三甲基木质素季铵盐/膨润土缓释剂的制备及性能

doi:10.3969/j.issn.0253-2417.2015.05.012

Abstract

Abstract: In order to enhance the added value of lignin products, the slow release formulation based on lignin derived trimethyl quaternary ammonium salt/bentonite(L-Bt) was synthesized with using sodium-based bentonite as a raw material and trimethyl quaternary ammonium lignin (T-QL) as the modification agent. Hymexazol was selected as a simulate pesticide. The adsorption and slow release performance of L-Bt formulation for hymexazol were investigated. The structure and basal spacing of modified bentonite were analyzed by FT-IR and XRD. The results showed that quaternary ammonium ion was successfully loaded on bentonite. The modification caused the expansion of the interlayer domain of bentonite, and led to the increase of the basal spacing. The optimum adsorption conditions for hymexazol were L-0.8Bt (the T-QL dosage was 0.8 times of cation exchange capacity (CEC) of bentonite), the dosage of L-0.8Bt 0.06 g, adsorption time 10 h, mass concentration of hymexazol 500 mg/L and pH value of 4. Additionally, the effect of potion proportion and temperature on the cumulative release rate of L-0.8Bt with the maximum adsorption capacity 281 mg/g was studied by water soluble method. The result showed that Accumulative drug release rate increased gradually with the increase of loading drug ratio and temperature.

Key words: lignin derived trimethyl quaternary ammonium salt, bentonite, adsorption, hymexazol, slow release

CLC Number:

TQ35

TIAN Jin-ling, REN Shi-xue, FANG Gui-zhen. Preparation and Performance of Slow Release Formulation Based on Lignin Derived Trimethyl Quaternary Ammonium Salt/Bentonite[J]. Chemistry and Industry of Forest Products, 2015, 35(5): 71-78.

