Chemistry and Industry of Forest Products ›› 2019, Vol. 39 ›› Issue (4): 56-64.doi: 10.3969/j.issn.0253-2417.2019.04.008
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Shaoji WU(),Kun JIANG,Yueyuan YE,Yunquan LIU*(),Duo WANG,Shuirong LI
Received:
2019-02-26
Online:
2019-08-25
Published:
2019-08-23
Contact:
Yunquan LIU
E-mail:wushaojixmu@163.com;yq_liu@xmu.edu.cn
Supported by:
CLC Number:
Shaoji WU,Kun JIANG,Yueyuan YE,Yunquan LIU,Duo WANG,Shuirong LI. Preparation of Activated Carbon from Co-pyrolysis Char of Sewage Sludge and Poplar Sawdust and Its Application in Wastewater Treatment[J]. Chemistry and Industry of Forest Products, 2019, 39(4): 56-64.
Table 1
Proximate and ultimate analysis for feedstocks"
样品 samples | 工业分析industrial analysis/% | 元素分析elemental analysis/% | 低位热值/(MJ·kg-1) low heat value | ||||||||
水分 moisture | 灰分 ash | 挥发分 volatile | 固定碳 fixed carbon | C | H | N | S | O | |||
污泥sewage sludge | 3.8 | 56.3 | 36.5 | 3.4 | 20.8 | 3.4 | 1.8 | 1.7 | 16.0 | 8.6 | |
杨木屑poplar sawdust | 6.5 | 0.5 | 81.1 | 11.9 | 49.9 | 5.6 | 0.1 | 0.1 | 43.8 | 19.2 |
Table 2
Textural parameters of co-pyrolysis char before and after activation"
样品 samples | SBET/ (m2·g-1) | 微孔比表面积/(m2·g-1) micropore specific surface area | 总孔容积/(cm3·g-1) total pore volume | 微孔容积/(cm3·g-1) micropore volume | 平均孔径/ nm average pore size |
共热解焦co-pyrolysis char | 70.5 | 7.5 | 0.124 | 0.003 | 15.0 |
活性炭activated carbon | 551.0 | 383.8 | 0.294 | 0.169 | 2.7 |
1 |
KOULOUMBIS P , RIGAS F , MAVRIDOU A . Environmental problems from the disposal of sewage sludge in Greece[J]. International Journal of Environmental Health Research, 2000, 10 (1): 77- 83.
doi: 10.1080/09603120073027 |
2 | DENG S H , TAN H Z , WANG X B , et al. Investigation on the fast co-pyrolysis of sewage sludge with biomass and the combustion reactivity of residual char[J]. Bioresource Technology, 2017, 239 (3): 302- 310. |
3 | DING H S , JIANG H . Self-heating co-pyrolysis of excessive activated sludge with waste biomass:Energy balance and sludge reduction[J]. Bioresource Technology, 2013, 133 (1): 16- 22. |
4 |
ROZADA F , OTERO M , MORÁNA , et al. Adsorption of heavy metals onto sewage sludge-derived materials[J]. Bioresource Technology, 2008, 99 (14): 6332- 6338.
doi: 10.1016/j.biortech.2007.12.015 |
5 | 邓皓, 王蓉沙, 张明栋, 等. 含油污泥制备高比表面积活性炭[J]. 山东大学学报(工学版), 2014, 44 (2): 69- 75. |
DENG H , WANG R S , ZHANG M D , et al. Preparation of activated carbon with high specific surface area using oily sludge[J]. Journal of Shandong University(Engineering Science), 2014, 44 (2): 69- 75. | |
6 | 闫中亚, 王俊芬, 吴玉英, 等. KOH活化脱墨污泥基活性炭的制备及表征[J]. 中国造纸学报, 2016, 31 (1): 32- 36. |
YAN Z Y , WANG J F , WU Y Y , et al. Preparation and characterization of activated carbon from deinking sludge activated by potassium hydroxide[J]. Transactions of China Pulp and Paper, 2016, 31 (1): 32- 36. | |
7 | 陈佼, 张建强, 陆一新, 等. 玉米芯生物炭对含盐污水中氨氮的吸附特性[J]. 安全与环境学报, 2017, 17 (3): 1088- 1093. |
CHEN J , ZHANG J Q , LU Y X , et al. Study on the adsorption feature of ammonium nitrogen in the salt-laden sewage by the corn cob biochar[J]. Journal of Safety and Environment, 2017, 17 (3): 1088- 1093. | |
8 | 彭小明.介孔碳材料制备及对两类典型有机污染物的吸附性能研究[D].南京:东南大学, 2015. |
PENG X M.The preparation of ordered mesoporous carbon materials and studies of adsorption properties for two typical organic pollutants[D]. Nanjing: Southeast University, 2015. | |
9 | OTOWA T , TANIBATA R , ITOH M . Production and adsorption characteristics of MAXSORB:High-surface-area active carbon[J]. Gas Separation & Purification, 1993, 7 (4): 241- 245. |
10 |
FU Y H , SHEN Y F , ZHANG Z D , et al. Activated bio-chars derived from rice husk via one-and two-step KOH-catalyzed pyrolysis for phenol adsorption[J]. Science of the Total Environment, 2019, 646, 1567- 1577.
