生物质焦油模型化合物脱除研究进展

doi:10.3969/j.issn.0253-2417.2019.04.001

Abstract

Abstract:

The tar formed in the process of biomass gasification not only reduces the utilization rate of biomass energy while increasing the maintenance cost of system, but also affects the long-term stable operations of gasification system seriously. How to effectively remove the tar from gasification process has become an urgent problem for researchers. As the ingredients of biomass tar is very complex, it is of great importance to select appropriate model compounds that represent the characteristics of tar. Starting from the pyrolysis mechanism of the typical tar model compounds for, the removal pathways of tar model compounds are reviewed from experimental research and theoretical calculation. The reaction mechanism of tar catalytic cracking is summarized with transition metal catalyst as representative. Afterwards, the latest research progress in catalysts and plasma treatment of tar is reviewed and their characteristics are concluded. Finally, the prospect of technologies for efficient tar removal in future is discussed.

Key words: biomass tar, model compound, catalytic decomposition, plasma method

CLC Number:

TQ35

Shuai MA,Xiaoying HU,Changqing DONG,Ying ZHAO,Xiaoqiang WANG,Jin ZHAO. Research Progress in the Removal of Biomass Tar Model Compounds[J]. Chemistry and Industry of Forest Products, 2019, 39(4): 1-8.

