Chemistry and Industry of Forest Products ›› 2021, Vol. 41 ›› Issue (4): 77-84.doi: 10.3969/j.issn.0253-2417.2021.04.011
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Qiong WANG1(), Xuan YANG1, Zhenghan CAI1, Yandan CHEN1, Biao HUANG1, Guanfeng LIN1,2,*()
Received:
2021-01-14
Online:
2021-08-28
Published:
2021-08-31
Contact:
Guanfeng LIN
E-mail:1160830134@qq.com;feton.lin@hotmail.com
CLC Number:
Qiong WANG, Xuan YANG, Zhenghan CAI, Yandan CHEN, Biao HUANG, Guanfeng LIN. Preparation of Multi-doped Activated Carbon Based on Alkali/Thiourea Synergistic Activation[J]. Chemistry and Industry of Forest Products, 2021, 41(4): 77-84.
Table 1
Effects of activation temperatures and doping methods on iodine adsorption value and yield of doped activated carbon"
样品 samples | 原料用量raw material amount/g | 活化温度/℃ activation temp. | 得率/% yield | 碘吸附值/(mg·g-1) iodine value | ||
KOH | 硫脲 thiourea | 炭化料 carbonized material | ||||
P, T-800 | 15 | 5 | 5 | 800 | 23.2 | 1188.2 |
P, T-850 | 15 | 5 | 5 | 850 | 22.9 | 1832.9 |
P, T-900 | 15 | 5 | 5 | 900 | 22.3 | 2080.0 |
P, T-950 | 15 | 5 | 5 | 950 | 15.3 | 1850.9 |
P, T-1000 | 15 | 5 | 5 | 1000 | 12.7 | 1834.5 |
P-900 | 15 | 0 | 5 | 900 | 38.4 | 1684.4 |
T-900 | 0 | 5 | 5 | 900 | 18.0 | 644.8 |
C-900 | 0 | 0 | 5 | 900 | 41.3 | 789.7 |
Table 2
Specific surface area and pore structure of different types of doped activated carbon"
样品 samples | SBET/(m2·g-1) | VT/(cm3·g-1) | Vmicro/(cm3·g-1) | Vmeso/(cm3·g-1) | d/nm |
P, T-900 | 2517.2 | 1.73 | 0.14 | 1.59 | 2.75 |
P-900 | 1882.5 | 0.96 | 0.77 | 0.19 | 0.85 |
T-900 | 576.4 | 0.41 | 0.24 | 0.17 | 0.57 |
C-900 | 833.0 | 0.48 | 0.22 | 0.26 | 2.33 |
1 |
辛冉冉, 缪杭锦, 姜伟, 等. 氮掺杂高比表面多孔碳的一步化学活化法制备及其超电容性能[J]. 无机化学学报, 2019, 35 (10): 1781- 1790.
doi: 10.11862/CJIC.2019.222 |
XIN R R , MIAO H J , JIANG W , et al. N-doped porous carbons with high surface areas prepared through one-step chemical activation and their application for supercapacitors[J]. Chinese Journal of Inorganic Chemistry, 2019, 35 (10): 1781- 1790.
doi: 10.11862/CJIC.2019.222 |
|
2 | 左宋林, 王永芳, 张秋红. 活性炭作为电能储存与能源转化材料的研究进展[J]. 林业工程学报, 2018, 3 (4): 1- 11. |
ZUO S L , WANG Y F , ZHANG Q H . Activated carbons for the electrochemical storage of energy and electrochemical catalytic conversion of fuels: A review[J]. Journal of Forestry Engineering, 2018, 3 (4): 1- 11. | |
3 |
吴登鹏, 姚路, 林烨, 等. 氮掺杂活性炭的制备及其性能研究[J]. 电源技术, 2019, 43 (9): 1478- 1481.
doi: 10.3969/j.issn.1002-087X.2019.09.019 |
WU D P , YAO L , LIN Y , et al. Synthesis and electrochemical performance of nitrogen-doped activated carbon[J]. Power Technology, 2019, 43 (9): 1478- 1481.
doi: 10.3969/j.issn.1002-087X.2019.09.019 |
|
4 |
YU X , PARK H S . Sulfur-incorporated, porous graphene films for high performance flexible electrochemical capacitors[J]. Carbon, 2014, 77, 59- 65.
doi: 10.1016/j.carbon.2014.05.002 |
5 |
HAN J , ZHANG L L , LEE S , et al. Generation of B-doped graphene nanoplatelets using a solution process and their supercapacitor applications[J]. ACS Nano, 2013, 7 (1): 19- 26.
doi: 10.1021/nn3034309 |
6 |
FULVIO P F , LEE J S , MAYES R T , et al. Boron and nitrogen-rich carbons from ionic liquid precursors with tailorable surface properties[J]. Physical Chemistry Chemical Physics, 2011, 13 (30): 13486- 13491.