doi: 10.1016/j.scitotenv.2018.07.423 |
11 | KONG L , ZHU Y , LIU M , et al. Conversion of Fe-rich waste sludge into nano-flake Fe-SC hybrid Fenton-like catalyst for degradation of AOⅡ[J]. Environmental Pollution, 2016, 216 (2): 568- 574. |
12 | DENG L , XU G , YAN Z , et al. Removal effect of Cr(Ⅵ)by adsorbent made from sewage sludge[J]. Water Science & Technology, 2010, 62 (12): 2961- 2969. |
13 | 谷麟, 杨文昊, 崔建军, 等. 尿素活化污泥制备生物质活性炭的研究[J]. 现代化工, 2018, 38 (9): 124- 127. |
GU L , YANG W H , CUI J J , et al. Synthesis of biomass-based activated carbon from urea activated sludge[J]. Modern Chemical Industry, 2018, 38 (9): 124- 127. | |
14 | SHAN D , DENG S , ZHAO T , et al. Preparation of ultrafine magnetic biochar and activated carbon for pharmaceutical adsorption and subsequent degradation by ball milling[J]. Journal of Hazardous Materials, 2016, 305 (2): 156- 163. |
15 | 李露霏, 虞宇翔, 常建民. 成型生物质快速热解炭制备活性炭活化工艺研究及其性能表征[J]. 化工新型材料, 2018, 46 (3): 239- 243. |
LI L F , YU Y X , CHANG J M . Activation process and characterization of activated carbon derived from fast pyrolytic char[J]. New Chemical Materials, 2018, 46 (3): 239- 243. | |
16 |
房平, 邵瑞华, 任娟. 活性炭对苯酚的吸附研究[J]. 炭素技术, 2011, 30 (2): 12- 16.
doi: 10.3969/j.issn.1001-3741.2011.02.004 |
FANG P , SHAO R H , REN J . Adsorption of phenol on activated carbon[J]. Carbon Techniques, 2011, 30 (2): 12- 16.
doi: 10.3969/j.issn.1001-3741.2011.02.004 |
|
17 | GHAZY M , HARBY K , ASKALANY A , et al. Adsorption isotherms and kinetics of activated carbon/difluoroethane adsorption pair:Theory and experiments[J]. International Journal of Refrigeration, 2016, 70 (2): 196- 205. |
18 | YU F , YA S , ZHEN Z , et al. Activated bio-chars derived from rice husk via one-and two-step KOH-catalyzed pyrolysis for phenol adsorption[J]. Science of The Total Environment, 2019, 646 (5): 1567- 1577. |
19 |
KUO C , WU C , WU J , et al. Adsorption of direct dyes from aqueous solutions by carbon nanotubes:Determination of equilibrium, kinetics and thermodynamics parameters[J]. Journal of Colloid and Interface Science, 2008, 327 (2): 308- 315.
doi: 10.1016/j.jcis.2008.08.038 |
20 | 杨晓霞, 陈浩敏, 高晓明, 等. 活性炭吸附对硝基苯酚的动力学和热力学研究[J]. 离子交换与吸附, 2018, 34 (3): 59- 70. |
YANG X X , CHEN H M , GAO X M , et al. Adsorption kinetics and thermodynamics of p-nitrophenol on activation carbon[J]. Ion Exchange and Adsorption, 2018, 34 (3): 59- 70. | |
21 | GOKCE Y , AKTAS Z . Nitric acid modification of activated carbon produced from waste tea and adsorption of methylene blue and phenol[J]. Applied Surface Science, 2014, 313 (10): 352- 359. |
22 | MAJA T , NIKOLA B , ALEKSANDAR S , et al. Surface functionalised adsorbent for emerging pharmaceutical removal:Adsorption performance and mechanisms[J]. Process Safety and Environmental Protection, 2019, 125 (3): 50- 63. |
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