杨木碳水化合物自水解特征的P因子调控

doi:10.3969/j.issn.0253-2417.2019.04.009

Abstract

Abstract:

To regulate carbohydrate reaction in the poplar autohydrolysis of biorefining, the effects of different P-factors on the pH value, hydrolysis rate, reducing sugar, holocellulose, different monosaccharides and furfural product in the poplar autohydrolysis system were studied in detail. The results showed that with the increase of P-factor to about 2 800, the pH value of the system decreased continuously to 3.6, the total hydrolysis rate and holocellulose removal rate reached 47% and 54%, respectively. Arabinose and rhamnose in pentosan were almost completely hydrolyzed, xylan was mostly hydrolyzed, and the removal rate of glucan was 37%(mostly from hemicellulose). The trend of total hydrolysis, holocellulose removal and pentosan removal could be divided into a fast and a following slow removal phase in the process. There was a positive correlation between P-factor and furfural production, which could be divided into a slow and a fast phase, and the conversion of pentose to furfural was 40%. P-factor could regulate the autohydrolysis of carbohydrate in poplar.

Key words: poplar, carbohydrate, P-factor, autohydrolysis, monosaccharide

CLC Number:

TQ353

Pengfei WANG,Hao REN,Huamin ZHAI. P-factor Regulation of Characteristics in the Auto Hydrolysis ofPoplar Carbohydrate[J]. Chemistry and Industry of Forest Products, 2019, 39(4): 65-71.

