麦草碱木质素溶解性质的定量探究

doi:10.3969/j.issn.0253-2417.2018.01.004

Abstract

Abstract: For quantitative characterizing the solubility properties of wheat straw alkali lignin,the solubility parameters were measured by inverse gas chromatography (IGC) and Hansen solubility parameter (HSP) method.By IGC method,the solubility parameter (δ₂) and the related thermodynamic properties of wheat straw alkali lignin were determined in 403.15-443.15 K;wheat straw alkali lignin was used as the stationary phase,and 7 classes of 20 kinds of organic solvents,namely aliphatic,cycloaliphatic,aromatic hydrocarbons,alcohols,ketones,halohydrocarbons and tetrahydrofuran totally 7 classes of 20 kinds of organic solvents were used as the probe molecules;the δ₂ was derived as 20.09(J/cm³)^0.5 at 298.15 K by linear extrapolation and the δ₂ increased with the increase of temperature in 403.15-443.15 K.By HSP method,the solubility parameter (δ_T) was measured as 20.68(J/cm³)^0.5 at 298.15 K.The δ₂ and δ_T values were consistent by IGC and HSP method.And tetrahydrofuran,alcohols and ketones had a good trend of solving straw alkali lignin.

Key words: inverse gas chromatography, Hansen solubility parameter, straw alkali lignin, solubility parameter

CLC Number:

TQ35

NI Haiyue, REN Shixue, FANG Guizhen, MA Yanli, LIU Xiaole. Quantitative Research on Solubility Property of Straw Wheat Alkali Lignin[J]. Chemistry and Industry of Forest Products, 2018, 38(1): 25-32.

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Quantitative Research on Solubility Property of Straw Wheat Alkali Lignin

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