Figures/Tables 3

References 56

1	王夺, 刘运权. 生物质气化技术及焦油裂解催化剂的研究进展[J]. 生物质化学工程, 2012, 46 (2): 39- 47. doi: 10.3969/j.issn.1673-5854.2012.02.007
	WANG D , LIU Y Q . Research progress of biomass gasification technology and tar cracking catalyst[J]. Biomass Chemical Engineering, 2012, 46 (2): 39- 47. doi: 10.3969/j.issn.1673-5854.2012.02.007
2	吴悠, 赵立欣, 孟海波, 等. 生物质热解焦油脱除方法研究进展[J]. 化工环保, 2016, 36 (1): 17- 21. doi: 10.3969/j.issn.1006-1878.2016.01.004
	WU Y , ZHAO L X , MENG H B , et al. Research progress on removal methods of biomass pyrolysis tar[J]. Chemical Environmental Protection, 2016, 36 (1): 17- 21. doi: 10.3969/j.issn.1006-1878.2016.01.004
3	杨修春, 韦亚南, 李伟捷. 焦油裂解用催化剂的研究进展[J]. 化工进展, 2007, 26 (3): 326- 330. doi: 10.3321/j.issn:1000-6613.2007.03.006
	YANG X C , WEI Y N , LI W J . Research progress of catalysts for tar cracking[J]. Chemical Progress, 2007, 26 (3): 326- 330. doi: 10.3321/j.issn:1000-6613.2007.03.006
4	郭秀兰, 黄鹤, 周强, 等. 生物质焦油裂解催化剂研究进展[J]. 可再生能源, 2004, (01): 9- 13. doi: 10.3969/j.issn.1671-5292.2004.01.005
	GUO S L , HUANG H , ZHOU Q , et al. Research progress of biomass tar cracking catalyst[J]. Renewable Energy, 2004, (01): 9- 13. doi: 10.3969/j.issn.1671-5292.2004.01.005
5	GUAN G , KAEWPANHA M , HAO X , et al. Catalytic steam reforming of biomass tar:Prospects and challenges[J]. Renewable and Sustainable Energy Reviews, 2016, 58, 450- 461. doi: 10.1016/j.rser.2015.12.316
6	DEUTSCH B S , KRIEGER K A . Free radicals from the decomposition of toluene and butane-1[J]. The Journal of Physical Chemistry, 1962, 66 (9): 1569- 1573. doi: 10.1021/j100815a001
7	王惠, 杨海峰, 冉新权, 等. 甲苯热解机理的AM1研究(Ⅰ)热力学分析[J]. 无机化学学报, 2001, 17 (4): 538- 544. doi: 10.3321/j.issn:1001-4861.2001.04.014
	WANG H , YANG H F , RAN X Q , et al. AM1 thermodynamic research of the pyrolysis mechanism of toluene(Ⅰ)[J]. Chinese Journal of Inorganic Chemistry, 2001, 17 (4): 538- 544. doi: 10.3321/j.issn:1001-4861.2001.04.014
8	陈桂梅, 张香文, 米镇涛. 压力对USY催化甲苯裂解结焦及其前驱体的影响[J]. 燃料化学学报, 2007, 35 (2): 211- 216. doi: 10.3969/j.issn.0253-2409.2007.02.016
	CHEN G M , ZHANG S W , MI Z T . Effect of pressure on USY catalytic toluene cracking coking and its precursor[J]. Journal of Fuel Chemistry and Technology, 2007, 35 (2): 211- 216. doi: 10.3969/j.issn.0253-2409.2007.02.016
9	SUH I , ZHANG D , ZHANG R , et al. Theoretical study of OH addition reaction to toluene[J]. Chemical Physics Letters, 2002, 364 (5/6): 454- 462.
10	贾建波, 曾凡桂, 李美芬, 等. 用密度泛函理论研究煤中甲基苯生成甲烷的反应机理[J]. 化工学报, 2010, 61 (12): 3235- 3242.
	JIA J B , ZENG F G , LI M F , et al. study on the reaction mechanism of methyl benzene producing methane in coal by density functional theory[J]. Journal of Chemical Engineering, 2010, 61 (12): 3235- 3242.
11	HUANG H B , YE D Q , LEUNG D Y C , et al. Byproducts and pathways of toluene destruction via plasma-catalysis[J]. Journal of Molecular Catalysis A:Chemical, 2011, 336 (1/2): 87- 93.
12	孙萌.镍催化的碳-碳健活化及脱羧环化反应研究[D].兰州:兰州大学, 2013.
	SUN M.Study on carbon-carbon health activation and desorption of nickel catalyzed[D]. Lanzhou: Lanzhou University, 2013.
13	占贝贝, 刘斌, 胡芳. 镍催化惰性碳氢键活化研究进展[J]. 科学通报, 2015, 60 (31): 2907- 2917.
	ZHAN B B , LIU B , HU F . Research progress of nickel catalytic inert carbon hydrogen bond activation[J]. Scientific bulletin, 2015, 60 (31): 2907- 2917.
14	郑丹丹, 陆爱兰, 王艳. 过渡金属催化碳-氢键活化反应的研究进展[J]. 广州化工, 2013, 41 (4): 5- 8, 18. doi: 10.3969/j.issn.1001-9677.2013.04.003
	ZHENG D D , LU A L , WANG Y . Research progress of catalytic carbon-hydrogen bond activation reaction by transition metals[J]. Guangzhou Chemical, 2013, 41 (4): 5- 8, 18. doi: 10.3969/j.issn.1001-9677.2013.04.003
15	LUO X L , BAI R P , LIU S , et al. Mechanism of rhodium-catalyzed formyl activation:A computational study[J]. The Journal of Organic Chemistry, 2016, 81, 2320- 2326. doi: 10.1021/acs.joc.5b02828
16	GARBARINO G , WANG C Y , VALSAMAKIS I , et al. A study of Ni/Al₂O₃ and Ni-La/Al₂O₃ catalysts for the steam reforming of ethanol and phenol[J]. Applied Catalysts B:Environmental, 2015, 174, 21- 34.
17	ZOU X , MA Z , LIU H , et al. Green synthesis of Ni supported hematite catalysts for syngas production from catalytic cracking of toluene as a model compound of biomass tar[J]. Fuel, 2018, 217, 343- 351. doi: 10.1016/j.fuel.2017.12.063
