羧甲基半纤维素/壳聚糖/氧化石墨烯复合膜的制备及性能研究

doi:10.3969/j.issn.0253-2417.2019.06.002

Abstract

Abstract:

Carboxymethyl hemicellulose was modified by the carboxymethylation reaction which extracted from bamboo. The hemicellulose/chitosan/graphene oxide composite films were prepared from the obtained carboxymethyl hemicelluloses, chitosan and grapheme oxide, which possessed excellent mechanical and oxygen barrier properties. The properties of the composite films were analyzed by FT-IR, XRD, SEM, TGA, mechanical strength and oxygen barrier tests. The different contents of graphene oxide were detected to analyze the effects of structure and properties of the composite films. The matrix of CMH, CS, GO were combined mainly through ion bond and hydrogen bond, and the GO was dispersed uniformly in CMH/CS matrix. Therefore, the surface of the film was smooth and dense with regular layered structure. The mechanical properties and thermal stability of the composite films were obviously improved by the addition of GO, which was due to the enhancement of GO in the whole composite system. The oxygen barrier ability of the composite film was also increased. The best mechanical properties of composite membranes were as follows:the tensile stress was 73.63 MPa, the tensile strain was 20.24%, and Young's modulus was 2.28 GPa when the content of graphene oxide was 0.5%. Meanwhile, it performed the best oxygen barrier property when the content of graphene oxide was 0.5%, and the gas permeation coefficient of the film was reached to 3.793 cm³·cm/(m²·s·Pa). The initial decomposition and maximum loss ratio temperature of the FG_0.5 were 242.4 and 274.5℃, respectively.

Key words: carboxymethyl hemicelluloses, chitosan, graphene oxide, composite film

CLC Number:

TQ35

Ying GUAN,Jun RAO,Yule WU,Ran YANG,Hui GAO. Preparation and Characterization of Carboxymethyl Hemicelluloses/Chitosan/Graphene Oxide Composite Film[J]. Chemistry and Industry of Forest Products, 2019, 39(6): 13-20.

