Chemistry and Industry of Forest Products ›› 2022, Vol. 42 ›› Issue (2): 1-9.doi: 10.3969/j.issn.0253-2417.2022.02.001
Previous Articles Next Articles
Jian CHEN, Guomin WU, Shuping HUO, Zhenwu KONG()
Received:
2021-01-28
Online:
2022-04-28
Published:
2022-05-06
Contact:
Zhenwu KONG
E-mail:kongzwlhs@163.com
CLC Number:
Jian CHEN, Guomin WU, Shuping HUO, Zhenwu KONG. Synthesis of Allyl Modified Lacquer and Its Characteristics of UV/Oxygen Curing[J]. Chemistry and Industry of Forest Products, 2022, 42(2): 1-9.
Table 1
Main physical and chemical indexes of lacquer and modified lacquer"
样品 sample | 羟值/(mg·g-1) hydroxyl value | 碘值/(g·g-1) iodine value | 黏度/(mPa·s,25 ℃) viscosity | 外观 appearance |
烯丙基缩水甘油醚AGE | — | 2.14 | 4 | 无色透明液体colorless transparent liquid |
生漆lacquer | 231 | 1.81 | 1600 | 棕灰色液体brown-grey liquid |
烯丙基醚改性生漆AGE-L | 193 | 1.89 | 400 | 棕红色液体brown-red liquid |
烯丙基醚酯改性生漆MAA-AGE-L | 20 | 1.38 | 2000 | 棕红色液体brown-red liquid |
Table 2
Mechanical properties of curing coating of lacquer and allyl modified lacquer"
样品 sample | 固化方式 curing method | 铅笔硬度 pencil hardness | 附着力/级 adhesion/ grade | 柔韧性/mm flexibility | 抗冲击强度/(kg·cm) impact strength | |
正冲 forward impact | 反冲 back impact | |||||
生漆lacquer | 氧oxygen(30 ℃,7 d) | H | 7 | 10 | 10 | 5 |
氧+热oxygen+hot(130 ℃,6 h) | 4H | 7 | 10 | 5 | 5 | |
UV | B | 3 | 0.5 | 10 | 5 | |
烯丙基醚改性生漆 AGE-L | 氧oxygen(30 ℃,7 d) | 2H | 2 | 0.5 | 50 | 50 |
UV | H | 1 | 0.5 | 50 | 50 | |
烯丙基醚酯改性生漆 MAA-AGE-L | 氧oxygen(30 ℃,7 d) | 2H | 3 | 5 | 50 | 50 |
UV | 2H | 5 | 10 | 5 | 5 |
Table 3
Chemical resistance of cured coating of allyl modified lacquer"
样品 sample | 固化方式 curing method | H2O (7 d) | 无水乙醇ethanol (7 d) | 5% NaCl (7 d) | 10% HCl (3 d) | 10% H2SO4 (3 d) | 10% NaOH (3 h) |
生漆lacquer | 氧oxygen(30 ℃,7 d) | + | + | + | + | + | - |
UV(120 s) | + | + | + | + | + | - | |
烯丙基醚改性生漆 AGE-L | 氧oxygen(30 ℃,7 d) | + | + | + | + | + | - |
UV(120 s) | + | + | + | + | + | - | |
烯丙基醚酯改性生漆 MAA-AGE-L | 氧oxygen(30 ℃,7 d) | + | + | + | + | + | - |
UV(120 s) | + | + | + | + | + | - |
1 |
孙祥玲, 吴国民, 孔振武. 生漆改性及其应用进展[J]. 生物质化学工程, 2014, 48 (2): 41- 47.
doi: 10.3969/j.issn.1673-5854.2014.02.008 |
SUN X L , WU G M , KONG Z W . Modification and application progress of raw lacquer[J]. Biomass Chemical Engineering, 2014, 48 (2): 41- 47.
doi: 10.3969/j.issn.1673-5854.2014.02.008 |
|
2 | 杨和永. 大漆施工经验[M]. 北京: 化学工业出版社, 1986: 12- 18. |
YANG H Y . Construction Experience of Lacquer[M]. Beijing: Chemical Industry Press, 1986: 12- 18. | |
3 | 王云龙. 生漆的干燥技术[J]. 中国生漆, 1992, 11 (1): 32- 36. |
WANG Y L . Drying technology of raw lacquer[J]. Journal of Chinese Lacquer, 1992, 11 (1): 32- 36. | |
4 | ZHANG D , XIA J R , XUE H Y , et al. Improvement on properties of Chinese lacquer by polyamidoamine[J]. Polymer Engineering and Science, 2020, 60 (2): 1- 9. |
5 | YANG J H, CHEN N, ZHU J F, et al. Polymerization mechanism of natural lacquer sap with special phase structure[J/OL]. Scientific Reports, 2020, 10(1): 1-9[2020-12-18]. https://doi.org/10.1038/s41598-020-69823-0. |
6 | 周光龙, 彭经寿, 郑小江. 生漆及其产业化开发研究[M]. 湖北: 湖北科学技术出版社, 2012: 160- 163. |
ZHOU G L , PENG J S , ZHENG X J . Study on Raw Lacquer and Its Industrialization Development[M]. Hubei: Hubei Science and Technology Press, 2012: 160- 163. | |
7 |
LU R , HARIGAYA S , ISHIMURA T . Developement of a fast drying lacquer based on raw lacquer sap[J]. Progress in Organic Coatings, 2004, 51 (3): 238- 243.
doi: 10.1016/j.porgcoat.2004.08.006 |
8 |
LU R , NARUHIKO E , ZHANG F L , et al. Development of a new type lacquer based on Rhus vernicifera sap with chitosan[J]. Progress in Organic Coatings, 2014, 77 (2): 439- 443.
doi: 10.1016/j.porgcoat.2013.11.006 |
9 |
ISHIMURA T , LU R , YAMASAKI K , et al. Effects of hybridization of lacquer sap with organic silane on drying properties[J]. Progress in Organic Coatings, 2008, 62 (2): 193- 198.
doi: 10.1016/j.porgcoat.2007.11.001 |
10 |
ISHIMURA T , LU R , MIYAKOSHI T . Studies on the reaction mechanism between urushiol and organic silane[J]. Progress in Organic Coatings, 2006, 55 (1): 66- 69.
doi: 10.1016/j.porgcoat.2005.10.003 |
11 |
ISHIMURA T , LU R , KEI Y , et al. Development of an eco-friendly hybrid lacquer based on kurome lacquer sap[J]. Progress in Organic Coatings, 2010, 69 (1): 12- 15.
doi: 10.1016/j.porgcoat.2010.04.019 |
12 |
GAO R J , WANG L W , QI L . Effect of hexamethylenetetramine on the property of Chinese lacquer film[J]. Progress in Organic Coatings, 2019, 133, 169- 173.
doi: 10.1016/j.porgcoat.2019.04.031 |
13 | 胡炳环, 林金火, 徐艳莲, 等. 生漆改性研究及漆酚金属高聚物[J]. 中国生漆, 2000, 19 (3): 1- 7. |
HU B H , LIN J H , XU Y L , et al. Study on modification of raw lacquer and urushiol metal polymer[J]. Journal of Chinese Lacquer, 2000, 19 (3): 1- 7. | |
14 | 夏建荣. 紫外光固化技术和紫外光固化涂料研究[D]. 福州: 福建师范大学, 2011. |
XIA J R. Research on UV curing technology and UV curable coatings[D]. Fuzhou: Fujian Normal University, 2011. | |
15 | 蔡奋. 生漆化学[M]. 贵州: 贵州人民出版社, 1986. |
CAI F . Lacquer Chemistry[M]. Guizhou: Cuizhou People's Publishing House, 1986. | |
16 |
陈健, 吴国民, 霍淑平, 等. 含醚、酯键烯丙基腰果酚单体的合成与表征[J]. 林产化学与工业, 2019, 39 (4): 42- 48.
