	1.33	4H	1	0.50	0.67	5H	1
0.4	0.83	1.00	3H	1	0.33	0.58	5H	1
0.5	0.67	0.83	4H	1	0.25	0.50	4H	1
0.6	0.58	0.83	4H	1	0.17	0.42	4H	1
0.7	0.50	0.67	2H	1	0.17	0.33	4H	1
0.8	0.50	0.67	2H	1	0.17	0.33	4H	1

催干剂drier		桐油tung oil				聚合桐油polymerized tung oil
异辛酸稀土 REI	异辛酸钴 CI	表干时间/h surface drying time	实干时间/h hard drying time	硬度 hardness	附着力 adhesion	表干时间/h surface drying time	实干时间/h hard drying time	硬度 hardness	附着力 adhesion
0.6%	0.000%	4.25	4.5	3H	1	3.50	4.00	4H	1
0.6%	0.002%	2.50	3.0	4H	1	1.33	1.50	5H	1
0.6%	0.004%	2.30	3.0	5H	1	1.17	1.50	6H	1
0.6%	0.006%	2.30	3.0	4H	1	0.67	1.17	5H	1
0.6%	0.008%	2.17	2.5	5H	1	0.67	1.17	5H	1
0.6%	0.010%	2.00	2.5	4H	1	0.67	1.00	5H	1
0.6%	0.012%	2.00	2.5	4H	1	0.50	1.00	5H	1
0.6%	0.014%	2.00	2.5	4H	1	0.50	0.83	5H	1

Preparation of High-efficient Tung Oil Drier and Its Drying Performance

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