18	KAISALO N , KIHLMAN J , HANNULA I . Reforming solutions for biomass-derived gasification gas:Experimental results and concept assessment[J]. Fuel, 2015, 147, 208- 220. doi: 10.1016/j.fuel.2015.01.056
19	KAISALO N.Tar reforming in biomass gasification gas cleaning[D]. Helsinki: Aalto University, 2017.
20	ARTEXE M , ALVAREZ J , NAHIL M A , et al. Steam reforming of different biomass tar model compounds over Ni/Al₂O₃ catalysts[J]. Energy Conversion Management, 2017, 136, 119- 126. doi: 10.1016/j.enconman.2016.12.092
21	KAISALO N , SIMELL P , LEHTONEN J . Benzene steam reforming kinetics in biomass gasification gas cleaning[J]. Fuel, 2016, 182, 696- 703. doi: 10.1016/j.fuel.2016.06.042
22	KOIKE M , LI D , WATANABE H , et al. Comparative study on steam reforming of model aromatic compounds of biomass tar over Ni and Ni-Fe alloy nanoparticles[J]. Applied Catalgsis A:General, 2015, 506, 151- 162. doi: 10.1016/j.apcata.2015.09.007
23	刘子姣, 芦晓芳. 生物质焦油裂解用催化剂研究进展[J]. 资源节约与环保, 2014, (10): 66- 67.
	LIU Z J , LU X F . Research progress of catalysts for biomass tar cracking[J]. Resource conservation and Environmental protection, 2014, (10): 66- 67.
24	DONG H H , LEE R H , WANG J H , et al. The effect of addition of Ca, K and Mn over Ni-based catalyst on steam reforming of toluene as model tar compound[J]. Catal Today, 2016, 265, 95- 102. doi: 10.1016/j.cattod.2015.09.057
25	SHEN C , ZHOU W , YU H , et al. Ni nanoparticles supported on carbon as efficient catalysts for steam reforming of toluene(model tar)[J]. Chinese Journal of Chemical Engineering, 2018, 26 (2): 322- 329. doi: 10.1016/j.cjche.2017.03.028
26	BLANCO P H , WU C , ONWUDILI J A , et al. Characterization and evaluation of Ni/SiO₂ catalysts for hydrogen production and tar reduction from catalytic steam pyrolysis-reforming of refuse derived fuel[J]. Applied Catalysis B:Environmental, 2013, 134/135, 238- 250. doi: 10.1016/j.apcatb.2013.01.016
27	TUOMI S , KURKELA E , SIMELL P , et al. Behavior of tars on the filter in high temperature filtration of biomass-based gasification gas[J]. Fuel, 2015, 139, 220- 231. doi: 10.1016/j.fuel.2014.08.051
28	KORUS A , SAMSON A , SZLE A , et al. Pyrolytic toluene conversion to benzene and coke over activated carbon in a fixed-bed reactor[J]. Fuel, 2017, 207, 283- 292. doi: 10.1016/j.fuel.2017.06.088
29	NESTLER F , BURHENNE L , AMTENBRINK M J , et al. Catalytic decomposition of biomass tars:The impact of wood char surface characteristics on the catalytic performance for naphthalene removal[J]. Fuel Processing Technology, 2016, 145, 31- 41. doi: 10.1016/j.fuproc.2016.01.020
30	HERVY M , BERHANU S , WEISS-HORTALA E , et al. Multiscale characterization of chars mineral species for tar cracking[J]. Fuel, 2017, 189, 88- 97. doi: 10.1016/j.fuel.2016.10.089
31	GREGORIO F D , PARRILLO F , SALZANO E , et al. Removal of naphthalene by activated carbons from hot gas[J]. Chemical Engineering Journal, 2016, 291, 244- 253. doi: 10.1016/j.cej.2016.01.081
32	HOSOKAI S , KUMABE K , OHSHITA M , et al. Mechanism of decomposition of aromatics over charcoal and necessary condition for maintaining its activity[J]. Fuel, 2008, 87, 2914- 2922. doi: 10.1016/j.fuel.2008.04.019
33	ZHANG Y , LUO Y , WU W , et al. Heterogeneous cracking reaction of tar over biomass char, using naphthalene as model biomass tar[J]. Energy Fuels, 2014, 28, 3129- 3137. doi: 10.1021/ef4024349
34	LU P , QIAN X , HUANG Q , et al. Catalytic cracking of toluene as a tar model compound using sewage sludge derived char[J]. Energy Fuels, 2016.
35	李龙之, 宋占龙, 马春元, 等. 微波辅助生物质焦炭诱导甲苯裂解和重整试验[J]. 农业机械学报, 2015, 46 (10): 229- 234, 303. doi: 10.6041/j.issn.1000-1298.2015.10.030
	LI L Z , SONG Z L , MA C Y , et al. microwave assisted biomass coke induced toluene cracking and reforming test[J]. Journal of Agricultural Machinery, 2015, 46 (10): 229- 234, 303. doi: 10.6041/j.issn.1000-1298.2015.10.030
36	米铁, 余新明, 吴正舜. 微波作用下焦油模型化合物——甲苯裂解实验研究[J]. 江汉大学学报(自然科学版), 2012, 40 (5): 27- 31. doi: 10.3969/j.issn.1673-0143.2012.05.008
	MI T , YU X M , YU Z S . Experimental study on tar model compound:Toluene cracking under microwave[J]. Journal of Jianghan University(Natural Science Edition), 2012, 40 (5): 27- 31. doi: 10.3969/j.issn.1673-0143.2012.05.008
37	周晓.微波作用下焦油模型化合物热裂解研究[D].武汉:华中师范大学, 2014.
	ZHOU X.Study on thermal cracking of tar model compounds under microwave action[D]. Wuhan: Central China Normal University, 2014.
38	ZHU F , LI X , ZHANG H , et al. Destruction of toluene by rotating gliding arc discharge[J]. Fuel, 2016, 176, 78- 85. doi: 10.1016/j.fuel.2016.02.065
39	LIU S , MEI D , WANG L . Steam reforming of toluene as biomass tar model compound in a gliding arc discharge reactor[J]. Chemical Engineering Journal, 2017, 307, 793- 802. doi: 10.1016/j.cej.2016.08.005
40	王新新. 介质阻挡放电及其应用[J]. 高电压技术, 2009, 34 (1): 1- 11.
	WANG X X . Dielectric barrier discharge and its application[J]. High Voltage Technology, 2009, 34 (1): 1- 11.
41	SALEEM F , ZHANG K , HARVETY A . Role of CO₂ in the conversion of toluene as a tar surrogate in a nonthermal plasma dielectric barrier discharge reactor[J]. Energy & Fuels, 2018, 32 (4): 5164- 5170.
42	LIU L , WANG Q , SONG J , et al. Dry reforming of model biomass pyrolysis products to syngas by dielectric barrier discharge plasma[J]. International Journal of Hydrogen Energy, 2018, 43 (22): 10281- 10293. doi: 10.1016/j.ijhydene.2018.04.112
43	SALEEM F , ZHANG K , HARVEY A . Temperature dependence of non-thermal plasma assisted hydrocracking of toluene to lower hydrocarbons in a dielectric barrier discharge reactor[J]. Chemical Engineering Journal, 2019, 356, 1062- 1069. doi: 10.1016/j.cej.2018.08.050
44	NAIR S A , YAN K , PEMEN A , et al. Tar removal from biomass-derived fuel gas by pulsed corona discharges:A chemical kinetic study[J]. Industrial & Engineering Chemistry Research, 2004, 43 (7): 1649- 1658.
45	何丽娟, 李坚, 梁文俊, 等. 高频低温等离子体法去除甲苯的实验研究[J]. 高电压技术, 2009, 35 (5): 1105- 1108.
	HE L J , LI J , LIANG W J , et al. Experimental study on removal of toluene by high frequency low temperature plasma method[J]. High Voltage Technology, 2009, 35 (5): 1105- 1108.
46	左莉, 侯立安. 介质阻挡放电与脉冲电晕放电净化气态污染物的试验研究[J]. 洁净与空调技术, 2003, (3): 43- 45. doi: 10.3969/j.issn.1005-3298.2003.03.010
	ZUO L , HOU L A . Experimental study on purification of gaseous contaminants by dielectric barrier discharge and pulsed corona discharge[J]. Cleaning and Air Conditioning Technology, 2003, (3): 43- 45. doi: 10.3969/j.issn.1005-3298.2003.03.010
47	WANG B , YAO S , PENG Y , et al. Toluene removal over TiO₂-BaTiO₃ catalysts in an atmospheric dielectric barrier discharge[J]. Journal of Environmental Chemical Engineering, 2018, 6 (4): 3819- 3826. doi: 10.1016/j.jece.2018.06.006
48	ZHU T , LI J , JIN Y , et al. Decomposition of benzene by non-thermal plasma processing:Photocatalyst and ozone effect[J]. International Journal of Environmental Science & Technology, 2008, 5 (3): 375- 384.
49	WANG B , CHI C , XU M , et al. Plasma-catalytic removal of toluene over CeO₂-MnOx catalysts in an atmosphere dielectric barrier discharge[J]. Chemical Engineering Journal, 2017, 322, 679- 692. doi: 10.1016/j.cej.2017.03.153
50	王青.微波诱导金属放电催化转化生物质焦油的研究[D].济南:山东大学, 2018.
	WANG Q.Study on catalytic conversion of biomass tar by microwave induced metal discharge[D]. Jinan: Shandong University, 2018.
51	TAO K , OHTA N , LIU G , et al. Plasma enhanced catalytic reforming of biomass tar model compound to syngas[J]. Fuel, 2013, 104, 53- 57. doi: 10.1016/j.fuel.2010.05.044
52	甘蓉丽, 罗光前, 许洋, 等. 低温等离子体协同铜铈催化剂脱除甲苯[J]. 化工进展, 2018, 37 (9): 3416- 3423.
	GAN R L , LUO G Q , XU Y , et al. low temperature plasma collaborative copper cerium catalyst removal of toluene[J]. Chemical Progress, 2018, 37 (9): 3416- 3423.
53	龙千明, 刘媛, 范洪波. 低温等离子体催化处理甲苯气体[J]. 化工进展, 2010, 29 (7): 1350- 1357.
	LONG Q M , LIU Y , FAN H B . Low temperature plasma catalytic treatment of toluene gas[J]. Chemical Progress, 2010, 29 (7): 1350- 1357.
54	张宇川.基于铁基催化剂的生物质焦油微波裂解试验研究[D].济南:山东大学, 2018.
	ZHANG Y C.Experimental study on microwave cracking of biomass tar based on Ferro base catalyst[D]. Jinan: Shandong University, 2018.
55	GUO Y , YE D , CHEN K . Toluene decomposition using a wire-plate dielectric barrier discharge reactor with manganese oxide catalyst in situ[J]. Journal of Molecular Catalysis A:Chemical, 2006, 245 (1/2): 93- 100.
56	LIU S Y , MEI D . Hybrid plasma-catalytic steam reforming of toluene as a biomass tar model compound over Ni/Al₂O₃ catalysts[J]. Fuel Processing Technology, 2017, 166, 269- 275. doi: 10.1016/j.fuproc.2017.06.001

[1]	YANG Xiao-hui, XIAO Guo-min, JIANG Jian-chun, ZHOU Yong-hong. Synthesis and Characterization of A Novel Lignin Model Compound Named Guaiacylglycerol-β-guaiacyl Ether [J]. Chemistry and Industry of Forest Products, 2015, 35(5): 65-70.
[2]	NIE Ming-cai;KONG Zhen-wu;HUO Shu-ping;WU Guo-min;CHEN Jian. Crosslinking Reaction and Kinetics of Aminated Polyols from Lignin Model Compounds [J]. , 2012, 32(4): 21-27.
[3]	NIE Ming-cai;KONG Zhen-wu;HUO Shu-ping;WU Guo-min;CHEN Jian. Mannich Reaction of Lignin Model Compound Vanillin and Chemical Structure Characterization of Its Product [J]. , 2012, 32(3): 13-18.
[4]	NIE Ming-cai;HUO Shu-ping;KONG Zhen-wu. Research Progress of Lignin Model Compounds [J]. , 2010, 30(5): 115-121.
[5]	ZHAO Fang;XIE Yi-min;WANG Song;WANG Peng. Study on Co-polymerization of Coniferin with Model Compound of Lignin [J]. , 2009, 29(1): 1-6.
[6]	XIE Yi-min;HU Zhou-jian;WU Hong;LAI Yan-ming. SYNTHESIS OF β-O-4 TYPE LIGNIN MODEL COMPOUND AND ITS BIOMIMETIC DEGRADATION WITH GIF SYSTEM(Ⅱ) [J]. , 2004, 24(1): 1-6.

Research Progress in the Removal of Biomass Tar Model Compounds

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 3

References 56

Related Articles 6

Recommended Articles

Metrics

Comments