References

[1] 乔维川,洪建国,李忠正.嗜黑液菌厌氧降解过程中木质素结构的变化[J].南京林业大学学报:自然科学版,2007,31(5):34-38. QIAO Wei-chuan,HONG Jian-guo,LI Zhong-zheng.Change of lignin structure by anaerobic degradation of black-liquor-philic[J].Journal of Nanjing Forestry University:Natural Sciences Edition, 2007, 31(5): 34-38.
[2] 廖俊和,罗学刚.木质素吸附缓释性质及在肥料中的应用[J].中国土壤与肥料,2004,12(5):43-45. LIAO Jun-he,LUO Xue-gang.Absorptive and slow-released properties of lignin and its application in fertilizer[J].Soils and Fertilizers,2004,12(5):43-45.
[3] 于瑞莲.膨润土的改性及其在废水处理中的应用[J].环境技术,2003(1):18-21. YU Rui-lian.Bentonite's modifying and its application in wastewater treatment[J].Environmental Technology,2003(1):18-21.
[4] 孙洪良,朱利中.表面活性剂改性的螯合剂有机膨润土对水中有机污染物和重金属的协同吸附研究[J].高等学校化学学报,2007,28(8):1475-1479. SUN Hong-liang,ZHU Li-zhong.Simultaneous adsorption of organic pollutant and heavy metal onto surfactant-modified organobentonites with chelating ligands[J].Chemical Journal of Chinese Universities,2007,28(8):1475-1479.
[5] 任娟.有机膨润土对水中克百威的吸附研究[D].青岛:中国海洋大学硕士学位论文,2010. REN Juan.Adsorption of carbofur onto organic bentonite in water[D].Qingdao:Master Degree Thesis of Ocean University of China,2010.
[6] 董燕,孔志杰,李平高,等.有机膨润土对吡虫啉的吸附[J].广西大学学报:自然科学版,2013,38(3): 569-574. DONG Yan,KONG Zhi-jie,LI Ping-gao,et al.Adsorption characteristics of organobentonite towards imidacloprid[J].Journal of Guangxi University:Natural Sciences Edition,2013,38(3):569-575.
[7] 王通,朱润良,葛飞,等.CTMAB/CPAM复合改性膨润土吸附水中苯酚和硝基苯[J].环境科学,2010,31(2):385-389. WANG Tong,ZHU Run-liang,GE Fei,et al.Sorption of phenol and nitrobenzene in water by CTMAB/CPAM organobentonites[J].Environmental Science,2010,31(2):385-389.
[8] 姚敏.膨润土/表面活性剂一体化工艺吸附去除染化废水中的持久性有机污染物[D].杭州:浙江大学博士学位论文,2012. YAO Min.Adsorption removal of persistent organic pollutants from dyeing wastewater by bentonite/surfactant in one-step process[D].Hangzhou:Doctoral Dissertation of Zhejiang University,2012.
[9] 黄子伦,陈利标,付丽华,等.有机膨润土辛硫磷缓释剂的制备和释放研究[J].广西大学学报:自然科学版,2012,37(5) : 881-886. HUANG Zi-lun,CHEN Li-biao,FU Li-hua,et al.Controlled release of phoxim from organobentonite based ormulation[J].Journal of Guangxi University:Natural Sciences Edition,2012,37(5):881-886.
[10] GARRIDO-HERRERA F J,GONZALEZ-PRADAS E,FERNANDEZ-PEREZ M.Controlled release of isoproturon,imida-cloprid,and cyromazine from alginate-bentonite-activated carbon formulations[J]. Journal of Agricultural and Food Chemistry,2006,54(26):10053-10060.
[11] SINGH B,SHARMA D K,KUMAR R,et al.Controlled release of the fungicide thiram from starch-alginate-clay based formulation[J]. Applied Clay Science,2009,45(1/2):76-82.
[12] SINGH B,SHARMA D K,KUMAR R,et al.Controlled release of thiram from neem-alginate-clay based delivery systems to manage environmental and health hazards[J].Applied Clay Science,2010,47(3/4):384-391.
[13] 徐立恒.有机膨润土的结构调控及吸附性能研究[D].杭州:浙江大学博士学位论文,2009. XU Li-heng.Structure regulation of organobentonites and their sorption characteristics[D].Hangzhou:Doctoral Dissertation of Zhejiang University,2009.
[14] 黄子伦.膨润土基农药缓释剂的制备及其缓释性能研究[D].南宁:广西大学硕士学位论文,2012. HUANG Zi-lun.Controlled release of pesticide from an organo-bentonite based formulation[D].Nanning:Master Degree Thesis of Guangxi University,2012.
[15] 郭新锋,黎艳,王娟芳,等.几种测定膨润土阳离子交换容量方法的比较[J].计量测试与检定,2008,18(1):10-12. GUO Xin-feng,LI Yan,WANG Juan-fang,et al.Comparison of several measuring methods for bentonite cation exchange capacity[J].Metrology Test Technology and Verification,2008,18(1):10-12.
[16] 任世学.超声波活化碱木质素及多效碱木质素水处理剂合成与应用研究[D].哈尔滨:东北林业大学博士学位论文,2005. REN Shi-xue.Study on actived alkali lignin with ultrasonic process and application of multi-function water treatment agent based on alkali lignin[D].Harbin:Doctoral Dissertation of Northeast Forestry University,2005.
[17] XU S,BOYD S A.Cationic surtactant adsorption by swelling and nonswelling layer silicates[J].Langmuir,1995,11(7):2508-2514.
[18] JAYNES W F,BOYD S A.Clay mineral type and organic compound sorption by hexadecyltrimethylammonioum-exchangeed clays[J].Soil Science Society of America Journal,1991,55(1):43-48.
[19] KWOLEK T,HODOROWICZ M, STADNICHA K.Adsorption isotherms of homologous alkyldimethylbenzylammonium bromides on sodium montmorillonite[J].Journal of Colloid Interface Science,2003,264(1):14-19.
[20] ZHU Run-liang,ZHU Li-zhong,XU Li-heng.Sorption characteristics of CTMA-bentonite complexes as controlled by surfactant paching density[J].Colloid Surface A,2007,294(1):221-227.
[21] 聂锦旭.改性膨润土吸附剂的制备及其在废水处理中的应用[D].广州:中国科学院广州地球化学研究所博士学位论文,2005. NIE Jin-xu.Modified bentonite absorbent preparation and application in wastewater treatment[D].Guangzhou:Doctoral Dissertation of Guangzhou Institute of Geochemistry,Chinese Academy of Sciences,2005.
[22] 谢晶曦,常俊标,王绪明.红外光谱在有机化学和药物化学中的应用[M].北京:科学出版社,2001:316-366. XIE Jing-xi,CHANG Jun-biao,WANG Xu-ming.Application of Infrared Spectroscopy in Organic Chemistry and Medicinal Chemistry[M].Beijing: Science Press,2001:316-366.
[23] 夏旭林,古绪鹏.季胺盐改性木质素及其絮凝性能试验[J].广州化工,2010,38(4):87-89. XIA Xu-lin,GU Xu-peng.Lignin modification with quaternary ammonium salt and its flocculation tests[J].Guangzhou Chemical Industry,2010,38(4):87-89.
[24] 冯芳芳.两种介孔分子筛对恶霉灵和吡虫啉的吸附及缓释性能研究[D].临汾:山西师范大学硕士学位论文,2013. FENG Fang-fang.Two kinds of mesoporous molecular sieve for evil mildew and imidacloprid adsorption and slow-release performance study[D].Linfen:Master Degree Thesis of Shanxi Normal University,2013.

Preparation and Performance of Slow Release Formulation Based on Lignin Derived Trimethyl Quaternary Ammonium Salt/Bentonite

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