木薯淀粉预处理及对酶法合成松香淀粉酯的影响

doi:10.3969/j.issn.0253-2417.2015.01.014

Abstract

Abstract: Pretreatment of cassava starch with NaOH/Urea and its effect on enzymatic synthesis of rosin starch ester were studied in this paper. The granule morphology and crystal structure of pretreated cassava starch were characterized by SEM, FT-IR, and XRD methods. The results showed that the granule of starch still maintained a certain round or oval morphological structure after pretreatment, but its surface was broken and exhibited some kinds of crack. The crystallinity of pretreated cassava starch was reduced. Based on the comparison of physicochemical properties between cassava starch and pretreated cassava starch, it was showed that the dissolution rate and transparency of pretreated cassava starch increased 38.2 percent and 9.1 percent, and the relative viscosity went down. Enzymatic esterifications of cassava starch and pretreated cassava starch with rosin were carried out. The degree of substitutions(D_S) of the esterifications were determined in order to investigate the effect of pretreatment on the reaction. The results indicated that pretreatment increased the degree of substitution of esterified products remarkably, and the D_S value of 0.102 was achieved. FT-IR analysis showed that a new peak at 1720 cm^-1 was observed in the spectra of esterified products produced from pretreated cassava starch, which corresponded to CO stretching in the ester group. The results indicated that the chemical reactivity of pretreated cassava starch increased significantly.

Key words: rosin, cassava starch, pretreated, esterification, immobilized lipase

CLC Number:

TQ351
TS231

LI He, LIN Ri-hui, LONG Han, WANG Sheng, CHEN Ran-qiong, WEI Cheng-yu. Pretreatment of Cassava Starch and Its Effect on Enzymatic Synthesis of Rosin Starch Ester[J]. Chemistry and Industry of Forest Products, 2015, 35(1): 89-93.

References

[1] 孙慧敏,马晓军.木薯淀粉及木薯变性淀粉性质比较研究[J].食品工业科技,2008,29(6):82-84. SUN Hui-min,MA Xiao-jun.Study on comparison of properties of tapioca and complex modified starches[J].Science and Technology of Food Industry,2008,29(6):82-84.
[2] DUAN Wen-gui,FANG Hua-xiang,MA Huan-ge,et al.Microwave-assisted synthesis of maleated rosin-cassava starch ester[J].Chemistry and Industry of Forest Products,2009,29(5):16-22.
[3] 唐世华,李景权,覃浩鹏,等.松香酸淀粉酯的合成与结构表征[J].林产化学与工业,2011,31(6):55-60. TANG Shi-hua,LI Jing-quan,QIN Hao-peng,et al.Synthesis and structure characterization of rosin starch ester[J].Chemistry and Industry of Forest Products,2011,31(6):55-60.
[4] HORCHANI H,CHABOUNI M,GARGOURI Y,et al.Solvent-free lipase-catalyzed synthesis of long-chain starch esters using microwave heating:Optimization by response surface methodology[J].Carbohydrate Polymers,2010,79(2):466-474.
[5] GENG Feng-ying,CHANG P R,YU Jiu-gao,et al.The fabrication and the properties of pretreated corn starch laurate[J].Carbohydrate Polymers,2010,80(2):360-365.
[6] HUANG Zu-qiang,XIE Xin-ling,CHEN Yuan,et al.Ball-milling treatment effect on physicochemical properties and features for cassava and maize starches[J].Comptes Rendus Chimie,2008,11(1/2):73-79.
[7] SHARIFFA Y N,KARIM A A,FAZILAH A.Enzymatic hydrolysis of granular native and mildly heat-treated tapioca and sweet potato starches at sub-gelatinization temperature[J].Food Hydrocolloids,2009,23(2):434- 440.
[8] LU Xuan-xuan,LUO Zhi-gang,YU Shu-juan,et al.Lipase-catalyzed synthesis of starch palmitate in mixed ionic liquids[J].Journal of Agricultural and Food Chemistry,2012,60(36):9273-9279.
[9] WIM T,MOHAMED N B,ALAIN D.Starch nanocrystals with large chain surface modifications[J].Langmuir,2006,22(10):4804-4810.
[10] ZHOU Jin-ping,ZHANG Li-na.Solubility of cellulose in NaOH /urea aqueous solution[J].Polymer Journal,2000,32(10):866-870.
[11] BAI Yan-jie,SHI Yong-cheng,WETZEL D L.Fourier transform infrared (FT-IR) microspectroscopic census of single starch granules for octenyl succinate ester modification[J].Journal of Agricultural and Food Chemistry,2009,57(14):6443-6448.
[12] XIN Jia-ying,WANG Yan,LIU Tie,et al.Biosysthesis of corn starch palmitate by lipase Novozym 435[J].International Journal of Molecular Sciences,2012,13(12):7226-7236.
[13] HUANG Zu-qiang,LU Jian-ping,LI Xuan-hai,et al.Effect of mechanical activation on physico-chemical properties and structure of cassava starch[J].Carbohydrate Polymers,2007,68(1):128-135.

