Chemistry and Industry of Forest Products ›› 2019, Vol. 39 ›› Issue (1): 13-22.doi: 10.3969/j.issn.0253-2417.2019.01.002
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Si LU1,2,Qiong WANG2,Xun LI1,Wei QI2,*(),Zhongming WANG2,Zhenhong YUAN2
Received:
2018-10-22
Online:
2019-02-25
Published:
2019-03-14
Contact:
Wei QI
E-mail:qiwei@ms.giec.ac.cn
Supported by:
CLC Number:
Si LU,Qiong WANG,Xun LI,Wei QI,Zhongming WANG,Zhenhong YUAN. Progress on Preparation and Application of 5-Hydroxymethylfurfural[J]. Chemistry and Industry of Forest Products, 2019, 39(1): 13-22.
Table 1
Biomass dehydration to synthetize HMF by metal chloride"
原料 raw material | 反应介质 reaction medium | 催化剂catalyst/%1) | 收率/% yield | 文献 reference | |
名称species | 加入量adding amount | ||||
葡萄糖glucose | DMA/LiBr | CrCl3 | 6% | 79 | [ |
纤维素cellulose | DMA-LiCl/[EMIM]Cl | CrCl2/HCl | 6%/6% | 54 | [ |
玉米秸秆corn stalks | DMA-LiCl/[EMIM]Cl | CrCl3/HCl | 10%/10% | 48 | [ |
葡萄糖glucose | [BMIM][Cl] | CrCl3 | 6% | 91 | [ |
葡萄糖glucose | ChCl | CrCl2 | 10% | 45 | [ |
葡萄糖glucose | H2O | ZnSO4 | 5% | 15 | [ |
果糖fructose | [BMIM]Cl | CrCl3·6H2O | 10% | 75 | [ |
果糖fructose | [C2MIM]Br | ErCl3·6H2O | 6% | 92 | [ |
果糖fructose | [BMIM]Cl | IrCl3 | 7% | 89 | [ |
纤维素cellulose | H2O-THF | AlCl3 | 40% | 37 | [ |
果糖fructose | [BMIM]Cl | NbCl5 | 20% | 79 | [ |
果糖fructose | [BMIM]Cl/DMSO | GeCl4 | 10% | 70 | [ |
果糖fructose | [BMIM]Cl | ScCl3 | 10% | 95 | [ |
琼脂糖agarose | H2O | MgCl2 | 1%a | 41 | [ |
果糖fructose | CH3NO2 | ZrCl4 | 10% | 73 | [ |
菊粉inulin | CH3NO2 | ZrCl4 | 10% | 74 | [ |
葡萄糖glucose | KBr/MeCN | CrCl3·6H2O | 10% | 50 | [ |
葡萄糖glucose | CPME/H2O | AlCl3/HClb | 2.5% | 55 | [ |
甘露糖mannose | DMSO/H2O | AlCl3·6H2O | 10% | 60 | [ |
Table 2
Biomass dehydration to synthetize HMF by solid acid"
催化剂类型 catalyst type | 催化剂catalyst1) | 原料 raw material | 反应介质 reaction medium | 收率/% yield | 文献 reference | |
名称species | 加入量adding amount | |||||
离子交换树脂 ion exchange resin | Amberlyst-15 | 1% | 菊粉inulin | [BMIM]HSO4/ [BMIM]Cl | 82 | [ |
D001-cc | 100% | 果糖fructose | [BMIM]Cl | 93 | [ | |
Aquivion@SiO2 | 53% | 果糖fructose | DMSO | 85 | [ | |
分子筛 molecular sieve | Taa-SBA-15 | 3.30% | 果糖fructose | H2O | 49 | [ |
Sn-Betaa/HClb | 200% | 葡萄糖glucose | H2O/THF/NaCl | 72 | [ | |
Sn-Beta/HClb | 3.50% | 淀粉starch | H2O/THF/NaCl | 69 | [ | |
H-ZSM-5 | 200% | 微晶纤维素MCC | H2O | 46 | [ | |
SBA-15-SO3H | 200% | 果糖fructose | DMSO | 96 | [ | |
碳基固体酸 carbon-based solid acid | Glu-TsOH | 125% | 果糖fructose | DMSO | 91 | [ |
CNT-PSSA | 10% | 果糖fructose | DMSO | 89 | [ | |
LCC | 10% | 果糖fructose | DMSO/[BMIM]Cl | 84 | [ | |
碳基固体酸CS | 20% | 果糖fructose | DMSO | 90 | [ | |
SPAN | 33% | 果糖fructose | H2O/DX | 71 | [ | |
C2-SO3H | 50% | 果糖fructose | DMSO | 87 | [ | |
金属氧化物及其络合物 metal oxides and complexes | 介孔TiO2 | 50% | 果糖fructose | DMA-LiCl/ [BMIM]Cl | 82 | [ |
Al2O3-B2O3 | 40% | 葡萄糖glucose | DMSO | 41 | [ | |
B2O3/ZrO2-Al2O3 | 40% | 葡萄糖glucose | DMSO | 41 | [ | |
超强酸 superacid | SO42-/ZrO2-Al2O3 | 6% | 淀粉starch | DMSO/H2O | 55 | [ |
SO42-/ZrO2-TiO2 | 50% | 葡萄糖glucose | H2O/NBA | 26 | [ | |
AgSTA | 10% | 果糖fructose | 过热水 superheated water | 86 | [ | |
AgSTA | 10% | 蔗糖sucrose | 过热水 superheated water | 63 | [ | |
SiO2-ATS-PTA | 100% | 葡萄糖glucose | CP/H2O | 78 | [ |
Table 3
Production of HMF from biomass by dilute acid organic solvent system"
底物 substrate | 水固比 water-solid ratio | 催化剂 catalyst | 有机相 organic phase | 收率/% yield | 文献 reference |
枫木maple | 20:1 | H2SO4 | MIBK/两相biphase | 36 | [ |
枫木maple | 5:1 | H2SO4 | THF/均相homogeneous | 21 | [ |
枫木maple | 4:1 | 金属盐metal salt/H2SO4 | THF/均相homogeneous | 51 | [ |
玉米秸秆corn stalks | 4:1 | 金属盐metal salt/H2SO4 | THF/均相homogeneous | 45 | [ |
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