doi: 10.3969/j.issn.0253-2417.2019.04.006 |
CHEN J , WU G M , HUO S P , et al. Synthesis and characterization of allyl cardanol monomer with ether bond and eater bond[J]. Chemistry and Industry of Forest Products, 2019, 39 (4): 42- 48.
doi: 10.3969/j.issn.0253-2417.2019.04.006 |
|
17 |
陈健, 吴国民, 霍淑平, 等. 烯丙基酯型腰果酚光固化单体的合成与性能研究[J]. 林产化学与工业, 2020, 40 (5): 34- 42.
doi: 10.3969/j.issn.0253-2417.2020.05.005 |
CHEN J , WU G M , HUO S P , et al. Synthesis and properties of photocurable monomers from cardanol with allyl ester group[J]. Chemistry and Industry of Forest Products, 2020, 40 (5): 34- 42.
doi: 10.3969/j.issn.0253-2417.2020.05.005 |
|
18 | 贺克强. 涂料催干剂的进展与反应机理[J]. 武汉工业大学学报, 2000, 22 (4): 16- 19. |
HE K Q . The developments and reaction mechanism in driers for coating[J]. Journal of Wuhan University of Technology, 2000, 22 (4): 16- 19. | |
19 | 金章岩, 陈天佑. 中国生漆的红外光谱分析[J]. 中国生漆, 1985, 4 (1): 1- 10. |
JIN Z Y , CHEN T Y . Infrared spectrum analysis of Chinese lacquer[J]. Journal of Chinese Lacquer, 1985, 4 (1): 1- 10. | |
20 | 余仲元, 李勇富, 郭明高. 中国生漆的红外光谱研究[J]. 中国生漆, 1989, 8 (3): 1- 8. |
YU Z Y , LI Y F , GUO M G . Study on infrared spectrum of Chinese lacquer[J]. Journal of Chinese Lacquer, 1989, 8 (3): 1- 8. | |
21 | 杜希文, 原续波. 材料分析方法[M]. 天津: 天津大学出版社, 2006: 247- 253. |
DU X W , YUAN X B . Analysis Techniques in Materials Science[M]. Tianjin: Tianjin University Press, 2006: 247- 253. | |
22 | LU R, MIYAKOSHI T. Lacquer Chemistry and Applications[M]. [S.l.]: Elsevier, 2015: 27-29, 218. |
23 | 贺潜, 郑杰, 田云刚, 等. 生漆中Cl5三烯漆酚的分离制备[J]. 吉首大学学报(自然科学版), 2016, 37 (5): 42- 44. |
HE Q , ZHENG J , TIAN Y G , et al. Separation and preparation of a C15 triolefinic urushiol from raw lacquer[J]. Journal of Jishou University(Natural Science Edition), 2016, 37 (5): 42- 44. | |
24 |
张飞龙. 生漆成膜的分子机理[J]. 中国生漆, 2012, 31 (1): 13- 20.
doi: 10.3969/j.issn.1000-7067.2012.01.004 |
ZHANG F L . Molecular mechanism of lacquer film formation[J]. Journal of Chinese Lacquer, 2012, 31 (1): 13- 20.