[1]	XU Jiali, ZHANG Haibo, YAO Shufeng, GAO Hong, SHANG Shibin. Research Progress of Forestry Biomass-based Film Preservatives of Fruit and Vegetable [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 10-16.
[2]	SHEN Chen, WANG Yaming, JIANG Lihong, ZHENG Yan'e, SONG Shuangshuang, LAI Qian. Preparation and Characterization of Ni-P/rGO Composite Catalysts and Their Hydrogenation Properties of Rosin [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 57-64.
[3]	CHENG Zenghui, ZHANG Daihui, WANG Jifu, WANG Chunpeng, CHU Fuxiang, XU Feng. Preparation of Monodisperse Rosin-based Polymer Microspheres by Dispersion Polymerization [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 39-45.
[4]	LUO Yunlong, SHEN Minggui, CAI Zhaosheng, SHANG Shibin, SONG Zhanqian. Synthesis and Antiviral Activity Evaluation of Dehydroabietic Acid Amide Derived 3,4-Dihydropyrimidinthiones [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 46-52.
[5]	LI Xiaohao, XIE Congxia. Preparation, Characterization and Performance for RosinHydrogenation of Pd/mpg-C₃N₄ Catalyst [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 73-80.
[6]	FENG Xiaolong, LI Xiaotong, HUANG Lingge, GUO Kai. Preparation and Properties of Ultraviolet-curing Modified Rosin Methacrylate [J]. Chemistry and Industry of Forest Products, 2018, 38(5): 45-52.
[7]	YUE Xiantian, ZENG Tao, LING Qinghua, WANG Xueyuan. Isomerization of Resin Acid Under Desorption-distillation Processes with Different Medium [J]. Chemistry and Industry of Forest Products, 2018, 38(4): 124-128.
[8]	LI Zhaoshuang, LI Jianfang, LIU He, SHANG Shibin, SONG Zhanqian. Research Progress of Biological Activity of Rosin Derivatives [J]. Chemistry and Industry of Forest Products, 2018, 38(3): 17-24.
[9]	ZHANG Haibo, JIANG Jianxin, GAO Hong, SHANG Shibin, SONG Zhanqian. Drug Release and Kinetics Properties of Rosin-based Polyacrylamide Hydrogels [J]. Chemistry and Industry of Forest Products, 2018, 38(3): 25-32.
[10]	HUANG Jing, XIAO Zhuanquan, WANG Zongde, FAN Guorong. Synthesis and Antifungal Activity of Ethylene Glycol Mono Hydronopol Ether and Its Carboxylic Ester [J]. Chemistry and Industry of Forest Products, 2018, 38(3): 103-108.
[11]	LIN Haixia, YANG Mingsheng, TIAN Chao, HAN Chunrui. Self-assembly,Mixed System and Drug-loading Research of Rosin-based Tertiary Amine Salt [J]. Chemistry and Industry of Forest Products, 2018, 38(2): 59-66.
[12]	LI Qiaoguang, LIU He, LI Jianfang, SHANG Shibin, SONG Zhanqian. Synthesis of Rosin Based Crosslinking Agent and Its Effect on Properties of Cured Silicone Rubber [J]. Chemistry and Industry of Forest Products, 2018, 38(2): 87-93.
[13]	LI Qiaoguang, LIU He, SHANG Shibin, SONG Zhanqian. Research Progress of Rosin and Its Derivatives in Polymer Synthesis [J]. Chemistry and Industry of Forest Products, 2017, 37(4): 23-29.
[14]	WU Jia, LU Youda, YANG Hui, LAI Xichen, LIN Rihui, CHEN Qiyong. Absorption of Benzopyrene by Rosin Starch Ester [J]. Chemistry and Industry of Forest Products, 2017, 37(4): 67-72.
[15]	LIU Wenzhu, TANG Kehua, LI Shuo. Prepration of Solid Base Catalyst Added with Tung Shell Ash and Its Application in Methyl Esterification of Tung Oil [J]. Chemistry and Industry of Forest Products, 2017, 37(4): 73-80.

Pretreatment of Cassava Starch and Its Effect on Enzymatic Synthesis of Rosin Starch Ester

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments