含氮杂环桐油基硬质聚氨酯泡沫塑料的制备及性能表征

doi:10.3969/j.issn.0253-2417.2019.02.008

Abstract

Abstract:

Nitrogen-containing heterocyclic tung oil-based polyol (PTOT) was synthesized by the ring opening reaction between epoxidized eleostearic acid monoglyceride (EGTO) and 1, 3, 5-tris(2-hydroxyethyl) isocyanurate (THEIC). PTOT was used to substitute part of phthalic anhydride polyester polyol (PAPP) to prepare rigid polyurethane foam(RPUF). FT-IR, ¹H NMR, TG and universal testing machine were employed to characterize the chemical structure and the properties of the products. It can conclude that PTOT was obtained by the ring opening reaction, and the hydroxyl value and viscosity (25 ℃), acid value and moisture of PTOT were 378.42 mg/g and 1.84 Pa·s, respectively. The acid value was lower than 0.8 mg/g and the moisture was lower than 0.1%.With the increase of PTOT substitution amount, the limiting oxygen index (LOI) of the RPUF was increased while the compressive strength and thermal stability were decreased. When the amount of PTOT increased from 0 to 100%, the LOI increased from 19.7% to 23.0%, the compression strength decreased from 0.85 MPa to 0.59 MPa and the initial degradation temperature decreased from 276.0 ℃ to 273.5 ℃, respectively. The introduction of an appropriate amount of cellulose into RPUF could enhance the mechanical strength and retain its flame retardancy and thermal stability without lowering.

Key words: tung oil, 1, 3, 5-tris(2-hydroxyethyl) isocyanurate, rigid polyurethane foam, flame retardant, cellulose

CLC Number:

TQ35

Wei ZHOU,Puyou JIA,Meng ZHANG,Yonghong ZHOU. Preparation and Characterization of Nitrogen-containing Heterocyclic Tung Oil-based Rigid Polyurethane Foam[J]. Chemistry and Industry of Forest Products, 2019, 39(2): 53-58.

