蔗渣浆全无氯清洁漂白生产实践

doi:10.3969/j.issn.0253-2417.2014.06.011

Abstract

Abstract: The experimental research, process design and production practice of total chlorine free OpQPo bleaching bagasse pulp were introduced in this paper. The results showed that Kappa number decreased from 14.0-15.0 to 7.0-7.3 with a 50%-51% removal of residual lignin, and pulp brightness increased from 42%-45%(ISO) to 58%-60%(ISO) after a strengthened oxygen delignification. The production practice showed a better performance than that in lab. After subsequent pretreatment and pressurized hydrogen peroxide bleaching, the final pulp brightness was beyond 80% and the viscosity was over 800 mL/g. The pulp quality was much better than traditional Chlorine-Alkali Extraction-Hypochlorite(CEH) bleached pulp. Moreover, adsorbable organic halides (AOX) was not generated any more in the bleaching process. The wastewater was only discharged in chelating pretreatment (Q) stage and easily treated to meet the critical discharge standard due to its lower chromaticity and lower pollution load. In contrast to the traditional bleaching, no additional investment was needed in this new technology. Besides, the production procedure was flexible and the operation was stable. The investment of main equipments was about ￥13.55 million yuan.

Key words: bagasse pulp, OpQPo bleaching, production practice, AOX

CLC Number:

TQ35
TS745

HE Shui-lin, LI Jun, LI Zhi, XU Jun, MO Li-huan. Production Practice of Total Chlorine Free Clean Bleaching Bagasse Pulp[J]. Chemistry and Industry of Forest Products, 2014, 34(6): 69-74.

References

[1] 曹邦威.蔗渣原料在造纸工业中的应用[J].纸和造纸,2006,25:21-23.
[2] FLETCHER D E,JOHANSSON N G,BASTA J J,et al.TCF bleaching of sulfite pulps:New aspects[J].Tappi Journal,1997,80(12):143-147.
[3] FUHRMANN A L,RAUTONEN R.Effects of ECF and TCF bleaching sequences on the properties of softwood kraft pulp[J].Journal of Pulp and Paper Science,1997,23(10):487-493.
[4] NORMANDEAU G M.ECF bleach plant scale solutions at DMI Peace River Pulp Division[J].Pulp and Paper Canada,2003,104(4):32-36.
[5] 李军,李焜,吴绘敏,等.麦草浆OQPo清洁漂白生产实践[J].中国造纸,2009,28(6):38-41.
[6] 刘艳兰,陈克复,李军,等.蔗渣浆的全无氯漂白工艺[J].华南理工大学学报:自然科学版,2010,38(2):29-30,66.
[7] 王兆江,陈克复,李军,等.碱法蔗渣浆全无氯漂白技术研究[J].中国造纸,2009,28(12):1-4.
[8] VALCHEV I,VALCHEV E,CHRISTOVA E.Kinetics of oxygen delignification of hardwood kraft pulp[J].Cellulose Chemistry and Technology,1999,33(3):303-310.
[9] MALINEN R,FUHRMANN A.Recent trends in bleaching of chemical pulp[J].Paper and Timber,1995,77(3):78-83.
[10] 刘艳兰,陈克复,李军,等.麦草浆过氧化氢强化氧脱木质素的研究[J].中国造纸,2009,28(9):13-16.
[11] ZHANG Zeng,ZHAN Huai-yu,JAMEEL H,et al.Influence and control of metal ions: An investigation into high temperature peroxide bleaching[J].Journal of South China University of Technology (Natural Science),2000,28(2):35-41.
[12] GELLERSTEDT G,ZHANG Li-ming.Chemistry of TCF-bleaching with oxygen and hydrogen peroxide[J].ACS Symposium Series,2001,785:61-72.
[13] STROMBERG B,SZOPINSKI R.Pressurized hydrogen peroxide bleaching for improved TCF bleaching[C] //Proceedings of the 1994 International Pulp Bleaching Conference.Atlanta:TAPPI Press,1994.
[14] 邱玉桂,徐淑莺,余莉娜,等.自由基与纸浆漂白(Ⅰ)—自由基的产生及其在漂白中的作用[J].华南理工大学学报:自然科学版,2001,29(1):64-69.
[15] 陈克复.中高浓制浆造纸技术的理论与实践[M].北京:中国轻工业出版社,2007.
[16] 李玉峰,陈嘉川,杨桂花.简述几种AOX的治理技术[J].上海造纸,2007,38(5):57-59.
[17] YUKIO N,SAYURI Y,AKIKO K.Adsorbable organic halides (AOX),AOX formation potential,and PCDDs/DFs in landfill leachate and their removal in water treatment processes[J].Journal of Material Cycles and Waste Management,2001,3(2):126-134.
[18] 黄毅华.桉木蔗渣混合浆的漂白[J].广西轻工业,2004(4):24-27.

