Chemistry and Industry of Forest Products ›› 2021, Vol. 41 ›› Issue (6): 97-104.doi: 10.3969/j.issn.0253-2417.2021.06.013
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Jie TIAN1, Rui LOU1,*(), Xiangyu XUE1, Hong ZHANG1, Shubin WU2, Huimin XU3
Received:
2020-12-01
Online:
2021-12-28
Published:
2021-12-31
Contact:
Rui LOU
E-mail:lourui@sust.edu.cn
CLC Number:
Jie TIAN, Rui LOU, Xiangyu XUE, Hong ZHANG, Shubin WU, Huimin XU. Thermal Degradation Characteristics of Lignin Nanoparticles and Its Reaction Kinetics Analysis[J]. Chemistry and Industry of Forest Products, 2021, 41(6): 97-104.
Table 1
Primary elemental composition of different kinds of lignin"
样品sample | C | H | O | N | H/C | |
DES-木质素 DES-lignin | L100 | 58.31 | 4.15 | 34.69 | 0.41 | 0.85 |
L130 | 58.72 | 4.58 | 34.05 | 0.48 | 0.94 | |
L150 | 59.98 | 5.52 | 33.56 | 0.43 | 1.10 | |
柳木willow[ | 60.81 | 5.50 | 33.52 | 0.41 | 1.09 | |
磨木木质素[ milled wood lignin(MWL) | 银杏ginkgo | 59.34 | 6.04 | 33.16 | 0.81 | 1.12 |
松木pine | 59.25 | 5.98 | 34.74 | 0.03 | 1.21 | |
杨木poplar | 58.73 | 6.04 | 34.70 | 0.10 | 1.23 | |
酶解/温和酸解木质素[ enzymatic/mild acid hydrolysis lignin(EMAL) | 麦草wheat straw | 63.81 | 6.12 | 27.91 | 0.54 | 1.15 |
棉杆cotton stalk | 60.46 | 5.88 | 27.24 | 0.65 | 1.17 | |
蔗渣bagasse | 57.67 | 5.78 | 30.65 | 0.87 | 1.20 |
Table 2
Kinetic parameters of DES-lignin pyrolysis reaction"
DES-木质素 DES-lignin | 温度/℃ temperature | 线性拟合方程 linear fitting equation | R2 | E/(kJ·mol-1) | A/min-1 |
L100 | 200~300 | Y=-2722.80X-1.00 | 0.9725 | 52.13 | 18.80×104 |
330~450 | Y=-2358.95X-1.82 | 0.9862 | 49.25 | 59.00×103 | |
L130 | 200~300 | Y=-3496.39X-0.53 | 0.9188 | 51.76 | 20.14×104 |
330~450 | Y=-1765.915X-2.809 | 0.9859 | 35.63 | 28.50×102 | |
L150 | 200~300 | Y=-3062.743X-0.399 | 0.9662 | 51.52 | 14.58×104 |
330~450 | Y=-1585.127X-3.174 | 0.9856 | 32.65 | 12.28×102 |
1 |
KANG K , ZHU M Q , SUN G T , et al. Codensification of Eucommia ulmoides Oliver stem with pyrolysis oil and char for solid biofuel: An optimization and characterization study[J]. Applied Energy, 2018, 223, 347- 357.
doi: 10.1016/j.apenergy.2018.04.069 |
2 |
KAN T , STREZOV V , EVANS T J . Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters[J]. Renewable and Sustainable Energy Reviews, 2016, 57, 1126- 1140.
doi: 10.1016/j.rser.2015.12.185 |
3 |
XIAO B , SUN X F , SUN R C . Chemical, structural, and thermal characterizations of alkali-soluble lignins and hemicelluloses, and cellulose from maize stems, rye straw, and rice straw[J]. Polymer Degradation and Stability, 2001, 74 (2): 307- 319.
doi: 10.1016/S0141-3910(01)00163-X |
4 | HAO W M , BJÖRNERBÄCK F , TRUSHKINA Y , et al. High-performance magnetic activated carbon from solid waste from lignin conversion processes: 1.Their use as adsorbents for CO2[J]. ACS Sustainable Chemistry & Engineering, 2017, 5 (4): 3087- 3095. |
5 |
YANG B S , KANG K Y , JEONG M J . Preparation of lignin-based carbon aerogels as biomaterials for nano-supercapacitor[J]. Journal of the Korean Physical Society, 2017, 71 (8): 478- 482.
doi: 10.3938/jkps.71.478 |
6 | WEI R F, XIANG D W, LONG H M, et al. Reduction of iron oxide by lignin: Characteristics, kinetics and superiority[J/OL]. Energy, 2020, 197: 1-10[2020-11-13]. https://doi.org/10.1016/j.energy.2020.117203. |
7 | LOU R , MA R S , LIN K T , et al. Facile extraction of wheat straw by deep eutectic solvent (DES) to produce lignin nanoparticles[J]. ACS Sustainable Chemistry & Engineering, 2019, 7 (12): 10248- 10256. |
8 | LI T F, LYU G J, LIU Y, et al. Deep eutectic solvents (DESs) for the isolation of willow lignin (Salix matsudana cv. Zhuliu)[J/OL]. International Journal of Molecular Sciences, 2017, 18(11): 1-11[2020-11-13]. https://doi.org/10.3390/ijms18112266. |
9 | CHEN Y J , ZHANG L L , YU J , et al. High-purity lignin isolated from poplar wood meal through dissolving treatment with deep eutectic solvents[J]. Royal Society Open Science, 2019, 6 (1): 181- 757. |
10 |
娄瑞, 刘钰, 周寅轩, 等. 低共熔溶剂高效分离纳米木质素及其结构特性研究[J]. 陕西科技大学学报, 2020, 38 (6): 6- 10.