Figures/Tables 8

Fig.1

Table 1

Fig.2

Fig.3

Table 2

Fig.4

Fig.5

Table 3

References 12

1	李澜鹏, 白富栋, 乔凯, 等. 桐油多元醇的合成研究[J]. 中国油脂, 2016, 41 (12): 69- 72. doi: 10.3969/j.issn.1003-7969.2016.12.015
	LI L P , BAI F D , QIAO K , et al. Synthesis of tung oil based polyol[J]. China Oils and Fats, 2016, 41 (12): 69- 72. doi: 10.3969/j.issn.1003-7969.2016.12.015
2	李秀峥, 李澜鹏, 曹长海, 等. 植物油多元醇的研究及商业化应用进展[J]. 聚氨酯工业, 2018, 33 (2): 1- 4. doi: 10.3969/j.issn.1005-1902.2018.02.001
	LI X Z , LI L P , CAO C H , et al. Advances in research and commercial application of vegetable oil polyols[J]. Polyurethane Industry, 2018, 33 (2): 1- 4. doi: 10.3969/j.issn.1005-1902.2018.02.001
3	姜志国, 刘红梅, 李效玉. 植物油多元醇改性硬质聚氨酯泡沫性能的研究[J]. 聚氨酯工业, 2007, 22 (6): 22- 25. doi: 10.3969/j.issn.1005-1902.2007.06.006
	JIANG Z G , LIU H M , LI X Y . Study on properties of rigid polyurethane foam modified by vegetable oil polyol[J]. Polyurethane Industry, 2007, 22 (6): 22- 25. doi: 10.3969/j.issn.1005-1902.2007.06.006
4	贺舍予, 钟海雁, 金超, 等. 桐油主要脂肪酸定量分析方法的构建及其应用[J]. 中南林业科技大学学报, 2014, 10 (5): 83- 87. doi: 10.3969/j.issn.1673-923X.2014.05.018
	HE S Y , ZHONG H Y , JIN C , et al. Study and application of quantitative analysis of fatty acid of tung oil[J]. Journal of Central South University of Forestry & Technology, 2014, 10 (5): 83- 87. doi: 10.3969/j.issn.1673-923X.2014.05.018
5	李静, 蒋剑春, 徐俊明. 油酸基多元醇的制备及其在硬质聚氨酯泡沫中的应用研究[J]. 化工新型材料, 2011, 39 (6): 115- 117. doi: 10.3969/j.issn.1006-3536.2011.06.036
	LI J , JIANG J C , XU J M . Preparation of oleic acid-based polyol and its application in polyurethane rigid foam[J]. New Chemical Materials, 2011, 39 (6): 115- 117. doi: 10.3969/j.issn.1006-3536.2011.06.036
6	SHI X X , JIANG S H , ZHU J Y , et al. Establishment of a highly efficient flame-retardant system for rigid polyurethane foams based on bi-phase flame-retardant actions[J]. RSC Advances, 2018, 8 (18): 9985- 9995. doi: 10.1039/C7RA13315D
7	刘贺, 刘春霞, 马凤国. 阻燃型聚氨酯的研究进展[J]. 合成材料老化与应用, 2017, 46 (5): 113- 119.
	LIU H , LIU C X , MA F G . Research progress in flame-retardant polyurethane[J]. Synthetic Materials Aging and Application, 2017, 46 (5): 113- 119.
8	ZHOU X J , SAIN M M , OKSMAN K . Semi-rigid biopolyurethane foams based on palm-oil polyol and reinforced with cellulose nanocrystals[J]. Composites Part A:Applied Science & Manufacturing, 2016, 83, 56- 62.
9	邓月娥, 牛立元, 孙素琴. 植物油红外光谱特性分析[J]. 河南科技学院:自然科学版, 2005, 25 (3): 66- 69.
	DENG Y E , NIU L Y , SUN S Q . Analysis of the FT-IR spectroscopy characteristic of plant oil[J]. Journal of Henan Institute of Science and Technology, 2005, 25 (3): 66- 69.
10	赵祖兵, 张旭玲, 曾繁涤. 含三嗪环的酸酐固化剂合成及其环氧固化物性能研究[J]. 中国胶粘剂, 2007, 16 (10): 17- 19. doi: 10.3969/j.issn.1004-2849.2007.10.005
	ZAO Z B , ZHANG X L , ZEN F D . Synthesis for a anhydride curing agent of THEIC contained and properties research on epoxy hardener[J]. China Adhesives, 2007, 16 (10): 17- 19. doi: 10.3969/j.issn.1004-2849.2007.10.005
11	白斌, 周卫红, 丁毅飞, 等. 纤维素热解动力学分析方法研究[J]. 生物质化学工程, 2017, 51 (4): 8- 16. doi: 10.3969/j.issn.1673-5854.2017.04.002
	BAI B , ZHOU W H , DING Y F , et al. Analysis method of cellulose pyrolysis dynamics[J]. Biomass Chemical Engineering, 2017, 51 (4): 8- 16. doi: 10.3969/j.issn.1673-5854.2017.04.002
12	林梦霞, 邹萍萍, 张萍, 等. PLA/NCC微孔泡沫材料发泡性能研究[J]. 工程塑料应用, 2013, 41 (10): 90- 95. doi: 10.3969/j.issn.1001-3539.2013.10.022
	LIN M X , ZOU P P , ZHANG P , et al. Study on foaming properities of PLA/NCC microcellular foam material[J]. Engineering Plastics Application, 2013, 41 (10): 90- 95. doi: 10.3969/j.issn.1001-3539.2013.10.022

试样 samples	PAPP/g	PTOT/g	PAPI/g	纤维素/g cellulose	泡沫稳定剂/g foam stabilizer	催化剂/g catalyst	发泡剂/g foam agent	水/g water
P-1	100	0	115	0	4.00	0.06	20	0.06
P-2	60	40	115	0	4.00	0.06	20	0.06
P-3	0	100	115	0	4.00	0.06	20	0.06
P-4	60	40	115	2.85	4.00	0.06	20	0.06
P-5	60	40	115	5.71	4.00	0.06	20	0.06

试样 samples	压缩强度/MPa compressive strength	导热系数/(W·m^-1·K^-1) thermal conductivity	密度/(kg·m^-3) density
P-1	0.85	0.053	97.25
P-2	0.64	0.050	95.08
P-3	0.59	0.050	94.02
P-4	0.69	0.051	96.46
P-5	0.87	0.053	98.86

试样 samples	T_onset/℃	D_max/(%·min^-1)		T_max/℃		残炭率/% residue rate
试样 samples	T_onset/℃	第二阶段 the second stage	第三阶段 the third stage	第二阶段 the second stage	第三阶段 the third stage	残炭率/% residue rate
P-1	276.0	4.84	1.77	302.6	498.3	25.14
P-2	272.2	3.99	2.57	311.1	467.9	20.72
P-3	273.5	3.68	4.01	328.9	425.8	10.46
P-4	271.9	3.96	2.40	305.5	468.2	23.43
P-5	270.4	3.81	2.34	304.5	465.7	23.41