Figures/Tables 7

Table 1

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References 24

1	RAHMAN F A , AZIZ M M A , SAIDUR R , et al. Pollution to solution:Capture and sequestration of carbon dioxide(CO₂)and its utilization as a renewable energy source for a sustainable future[J]. Renewable and Sustainable Energy Reviews, 2017, 71, 112- 126. doi: 10.1016/j.rser.2017.01.011
2	OLOFSSON J , BÖRJESSON P . Residual biomass as resource:Life-cycle environmental impact of wastes in circular resource systems[J]. Journal of Cleaner Production, 2018, 196 (20): 997- 1006.
3	曲音波, 崔球, 刘巍峰, 等. 非粮生物质炼制技术-木质纤维素生物降解机理及其酶系合成调控[M]. 北京: 化学工业出版社, 2017: 1- 38.
	QU Y B , CUI Q , LIU W F , et al. Non-food Biomass Refining Technology-lignocellulose Biodegradation Mechanism and Enzymatic Synthesis Regulation[M]. Beijing: Chemical Industry Press, 2017: 1- 38.
4	YOO C G , PU Y , LI M , et al. Elucidating structural characteristics of biomass using solution-state 2D NMR with a mixture of deuterated dimethylsulfoxide and hexamethylphosphoramide[J]. ChemSusChem, 2016, 9 (10): 1090- 1095. doi: 10.1002/cssc.201600135
5	王鹏, 秦影, 傅英娟, 等. 杨木自水解液中溶解木质素和胶体木质素的结构特征[J]. 林产化学与工业, 2017, 37 (4): 59- 66. doi: 10.3969/j.issn.0253-2417.2017.04.009
	WANG P , QIN Y , FU Y G , et al. Structural characteristics of dissolved lignin and colloidal lignin in poplar natural hydrolysate[J]. Chemistry and Industry of Forest Products, 2017, 37 (4): 59- 66. doi: 10.3969/j.issn.0253-2417.2017.04.009
6	QIN L, LI W C, ZHU J Q, et al.Hydrolysis of Lignocellulosic Biomass to Sugars[M]//FANG Z, SMITH Jr R L, QI X H.Production of Platform Chemicals from Sustainable Resources.Singapore: Springer, 2017: 3-41.
7	YU Q , ZHUANG X , YUAN Z , et al. Hydrolysis of sweet sorghum bagasse hemicellulose with liquid hot water and its mechanism[J]. CIESC Journal, 2012, 63 (2): 599- 605.
8	SIXTA H, POTTHAST A, KROTSCHECK A.Chemical Pulping Processe[C]//SIXTA H.Handbook of Pulp.Weinheim: Wiley-VCH Verlag GmbH Co.KGaA, 2006: 1045-1062.
9	刘超, 刘娜, 秦梦华, 等. 杨木片高温热水解过程中聚戊糖的溶出特点[J]. 纸和造纸, 2014, 33 (5): 10- 15.
	LIU C , LIU N , QIN M H , et al. Characteristics of pentose-polysaccharide in the process of high temperature hydrolysis of poplar wood chips[J]. Paper and Paper Making, 2014, 33 (5): 10- 15.
10	徐丰, 吉兴香, 王强, 等. 热水预处理过程中P因子对杨木半纤维素溶出效果的影响[J]. 中国造纸, 2018, 37 (8): 1- 7.
	XU F , JI X X , WANG Q , et al. Effect of P factor on hemicellulose dissolution of poplar during hot water pretreatment[J]. China Pulp & Paper, 2018, 37 (8): 1- 7.
11	袁梅婷, 翟华敏, 冯年捷, 等. 麦草自水解过程中半纤维素和木质素的变化特性[J]. 纤维素科学与技术, 2015, 23 (2): 55- 61. doi: 10.3969/j.issn.1004-8405.2015.02.009
	YUAN M T , ZHAI H M , FENG N J , et al. Changes of hemicellulose and lignin in wheat straw during self-hydrolysis[J]. Cellulose Science and Technology, 2015, 23 (2): 55- 61. doi: 10.3969/j.issn.1004-8405.2015.02.009
12	侯光北, 冯年捷, 张琳, 等. 麦草碱性亚硫酸盐制浆废液的木聚糖酶解特性[J]. 南京林业大学学报(自然科学版), 2014, 38 (4): 113- 117.
	HOU G B , FENG N J , ZHANG L , et al. Enzymatic hydrolysis of xylanase in wheat straw alkaline sulfite pulping waste liquor[J]. Journal of Nanjing Forestry University(Natural Science Edition), 2014, 38 (4): 113- 117.
13	BORCHARDT L G , PIPER C V . A gas chromatographic method for carbohydrates as alditol-acetates[J]. TAPPI, 1970, 53, 257- 260.
14	CUI Z , SHENG C X , LIN L X , et al. Rapid method for determination of furfural and 5-hydroxymethyl furfural in pre-extraction stream of biomass using UV spectroscopy[J]. Spectroscopy & Spectral Analysis, 2010, 30 (1): 247- 250.
15	THOMAS P , GASTON O , MICHAEL H , et al. Lignin repolymerisation in spruce autohydrolysis pretreatment increases cellulase deactivation[J]. Green Chemistry, 2015, 17 (6): 3521- 3532. doi: 10.1039/C4GC02381A
16	SHINDE S D , MENG X , KUMAR R , et al. Recent advances in understanding the pseudo-lignin formation in a lignocellulosic biorefinery[J]. Green Chemistry, 2018, 20 (10): 2192- 2205. doi: 10.1039/C8GC00353J
17	段超, 冯文英, 张艳玲, 等. 热水预水解对杨木预水解液性能的影响[J]. 中华纸业, 2013, (10): 29- 34. doi: 10.3969/j.issn.1007-9211.2013.10.010
	DUAN C , FENG W Y , ZHANG Y L , et al. Effects of hot water pre-hydrolysis on the properties of poplar pre-hydrolysate[J]. China Pulp & Paper Industry, 2013, (10): 29- 34. doi: 10.3969/j.issn.1007-9211.2013.10.010
18	耿星月, 刘苇, 侯庆喜, 等. 自水解预处理对杨木聚木糖分布的影响[J]. 中国造纸, 2016, 35 (7): 1- 6.
	GENG X Y , LIU W , HOU Q X , et al. Effects of self-hydrolysis pretreatment on the distribution of xylitol in poplar[J]. China Pulp & Paper, 2016, 35 (7): 1- 6.
19	ASPROMONTE S G , ROMERO A , BOIX A V , et al. Hydrolysis of cellulose to glucose by supercritical water and silver mesoporous zeolite catalysts[J]. Cellulose, 2019, 26 (4): 2471- 2485. doi: 10.1007/s10570-018-2221-5
20	李梓木, 于艳玲, 孙嘉星, 等. 水热预处理工艺参数对玉米秸秆组分与酶解效率的影响[J]. 化工学报, 2015, (4): 529- 536.
	LI Z M , YU Y L , SUN J X , et al. Effects of hydrothermal pretreatment parameters on components and enzymatic hydrolysis efficiency of corn straw[J]. Journal of Chemical Industry, 2015, (4): 1529- 1536.
21	SILVA F T , DUARTE , LUIS C , et al. Hydrothermal pretreatment of several lignocellulosic mixtures containing wheat straw and two hardwood residues available in Southern Europe[J]. Bioresource Technology, 2015, 183, 213- 220. doi: 10.1016/j.biortech.2015.01.059
22	SARKAR M , RAO C V N . The structure of degraded, mangle gum[J]. Carbohydrate Research, 1975, 41 (1): 163- 174. doi: 10.1016/S0008-6215(00)87016-0
23	ZHANG X , MENG L , XU F , et al. Pretreatment of partially delignified hybrid poplar for biofuels production:Characterization of organosolv hemicelluloses[J]. Industrial Crops and Products, 2011, 33 (2): 310- 316. doi: 10.1016/j.indcrop.2010.11.016
24	FREDERIC D , WANG Y T , ANITHA M , et al. Hydrolysis of hemicellulose and derivatives:A review of recent advances in the production of furfural[J]. Frontiers in Chemistry, 2018, 6, 146. doi: 10.3389/fchem.2018.00146

温度 temperature/℃	保温时间 holding time/min	P因子 P-factor
	0	64
	30	168
160	60	304
	90	451
	120	585
	0	142
	30	414
170	60	709
	90	1009
	120	1304
	0	300
	30	927
	60	1554
180	70	1762
	90	2189
	100	2388
	120	2816

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P-factor Regulation of Characteristics in the Auto Hydrolysis ofPoplar Carbohydrate

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