doi: 10.3969/j.issn.1000-5811.2020.06.002 |
LOU R , LIU Y , ZHOU Y X , et al. Study on the extraction and structural performance of lignin nanoparticles by deep eutectic solvent method[J]. Journal of Shaanxi University of Science & Technology, 2020, 38 (6): 6- 10.
doi: 10.3969/j.issn.1000-5811.2020.06.002 |
|
11 | DAS L , LI M , STEVENS J , et al. Characterization and catalytic transfer hydrogenolysis of deep eutectic solvent extracted sorghum lignin to phenolic compounds[J]. ACS Sustainable Chemistry & Engineering, 2018, 6 (8): 10408- 10420. |
12 | 崔兴凯, 赵雪冰, 刘德华. 五种甘蔗渣分离木质素热解特性及动力学[J]. 化工进展, 2017, 36 (8): 2910- 2915. |
CUI X K , ZHAO X B , LIU D H . Pyrolysis characteristics and kinetics of five isolated lignins from sugarcane bagasse[J]. Chemical Industry and Engineering Progress, 2017, 36 (8): 2910- 2915. | |
13 |
WANG S R , RU B , LIN H Z , et al. Pyrolysis behaviors of four lignin polymers isolated from the same pine wood[J]. Bioresource Technology, 2015, 182, 120- 127.
doi: 10.1016/j.biortech.2015.01.127 |
14 | 娄瑞, 武书彬, 赵红霞, 等. 基于不同热分析法的稻草木质素热解反应动力学研究[J]. 中国科技论文在线精品论文, 2017, 10 (9): 1011- 1018. |
LOU R , WU S B , ZHAO H X , et al. Study on pyrolysis kinetics of lignin derived from rice straw by means of several thermosanalysis methods[J]. Chinese Science and Technology Papers Online Boutique Papers, 2017, 10 (9): 1011- 1018. | |
15 |
LYU G J , WU Q , LI T F , et al. Thermochemical properties of lignin extracted from willow by deep eutectic solvents (DES)[J]. Cellulose, 2019, 26 (15): 8501- 8511.
doi: 10.1007/s10570-019-02489-8 |
16 | COATS A W , REDFERN J P . Kinetic parameters from thermogravimetric data[J]. Nature, 1964, 201 (4): 68- 69. |
17 | SLUITER A, HAMES B, RUIZ R, et al. Determination of structural carbohydrates and lignin in biomass: Laboratory Analytical Procedure (LAP): NREL/TP-510-42618[G]. Golden: National Renewable Energy Laboratory, 2012-08-03. |
18 |
GUO X J , WANG S R , WANG K G , et al. Influence of extractives on mechanism of biomass pyrolysis[J]. Journal of Fuel Chemistry and Technology, 2010, 38 (1): 42- 46.
doi: 10.1016/S1872-5813(10)60019-9 |
19 |
张肖肖, 娄瑞, 董继先, 等. 低共熔溶剂应用于松木类木质素分离的研究[J]. 陕西科技大学学报, 2019, 37 (6): 13- 17.
doi: 10.3969/j.issn.1000-5811.2019.06.003 |
ZHANG X X , LOU R , DONG J X , et al. Study on the separation of lignin from pine biomass based on deep eutectic solvent[J]. Journal of Shaanxi University of Science & Technology, 2019, 37 (6): 13- 17.
doi: 10.3969/j.issn.1000-5811.2019.06.003 |
|
20 | 蒋恩臣, 陈爱慧, 秦丽元, 等. 木质素热解制备焦炭的试验研究[J]. 可再生能源, 2015, 33 (7): 1066- 1071. |
JIANG E C , CHEN A H , QIN L Y , et al. Experimental study on char produced from lignin pyrolysis[J]. Renewable Energy Resources, 2015, 33 (7): 1066- 1071. | |
21 | 刘洪杰, 邢山川, 张思思, 等. 低共熔溶剂试剂分离提取玉米芯纤维素[J]. 河北科技大学学报, 2017, 38 (6): 548- 554. |
LIU H J , XING S C , ZHANG S S , et al. Study on extraction of cellulose from corn cobs by deep eutectic solvents[J]. Journal of Hebei University of Science and Technology, 2017, 38 (6): 548- 554. | |
22 | LYU G, LI T, JI X, et al, Characterization of lignin extracted from willow by deep eutectic solvent treatments[J/OL]. Polymers, 2018, 10(8): 1-11[2020-11-13]. https://doi.org/10.3390/plym10080869. |
23 |
WANG L , ZHANG R , LI J , et al. Comparative study of the fast pyrolysis behavior of ginkgo, poplar, and wheat straw lignin at different temperatures[J]. Industrial Crops and Products, 2018, 122, 465- 472.
doi: 10.1016/j.indcrop.2018.06.038 |
24 | 武书彬, 胡元, 娄瑞, 等. 木质纤维生物质及其组分的理化特性与热解规律[M]. 北京: 科学出版社, 2013: 141- 172. |
WU S B , HU Y , LOU R , et al. Physicochemical Properties and Pyrolysis of Lignocellulosic Biomass and Its Components[M]. Beijing: Science Press, 2013: 141- 172. | |
25 |
林展飞, 宋兴飞, 刘心志. 黑液木质素焦热解动力学分析[J]. 能源研究与利用, 2019, (5): 38- 53.
doi: 10.3969/j.issn.1001-5523.2019.05.017 |
LIN Z F , SONG X F , LIU X Z . Pyrolysis kinetics of lignin coke in black liquor[J]. Energy Research & Utilization, 2019, (5): 38- 53.
doi: 10.3969/j.issn.1001-5523.2019.05.017 |
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