[1]	XING Jianxiong, ZHENG Kai, HAN Zunqiang, XU Weitao, WANG Kun. Research Progress on Application of Cellulose-based Materials as Electrode in Flexible Supercapacitor [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 9-17.
[2]	CHEN Jinwei, WANG Dan, SHANG Shibin, LIU He, CAI Zhaosheng. Preparation of Amino-terminated Hyperbranched Polymer Grafted Dialdehyde-based Nanocellulose and Its Adsorption Properties of Ni²⁺ [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 18-26.
[3]	CHEN Yan, WANG Zixin, LI Qizhen, XIA Jianyu, LIU Zhulan, CAO Yunfeng. Synthesis and Characterization of Lignocellulose Oil-absorbing Aerogels [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 49-55.
[4]	XIONG Mingcheng, WANG Zi, YAN Yuxin, ZHENG Yanling, XIAO Zhenzhen, LU Qilin, HUANG Biao. Preparation of Nanocrystalline Cellulose by the Catalytic Hydrolysis of Pulp with p-Toluenesulfonic Acid Under Ultrasonication [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 72-76.
[5]	ZHAN Manjun, CHEN Zhilin, CHU Fuxiang. Effect of Hybrid Flame Retardant on Properties of Formaldehyde-free Ultra-low Density Fiberboard [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 87-93.
[6]	CHEN Chao, WANG Ao, SUN Kang, LU Xincheng, XU Wei, JIANG Jianchun. Graphitization of Biomass Catalyzed by Ni [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 94-100.
[7]	YU Yun, YANG Ningning, HUANG Bin, YANG Yan, LIAO Youwei. Preparation of High-efficient Tung Oil Drier and Its Drying Performance [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 101-107.
[8]	LI Yanqing, LIU Zhiming, CHENG Xiaokai, CAO Mengnan, WANG Jianan. Preparation and Performance Characterization of Sodium Alginate/Cellulose Composite Microspheres [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 67-72.
[9]	YIN Wenzhang, LI Jianqiang, XU Zhengmao, ZHANG Chunhui. Preparation of Micro-nanocellulose from Low Quality Fiber [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 89-95.
[10]	LU Chuanwei, WANG Chunpeng, CHU Fuxiang, WANG Jifu. Preparation and Characterization of Cellulose-fattyacid-furfural Derived Thermoplastic Elastomer via ATRP [J]. Chemistry and Industry of Forest Products, 2019, 39(1): 75-80.
[11]	CHEN Jinwei, SHANG Shibin, SHEN Minggui, WANG Dan, FU Fei, CAI Zhaosheng. Preparation of Amino Acid-terminated Nanocellulose and Adsorption Properties of Pb(Ⅱ) [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 11-19.
[12]	SONG Ruyuan, ZHAO Luyang, XIA Zihua, WU Weibing, JING Yi, DAI Hongqi. Preparation and Optical Properties of Fluorescent Probes Based on Cellulose Nanocrystals [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 51-58.
[13]	SHI Chun, LI Tiancheng, YANG Jing, YANG Haiyan, DENG Jia, SHI Zhengjun. Preparation and Characterization of Cellulose Acetate Films Derived from Bamboo [J]. Chemistry and Industry of Forest Products, 2018, 38(5): 70-76.
[14]	CHEN Zishu, ZHAO Zixuan, ZHANG Shaomeng, REN Hongwei. Effect of Hydrogen Bonding of Ammonium-based Deep Eutectic Solvents on Cellulose Dissolution [J]. Chemistry and Industry of Forest Products, 2018, 38(5): 93-99.
[15]	YING Wenjun, WU Kai, SHI Zhengjun, YANG Haiyan, ZHENG Zhifeng, YANG Jing. Pretreatment of Corn Cob by the Combination of H₃PO₄-H₂O₂ and Their Effect on Enzymatic Hydrolysis Efficiency [J]. Chemistry and Industry of Forest Products, 2018, 38(5): 100-106.

Preparation and Characterization of Nitrogen-containing Heterocyclic Tung Oil-based Rigid Polyurethane Foam

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 8

References 12

Related Articles 15

Recommended Articles

Metrics

Comments