doi: 10.1039/c1cp20631a |
7 |
WANG S Y , IYYAMPERUMAL E , ROY A , et al. Vertically aligned BCN nanotubes as efficient metal free electrocatalysts for the oxygen reduction reaction: A synergetic effect by co-doping with boron and nitrogen[J]. Angewandte Chemie International Edition, 2011, 50 (49): 11756- 11760.
doi: 10.1002/anie.201105204 |
8 |
HULICOVA-JURCAKOVA D , SEREDYCH M , GAO Q L , et al. Effect of surface phosphorus functionalities of activated carbons containing oxygen and nitrogen on electrochemical capacitance[J]. Carbon, 2009, 47 (6): 1576- 1584.
doi: 10.1016/j.carbon.2009.02.006 |
9 |
LIANG J , JIAO Y , JARONIEC M , et al. Sulfur and nitrogen dual-doped mesoporous graphene electrocatalyst for oxygen reduction with synergistically enhanced performance[J]. Angewandte Chemie International Edition, 2012, 51 (46): 11496- 11500.
doi: 10.1002/anie.201206720 |
10 |
CHEN H , YU F , WANG G , et al. Nitrogen and sulfur self-doped activated carbon directly derived from elm flower for high-performance supercapacitors[J]. ACS Omega, 2018, 3 (4): 4724- 4732.
doi: 10.1021/acsomega.8b00210 |
11 | LI Y J, WANG G L, WEI T, et al. Nitrogen and sulfur co-doped porous carbon nanosheets derived from willow catkin for supercapacitors[J/OL]. Nano Energy, 2016, 19: 1-11[2020-10-10]. http://dx.doi.org/10.1016/j.nanoen.2015.10.038. |
12 | 方建辉, 姚伯元, 韩福顺. 氢氧化钾活化石油焦制备高比表面积活性炭[J]. 化工进展, 2011, 30 (10): 2258- 2261. |
FANG J H , YAO B Y , HAN F S . Preparation of the activated carbon with high specific surface area from petroleum coke by KOH activation[J]. Chemiacal Industry and Eengineering Progress, 2011, 30 (10): 2258- 2261. | |
13 | VANSANT E F. International symposium on gas separation technology(ISG 89): Antwerp, belgium, 10-15 September 1989[J]. 1990, 4(2): 115-116. |
14 | SING K S W . Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)[J]. Pure & Applied Chemistry, 1985, 57 (4): 603- 619. |
15 | HULICOVA-JURCAKOVA D , SEREDYCH M , GAO Q L , et al. Combined effect of nitrogen- and oxygen-containing functional groups of microporous activated carbon on its electrochemical performance in supercapacitors[J]. Advanced Functional Materials, 2010, 19 (3): 438- 447. |
16 | TIAN W , GAO Q , QIAN W . Interlinked porous carbon nanoflakes derived from hydrolyzate residue during cellulosic bioethanol production for ultrahigh-rate supercapacitors in non-aqueous electrolytes[J]. ACS Sustainable Chemistry & Engineering, 2016, 5 (2): 1297- 1305. |
17 |
INAL I , HOLMES S M , BANFORD A , et al. The performance of supercapacitor electrodes developed from chemically activated carbon produced from waste tea[J]. Applied Surface Science, 2015, 357, 696- 703.
doi: 10.1016/j.apsusc.2015.09.067 |
18 |
GOPIRAMAN M , DENG D , KIM B S , et al. Three-dimensional cheese-like carbon nanoarchitecture with tremendous surface area and pore construction derived from corn as superior electrode materials for supercapacitors[J]. Applied Surface Science, 2017, 409, 52- 59.
doi: 10.1016/j.apsusc.2017.02.209 |
19 |
STRELKO V V , KUTS V S , THRWER P A . On the mechanism of possible influence of heteroatoms of nitrogen, boron and phosphorus in a carbon matrix on the catalytic activity of carbons in electron transfer reactions[J]. Carbon, 2000, 38 (10): 1499- 1503.
doi: 10.1016/S0008-6223(00)00121-4 |
20 |
YU X , KANG Y B , PARK H S . Sulfur and phosphorus co-doping of hierarchically porous graphene aerogels for enhancing supercapacitor performance[J]. Carbon, 2016, 101, 49- 56.
doi: 10.1016/j.carbon.2016.01.073 |
21 | 臧锐. 生物质基活性碳材料的制备及电化学性能的研究[D]. 南京: 南京航空航天大学, 2016. |
ZANG R. Preparation of biomass-based activated carbon and for electrochemical supercapacitors[D]. Nanjing: Nanjing University of Aeronautics and Austronautics, 2016. |
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