Production Practice of Total Chlorine Free Clean Bleaching Bagasse Pulp

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	MA Shuai, HU Xiaoying, DONG Changqing, ZHAO Ying, WANG Xiaoqiang, ZHAO Jin. Research Progress in the Removal of Biomass Tar Model Compounds [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 1-8.
[2]	XING Jianxiong, ZHENG Kai, HAN Zunqiang, XU Weitao, WANG Kun. Research Progress on Application of Cellulose-based Materials as Electrode in Flexible Supercapacitor [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 9-17.
[3]	CHEN Jinwei, WANG Dan, SHANG Shibin, LIU He, CAI Zhaosheng. Preparation of Amino-terminated Hyperbranched Polymer Grafted Dialdehyde-based Nanocellulose and Its Adsorption Properties of Ni²⁺ [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 18-26.
[4]	WANG Xiaoyu, DUAN Wengui, LIN Guishan, KANG Guoqiang, SHANG Minghao, LEI Fuhou. Synthesis and Antifungal Activity of (Z)-/(E)-Verbenone Oxime Ether Compounds [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 27-34.
[5]	ZHANG Qingtong, YUN Xiaojing, YAN Depeng, LI Mingfu, WANG Shuangfei, MIN Douyong. Preparation of Sliver Nanoparticles by Lignin Under Solar Light Irradiation [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 35-41.
[6]	CHEN Jian, WU Guomin, HUO Shuping, KONG Zhenwu. Synthesis and Characterization of Allyl Cardanol Monomer with Ether Bond and Ester Bond [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 42-48.
[7]	CHEN Yan, WANG Zixin, LI Qizhen, XIA Jianyu, LIU Zhulan, CAO Yunfeng. Synthesis and Characterization of Lignocellulose Oil-absorbing Aerogels [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 49-55.
[8]	WU Shaoji, JIANG Kun, YE Yueyuan, LIU Yunquan, WANG Duo, LI Shuirong. Preparation of Activated Carbon from Co-pyrolysis Char of Sewage Sludge and Poplar Sawdust and Its Application in Wastewater Treatment [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 56-64.
[9]	WANG Pengfei, REN Hao, ZHAI Huamin. P-factor Regulation of Characteristics in the Auto Hydrolysis ofPoplar Carbohydrate [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 65-71.
[10]	XIONG Mingcheng, WANG Zi, YAN Yuxin, ZHENG Yanling, XIAO Zhenzhen, LU Qilin, HUANG Biao. Preparation of Nanocrystalline Cellulose by the Catalytic Hydrolysis of Pulp with p-Toluenesulfonic Acid Under Ultrasonication [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 72-76.
[11]	LIU Yijun, YUAN Yuan, LIU Yangyang, ZHANG Fan, LI Jihua. Effects of Different Drying Methods on Physicochemical Properties and Essential Oil Quality of Melaleuca alternifolia Cheel [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 77-82.
[12]	WANG Xiaojie, HUANG Lixin, ZHANG Caihong, XIE Pujun, DENG Yejun, LIU Lujie. Preparation and Physicochemical Properties of Olive Leaf Extract [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 83-90.
[13]	PENG Yan, TANG Kehua, DONG Aiwen. Purification of Bletilla striata Polyphenols by Macroporous Resin and Its Antioxidant Activities in Vitro [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 91-99.
[14]	LI Junjie, DONG Yun, ZHAO Huaping, MA Hongxia. Synthesis and Characterization of Cardanol-based Epoxy Resin Containing A Cyclotriphosphazene Core [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 100-104.
[15]	ZHOU Jing, GUI Yuhao, GONG Shengzhao. Antioxidant Activity of Tea Seed Shell Fermentation Extracts and Its Inhibitory Effect on Intracellular Oxidative Damage [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 105-112.