Chemistry and Industry of Forest Products ›› 2019, Vol. 39 ›› Issue (3): 34-42.doi: 10.3969/j.issn.0253-2417.2019.03.005
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Shiqi LIU,Suping ZHANG*(),Taili YU,Qinjie CAI
Received:
2019-02-28
Online:
2019-06-28
Published:
2019-06-26
Contact:
Suping ZHANG
E-mail:zsp@ecust.edu.cn
Supported by:
CLC Number:
Shiqi LIU,Suping ZHANG,Taili YU,Qinjie CAI. Synergistic Effect of Co-pyrolysis of Biomass and Plastics[J]. Chemistry and Industry of Forest Products, 2019, 39(3): 34-42.
Table 2
Components of bio-oil from sawdust/LDPE at different temperature"
编号 No. | 组分 component | GC含量GC content/% | ||
500 ℃ | 600 ℃ | 700 ℃ | ||
1 | 十一烷undecane | — | 2.48 | 7.19 |
2 | 正十二烷dodecane | — | — | 8.33 |
3 | 环十二烷cyclododecane | — | — | 5.61 |
4 | 正十四烷tetradecane | — | — | 6.17 |
5 | 正十六烷hexadecane | 5.5 | 7.76 | — |
6 | 环十六烷cyclohexadecane | 5.47 | 2.31 | — |
7 | 正十九烷nonadecane | 12.24 | 11.39 | 1.89 |
8 | 1-十一烯1-undecene | — | — | 5.05 |
9 | 1-十二烯1-dodecene | — | — | 9.51 |
10 | 十四烯tetradecene | — | — | 3.13 |
11 | 十八烯octadecene | 3.64 | — | — |
12 | 1-二十二烯1-docosene | 4.23 | — | — |
13 | 乙酸acetic acid | 8.93 | 7.70 | 5.23 |
14 | 乙酸甲酯acetic acid, methyl ester | 3.31 | 4.24 | 1.59 |
15 | 糠醇2-furanmethanol | 1.50 | 1.64 | — |
16 | 愈创木酚2-methoxy-phenol | 4.11 | 4.43 | 2.70 |
17 | 2-甲氧基-4-甲基苯酚2-methoxy-4-methyl-phenol | 2.77 | 2.93 | 2.86 |
18 | 4-乙基愈创木酚4-ethyl-2-methoxy-phenol | 2.18 | 1.66 | 2.02 |
19 | 4-甲基愈创木酚2-methoxy-4-methyl-phenol | 3.81 | 5.62 | 3.86 |
20 | 邻苯二酚1, 2-benzenediol | 1.68 | 1.91 | — |
21 | 2-辛基苯酚2-octyl-phenol | — | 0.93 | 1.51 |
22 | 苯酚phenol | 3.51 | 4.60 | 2.43 |
23 | 2, 6-二甲氧基苯酚2, 6-dimethoxy-phenol | 1.37 | 1.07 | 0.95 |
24 | 对甲酚4-methyl-phenol | 0.95 | 1.52 | 1.97 |
25 | γ-丁内酯γ-butyrolactone | 0.97 | 0.91 | — |
26 | 2-甲氧基-4-(1-丙烯基)苯酚2-methoxy-4-(1-propenyl)-phenol | — | 1.28 | 1.02 |
27 | 乙酰氧基丙酮1-acetyloxy-2-propanone | 1.87 | 1.50 | 0.95 |
28 | 甲基环戊烯醇酮methyl cyclopentenolone | 2.03 | 1.62 | — |
29 | 3-呋喃甲醇3-furanmethanol | 1.40 | 3.05 | — |
30 | 丙酸propanoic acid | 0.90 | — | — |
31 | 十一醇undecanol | 1.52 | 2.09 | 1.21 |
32 | 十三烷醇n-tridecanol | 2.14 | 2.91 | 1.86 |
33 | 2-庚烯醛2-heptenal | 2.95 | — | — |
34 | 1-十七烷醇1- n-heptadecanol | 4.25 | 9.00 | 2.19 |
35 | 十二醛dodecanal | 2.81 | — | — |
36 | 十三烷醇n-tridecanol | — | — | 2.51 |
37 | 1-十六烷醇1-hentetracontanol | — | — | 2.78 |
38 | 十八醛octadecenal | 8.89 | 13.15 | 3.06 |
39 | 3, 7-二甲基-1-辛醇3, 7dimethyl-1-octanol | 1.04 | — | 2.04 |
40 | 2-甲基丁二酸环己基酯2-methyl butanoic acid cyclohexyl ester | 1.34 | 1.38 | 1.73 |
41 | 1, 4-丁二醇二乙酸酯1, 4-diacetate butandiol | 1.19 | 0.92 | 0.85 |
42 | 6-甲基-2-庚基乙酸酯6-methyl-2-heptanol acetate | — | — | 1.81 |
43 | 十八烷基环戊二烯酸octadecyl cyclopentadienoic acid | — | — | 0.92 |
44 | 环扁桃酯cyclandelate | — | — | 2.56 |
45 | 2-丁基四氢呋喃2-butyltetrahydro-furan | — | — | 1.06 |
