肉桂叶精油/β-环糊精微胶囊的制备及缓释特性

doi:10.3969/j.issn.0253-2417.2021.04.006

Abstract

Abstract:

In order to further broaden the application of Cinnamomum cassia leaves essential oil in food, feed and other fields, C. cassia leaves essential oil/β-cyclodextrin microcapsules were prepared by co-precipitation method with β-cyclodextrin as the wall material and C. cassia essential oil as the core material. The preparation conditions of microcapsules were optimized by orthogonal experimental design. Essential oil/β-cyclodextrin microcapsules were characterized by using gas chromatography-mass spectrometry(GC-MS) and Fourier transform infrared spectroscopy(FT-IR).The results showed that the suitable preparation conditions of microcapsules were wall-core ratio 6:1, temperature 50℃, time 4 h and stirring speed 1 000 r/min. The encapsulation efficiency of C. cassia essential oil of the obtained microcapsule was 74.17%. The GC-MS analysis showed that the main compositions of C. cassia essential oil were trans-cinnamaldehyde(81.39%), followed by o-methoxycinnamaldehyde(7.61%) and the main compositions of C. cassia essential oil in the microcapsule were also trans-cinnamaldehyde(78.68%) and o-methoxycinnamaldehyde(9.34%). FT-IR analysis showed that C. cassia leaves essential oil and β-cyclodextrin formed good inclusion complex. C. cassia leaves essential oil/β-cyclodextrin microcapsules had good thermal stability and slow-release properties.

Key words: Cinnamomum cassia leaves, essential oil, β-cyclodextrin, microcapsules, slow-release

CLC Number:

TQ35

Guoliang LI, Xiangping LIU. Preparation and Slow-release Properties of Cinnamomum cassia Leaves Essential Oil/β-Cyclodextrin Microcapsules[J]. Chemistry and Industry of Forest Products, 2021, 41(4): 35-41.

Figures/Tables 6

Table 1

Fig.1

Table 2

Table 3

Fig.2

Fig.3

References 21

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序号 No.	保留时间/min retention time	化合物 compound	相对峰面积/% relative peak area
1	3.237	水芹烯phellandrene	0.05
2	6.495	α-蒎烯α-pinene	0.08
3	8.041	莰烯camphene	0.05
4	8.585	苯甲醛benzaldehyde	0.01
5	9.021	β-蒎烯β-pinene	0.32
6	11.452	D-柠檬烯D-limonene	0.00
7	12.025	邻羟基苯甲醛o-hydroxybenzaldehyde	0.01
8	14.645	苯乙醇phenethyl alcohol	0.19
9	16.190	苯丙醛benzenepropanal	0.27
10	18.037	顺式肉桂醛cis-cinnamaldehyde	0.50
11	18.738	邻甲氧基苯甲醛o-anisaldehyde	0.88
12	19.659	反式肉桂醛trans-cinnamaldehyde	81.39
13	22.566	邻甲氧基苯丙酮o-methoxyphenylacetone	0.24
14	22.678	α-古巴烯α-copaene	0.59
15	24.522	α-荜澄茄油烯α-cubebene	0.46
16	24.895	石竹烯caryophyllene	0.21
17	25.422	乙酸肉桂酯cinnamyl acetate	0.15
18	25.400	香豆素coumarin	0.13
19	26.009	α-依兰油烯α-muurolene	0.12
20	26.583	β-没药烯β-bisabolene	0.09
21	26.623	β-杜松烯β-cadinene	0.29
22	26.793	邻甲氧基肉桂醛o-methoxycinnamaldehyde	7.61
23	39.192	反式-橙花叔醇trans-nerolidol	0.58
24	43.993	桉油烯醇espatulenol	0.91
25	51.099	氧化石竹烯caryophyllene oxide	0.90
26	54.376	苯甲酸苄酯benzyl benzoate	0.50
合计total			96.52

序号 No.	A 壁芯比 wall-core ratio	B 包埋温度/℃ encapsulation temperature	C 包埋时间/h encapsulation time	D 搅拌速度/(r·min^-1) agitation rate	包埋率/% encapsulation efficiency
1	6∶1	40	3	700	65
2	6∶1	50	4	1000	78
3	6∶1	60	5	1300	62
4	9∶1	40	4	1300	58
5	9∶1	50	5	700	48
6	9∶1	60	3	1000	45
7	12∶1	40	5	1000	61
8	12∶1	50	3	1300	63
9	12∶1	60	4	700	46
k₁	68.333	61.333	57.667	53.000
k₂	50.333	63.000	60.667	61.333
k₃	56.667	51.000	57.000	61.000
R	18.000	12.000	3.667	8.333

因素 factor	偏差平方和 squares of deviance	自由度 freedom	F值 F value	显著性 significance
A	500.222	2	2.198	*
B	253.556	2	1.114
C	22.889	2	0.101
D	133.556	2	0.587
误差error	1.56	2

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Preparation and Slow-release Properties of Cinnamomum cassia Leaves Essential Oil/β-Cyclodextrin Microcapsules

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