doi: 10.3969/j.issn.1000-7067.2012.01.004 |
|
25 | KUMANOTANI J . Urushiol(oriental lacquer): A natural aesthetic durable and future-promising coating[J]. Progress in Organic Coatings, 1995, 26 (2/3/4): 163- 195. |
26 | 袁雅慧. 光暗双固化保形涂料的研究[D]. 广州: 中山大学, 2004. |
YUAN Y H. Study on light and dark dual curing coating[D]. Guangzhou: Sun Yat-sen University, 2004. |
[1] | GAO Renjin, WANG Liwei, YE Yongxin, LI Wenyuan, XIA Jianrong. Preparation and Properties of Cellulose-based Urushiol Acetal Composite Coatings [J]. Chemistry and Industry of Forest Products, 2022, 42(2): 19-24. |
[2] | Hongxia CHEN, Hao ZHOU, Ran TAO, Zhiwen QI, Wenjun LI, Chengzhang WANG. Study on Polyphenols in Lacquer Tree by Matrix Solid-phase Dispersion and HPLC-IT-TOF/MS [J]. Chemistry and Industry of Forest Products, 2022, 42(1): 10-20. |
[3] | Jian CHEN, Guomin WU, Shuping HUO, Zhenwu KONG. Characteristics of UV Curing Reaction of Allyl Cardanol Monomers [J]. Chemistry and Industry of Forest Products, 2021, 41(2): 55-64. |
[4] | Hao ZHOU, Xingying XUE, Hongxia CHEN, Jianzhong YE, Chengzhang WANG. Preparation of Nanoemulsion of Lacquer Seed Oil and Its Anti-oxidation and Anti-UV Activity [J]. Chemistry and Industry of Forest Products, 2021, 41(1): 45-52. |
[5] | Jian CHEN,Guomin WU,Shuping HUO,Zhenwu KONG. Synthesis and Properties of Photocurable Monomers from Cardanol with Allyl Ester Group [J]. Chemistry and Industry of Forest Products, 2020, 40(5): 34-42. |
[6] | Zhiwen QI,Hao ZHOU,Hongxia CHEN,Changwei ZHANG,Tao DENG,Chengzhang WANG. pH Responsiveness and Their in vitro Properties of Urushiol-based BPAU-NH2-Gal Paclitaxel-loaded Micelle [J]. Chemistry and Industry of Forest Products, 2020, 40(5): 121-128. |
[7] | Lei ZENG,Yu CAO,Fuhou LEI,Bo'an SHI. Determination of Magnolol Based on Ru(bpy)32+-doped Silica/Urushiol Electrochemiluminescence Sensor [J]. Chemistry and Industry of Forest Products, 2020, 40(1): 25-30. |
[8] | Hao ZHOU,Zhiwen QI,Ran TAO,Hongxia CHEN,Chengzhang WANG. Synthesis and HDAC Inhibitory Activity of Novel Urushiol Hydroxamic Acid Derivatives [J]. Chemistry and Industry of Forest Products, 2020, 40(1): 106-112. |
[9] | Jian CHEN,Guomin WU,Shuping HUO,Zhenwu KONG. Synthesis and Characterization of Allyl Cardanol Monomer with Ether Bond and Ester Bond [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 42-48. |
[10] | Wan ZHAO,Qianwen CAO,Haitang WU,Xiaohua HUANG. Preparation and Properties of UV-curable Urushiol-cerium Polymer Coatings [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 113-119. |
[11] | Xingying XUE,Hao ZHOU,Changwei ZHANG,Hongxia CHEN,Chengzhang WANG. Preparation, Antibacterial Activity and Preservation of Lacquer Wax Composite Coating Preservative [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 123-128. |
[12] | Hao ZHOU,Zhiwen QI,Yulu MA,Chengzhang WANG. pH Responsiveness and in vitro Performance of Urushiol/Amphiphilic Copolymer mPEG-PBAE Micelles [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 25-32. |
[13] | CHEN Jian, WU Guomin, HUO Shuping, KONG Zhenwu. Research Progress of Cardanol Based UV-cured Materials [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 1-10. |
[14] | CHEN Hongxia, WANG Chengzhang, YE Jianzhong, ZHOU Hao, TAO Ran. Preparation Technology and Properties of Lacquer Wax Fatty Powder [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 67-74. |
[15] | LU Yanju, ZHAO Zhendong, GU Yan, WANG Jing, XU Shichao. Microwave Irradiation Synthesis, Characterization and UV-curing Reaction of Allyl Acrylpimarate [J]. Chemistry and Industry of Forest Products, 2017, 37(6): 49-55. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||