46 | 2-羟基-5-甲基苯乙酮2-hydroxy-5-methylphenyl-ethanone | — | — | 1.46 |
47 | 四氢糠醇2-tetrahydro-furanmethanol | 2.11 | — | — |
Table 3
Bio-oil component of lignin at 500 ℃"
组分 component | GC含量/% GC content |
愈创木酚2-methoxyphenol | 34.7 |
4-羟基-3-甲氧基苯甲醛vanillin | 11.7 |
4-羟基-3-甲氧基苯乙酮apocynin | 6.99 |
4-乙烯基-2-甲氧基苯酚2-methoxy-4-vinylphenol | 6.82 |
4-甲基愈创木酚creosol | 4.65 |
(E)-2-甲氧基-4-(1-丙烯基苯酚)trans-isoeugenol | 3.98 |
4-羟基-3-甲氧基苯丙酮1-(4-hydroxy-3-methoxyphenyl)- 2-propanone | 3.74 |
4-乙基愈创木酚4-ethyl-2-methoxyphenol | 3.31 |
苯酚phenol | 3.14 |
邻苯二甲醚1, 2-dimethoxybenzene | 3.08 |
2-甲氧基-6-甲基苯酚2-methoxy-6-methylphenol | 3.01 |
4-羟基-3-甲氧基苯乙酸homovanillic acid | 2.44 |
2-甲基苯酚2-methyl-phenol | 2.31 |
2-甲氧基-4-丙基-苯酚2-methoxy-4-propylphenol | 2.1 |
4((1E)-羟基-1-丙烯基)-2-甲氧基苯酚 4-((1E)-hydroxy-1-propenyl)-2-methoxy phenol | 1.97 |
2,4-二甲氧基苯乙酮2, 4-dimethoxyacetophenone | 1.84 |
4-甲基苯酚p-cresol | 1.74 |
3, 4-二甲氧基苯甲醛3, 4-dimethoxy-benzaldehyde | 1.6 |
4-乙氧基-3-甲氧基苯甲醛4-ethoxy-3-anisaldehyde | 0.73 |
Table 4
Bio-oil components of hemicellulose and cellulose at 500 ℃"
半纤维素热解油bio-oil of hemicellulose | |
组分 component | GC含量/% GC content |
2, 2-二乙基-3-甲基-恶唑烷 2, 2- diethyl-3-methyl-oxazolidine | 13.39 |
3, 4-二氢-6-羟基-2H-1-苯并吡喃-2-酮 3, 4-dihydro-6-hydroxy-2H-1-benzopyran-2-one | 12.51 |
1-羟基-2-丁酮1-hydroxybutan-2-one | 10.77 |
1-戊烯-3-醇1-penten-3-ol | 9.27 |
糠醛furfural | 9.14 |
1, 3-二氧杂环戊烯-2-酮 1, 3-dioxol-2-one | 6.71 |
4-甲基-5-(2-氧代亚丙基)呋喃-2-酮 4-methyl-5-(2-oxo-propylidene)furan-2-one | 5.15 |
甲酸formic acid | 4.62 |
3-甲基-2-羟基-2-环戊烯酮 3-hydroxy-2-methyl-1-2-cyclopenten-1-one | 3.62 |
5-甲基-2(3H)-呋喃酮5-methyl-2(3H)-furanone | 3.47 |
1-乙基-4-甲基环己烷1-ethyl-4-methylcyclohexane | 3.12 |
1, 2-环氧-2-甲基丁烷1, 2-epoxy-2-methylbutane | 2.96 |
乙酸acetic acid | 2.88 |
2, 3-二羟基苯甲醛2, 3-dihydroxybenzaldehyde | 2.29 |
邻苯二酚catechol | 1.84 |
6-甲基二氢-2H-吡喃-3(4H)-酮 6-methyl dihydro-2H-pyran-3(4H)-one | 1.78 |
糠醇2-furanylmethanol | 1.71 |
2-氧代丁酸甲酯2-oxo-butanoic acid methyl ester | 1.68 |
乙二醛glyoxal | 1.47 |
D-阿洛糖D-allose | 81.7 |
1, 6-脱水-β-D-呋喃葡萄糖 1, 6-anhydro-beta-D-glucofuranose | 5.68 |
2-乙烯基-4-甲基-1, 3-二氧戊环 2-ethenyl-4-methyl-1, 3-dioxolane | 3.15 |
左旋葡萄糖酮levoglucosenone | 1.41 |
5-壬酮5-nonanone | 1.16 |
3-乙基-哌啶-2, 6-二酮3-ethyl-piperidine-2, 6-dione | 0.93 |
糠醛furfural | 0.86 |
氰基甲酸乙酯carbonocyanidic acid, ethyl ester | 0.72 |
恶唑烷2, 2-二乙基-3-甲基2, 2-diethyl-3-methyl oxazolidine | 0.57 |
5-甲基呋喃醛5-methyl-2-furaldehyde | 0.38 |
1, 6-脱水-β-D-葡萄糖1, 6-anhydro-β-D-glucopyranose | 0.37 |
2, 5-呋喃二甲醛2, 5-furandicarbaldehyde | 0.34 |
乙烯基甲醚methoxy-ethene | 0.33 |
异丁烯2-methyl-1-propene | 0.25 |
2(5H)-呋喃酮2(5H)-furanone | 0.15 |
5-甲基-2(3H)-呋喃酮5-methyl-2(3H)-furanone | 0.15 |
1, 2, 5, 6-四氢吡啶1, 2, 5, 6-tetrahydropyridine | 0.15 |
1-(2-亚甲基环丙基)乙酮 1-(2-methylidenecyclopropyl)ethanone | 0.14 |
甲基环戊烯醇酮methyl cyclopentenolone | 0.07 |
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