一种松香基阴离子表面活性剂的合成与性能研究

doi:10.3969/j.issn.0253-2417.2022.01.007

Abstract

Abstract:

Using dehydroabietic acid (DA) and 6-aminocaproic acid as the raw materials, a rosin-based amino acid surfactant (R-6) was synthesized via reactions of chlorination, amidation and saponification reactions.The ¹H NMR and ¹³C NMR signals of dehydroabietic acid were analyzed by using 2D NMR techniques, and the structure of the final product was also confirmed by ¹H NMR and FT-IR.The solubility, surface tension and foam properties of R-6 were investigated.The results showed that at room temperature, R-6 showed excellent solubility of above 800 mmol/L in water.The critical micelle concentration (C_cmc) of the surfactant was 5.89 mmol/L, and the surface tension (γ_cmc) corresponding to C_cmc was 40.46 mN/m.With the increase of surfactant concentration, R-6 exhibited strong ability in stabilizing foams.When the concentration of R-6solution was 10 mmol/L, the foam half-life was as high as 1 966 min.

Key words: dehydroabietic acid, amino acid, surfactant, foam, solubility

CLC Number:

TQ35

Shujing PANG, Hao CHEN, Binglei SONG. Synthesis and Properties of a Rosin-based Anionic Surfactant[J]. Chemistry and Industry of Forest Products, 2022, 42(1): 51-56.

Figures/Tables 8

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References 20

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Synthesis and Properties of a Rosin-based Anionic Surfactant

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