Figures/Tables 10

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

Table 1

Fig.7

Table 2

Table 3

References 26

1	MOSIER N , WYMAN C , DALE B , et al. Features of promising technologies for pretreatment of lignocellulosic biomass[J]. Bioresources Technology, 2005, 96 (6): 673- 686. doi: 10.1016/j.biortech.2004.06.025
2	TIBOLLA H , PELISSARI F M , MARTINS J T , et al. Cellulose nanofibers produced from banana peel by chemical and mechanical treatments:Characterization and cytotoxicity assessment[J]. Food Hydrocolloids, 2018, 75, 192- 201. doi: 10.1016/j.foodhyd.2017.08.027
3	LESKINEN T , KING A W T , KILPELAINEN I , et al. Fractionation of lignocellulosic materials using ionic liquids.Part 2:Effect of particle size on the mechanisms of fractionation[J]. Industrial & Engineering Chemistry Research, 2013, 52 (11): 3958- 3966. doi: 10.1021/ie302896n
4	GUAN Y , QI X M , CHEN G G , et al. Facile approach to prepare drug-loading film from hemicelluloses and chitosan[J]. Carbohydrate Polymers, 2016, 153, 542- 548. doi: 10.1016/j.carbpol.2016.08.008
5	YAICH I A , EDLUND U , ALBERTSSON A C . Transfer of biomatrix/wood cell interactions to hemicellulose-based materials to control water interaction[J]. Chemical Reviews, 2017, 117 (12): 8177- 8207. doi: 10.1021/acs.chemrev.6b00841
6	PETZOLD-WELCKE K , SCHWIKAL K , DAUS S , et al. Xylan derivatives and their application potential—Mmini-review of own results[J]. Carbohydrate Polymers, 2014, 100, 80- 88. doi: 10.1016/j.carbpol.2012.11.052
7	CHEN G G , HU Y J , PENG F , et al. Fabrication of strong nanocomposite films with renewable forestry waste/montmorillonite/reduction of graphene oxide for fire retardant[J]. Chemical Engineering Journal, 2017, 337, 436- 445.
8	ZHAO W F , ODELIUS K , EDLUND U , et al. In situ synthesis of magnetic field-responsive hemicellulose:Hydrogels for drug delivery[J]. Biomacromolecules, 2015, 16 (8): 2522- 2528. doi: 10.1021/acs.biomac.5b00801
9	GUAN Y , CHEN J , QI X M , et al. Fabrication of biopolymer hydrogel containing Ag nanoparticles for antibacterial property[J]. Industrial & Engineering Chemistry Research, 2015, 54 (30): 7393- 7400.
10	FARHAT W , VENDITTI R , AYOUB A , et al. Towards thermoplastic hemicellulose:Chemistry and characteristics of poly-(ε-caprolactone) grafting onto hemicellulose backbones[J]. Materials & Design, 2018, 153, 298- 307. doi: 10.1016/j.matdes.2018.05.013
11	曾月, 敬雪莲, 李慧霖, 等. 羧甲基半纤维素/壳聚糖复合材料的制备及其对Cu²⁺的吸附性能研究[J]. 化工新型材料, 2018, 46 (4): 165- 168, 172.
	ZENG Y , JING X L , LI H L , et al. Study on preparation of carboxymethyl hemicellulose/chitosan composite and its adsorption for Cu²⁺ ion[J]. New Chemical Materials, 2018, 46 (4): 165- 168, 172.
12	ZHONG L X , PENG X W , YANG D , et al. Long-chain anhydride modification:A new strategy for preparing xylan films[J]. Journal of Agricultural & Food Chemistry, 2013, 61, 655- 661. doi: 10.1021/jf304818f
13	PENG X W , REN J L , ZHONG L X , et al. Nanocomposite films based on xylan-rich hemicelluloses and cellulose nanofibers with enhanced mechanical properties[J]. Biomacromolecules, 2011, 12 (9): 3321- 3329. doi: 10.1021/bm2008795
14	KOCHUMALAYIL J J , BERGLUND L A . Water-soluble hemicelluloses for high humidity applications-enzymatic modification of xyloglucan for mechanical and oxygen barrier properties[J]. Green Chemistry, 2014, 16, 1904- 1910. doi: 10.1039/C3GC41823E
15	GUAN Y , ZHANG B , TAN X , et al. Organic-inorganic composite films based on modified hemicelluloses with clay nanoplatelets[J]. ACS Sustainable Chemistry & Engineering, 2014, 2 (7): 1811- 1818.
16	RAO J , GAO H , GUAN Y , et al. Fabrication of hemicelluloses films with enhanced mechanical properties by graphene oxide for humidity sensing[J]. Carbohydrate Polymers, 2019, 208, 513- 520. doi: 10.1016/j.carbpol.2018.12.099
17	KACURAKOVA M , WELLNER N , EBRINGEROVA A , et al. Characterisation of xylan-type polysaccharides and associated cell wall components by FT-IR and FT-Raman spectroscopies[J]. Food Hydrocolloids, 1999, 13 (1): 35- 41. doi: 10.1016/S0268-005X(98)00067-8
18	EBRINGEROVA A , HROMADKOVA Z , ALFOLDI J , et al. Structural and solution properties of corn cob heteroxylans[J]. Carbohydrate Polymers, 1992, 19 (2): 99- 105. doi: 10.1016/0144-8617(92)90119-B
19	REN J L , SUN R C , PENG F . Carboxymethylation of hemicelluloses isolated from sugarcane bagasse[J]. Polymer Degradation & Stability, 2008, 93 (4): 786- 793. doi: 10.1016/j.polymdegradstab.2008.01.011
20	PENG X W , REN J L , ZHONG L X , et al. Microwave-induced synthesis of carboxymethyl hemicelluloses and their rheological properties[J]. Journal of Agricultural & Food Chemistry, 2011, 59 (2): 570- 576.
21	PENG F , REN J L , XU F , et al. Fractional study of alkali-soluble hemicelluloses obtained by graded ethanol precipitation from sugar cane bagasse[J]. Journal of Agricultural & Food Chemistry, 2010, 58 (3): 1768- 1776.
22	MILLONEN K S , STEVANIC J S , JOLY C , et al. Composite films from spruce galactoglucomannans with microfibrillated spruce wood cellulose[J]. Cellulose, 2011, 18 (3): 713- 726. doi: 10.1007/s10570-011-9524-0
23	SERRERO A , TROMBOTTO S , CASSAGNAU P , et al. Polysaccharide gels based on chitosan and modified starch:Structural characterization and linear viscoelastic behavior[J]. Biomacromolecules, 2010, 11 (6): 1534- 1543. doi: 10.1021/bm1001813
24	LIU S , FANG Y , ODERINDE O , et al. Zinc ions enhanced nacre-like chitosan/graphene oxide composite film with superior mechanical and shape memory properties[J]. Chemical Engineering Journal, 2017, 321, 502- 509. doi: 10.1016/j.cej.2017.03.087
25	HAN D L , YAN L F , CHEN W F , et al. Preparation of chitosan/graphene oxide composite film with enhanced mechanical strength in the wet state[J]. Carbohydrate Polymers, 2011, 83 (2): 653- 658. doi: 10.1016/j.carbpol.2010.08.038
26	JIN X Q , LI G Q , JIANG H H , et al. High strength graphene oxide/chitosan composite screws with a steel-concrete structure[J]. Carbohydrate Polymers, 2019, 214, 167- 173. doi: 10.1016/j.carbpol.2019.03.039

样品 samples	拉伸应力/MPa tensile stress	拉伸应变/% tensile strain	杨氏模量/GPa Young's modulus	断裂能/(N·m^-1) breaking energy
FG₀	47.21±3.52	3.62±1.21	1.30±0.29	141.34
FG_0.25	67.53±2.23	10.13±1.65	1.92±0.14	627.02
FG_0.5	73.63±5.06	20.24±3.22	2.28±0.16	1293.24
FG_0.75	69.60±1.06	15.55±2.11	2.25±0.05	945.05
FG₁	55.23±2.83	13.98±1.46	1.71±0.19	671.17

样品 samples	初始分解温度(T₀)/℃ initial decomposition temp.	最大热失重速率温度/℃ maximum loss ratio temp.		最大热失重速率/(%· ℃^-1) the maximum loss ratio	残渣率/% residuals
样品 samples	初始分解温度(T₀)/℃ initial decomposition temp.	T₁	T₂	最大热失重速率/(%· ℃^-1) the maximum loss ratio	残渣率/% residuals
CMH	261.8	290.2	—	-10.18	24.47
CS	276.5	295.4	—	-10.44	34.91
GO	194.6	210.9	565.7	-6.95	37.86
FG₀	233.0	256.6	—	-5.69	33.23
FG_0.25	244.0	269.2	—	-7.07	34.12
FG_0.5	242.4	274.5	—	-6.72	34.96
FG_0.75	239.3	262.6	—	-6.71	35.64
FG₁	241.5	264.9	—	-7.08	35.77

样品 sample	气体透过率/ (cm³·m^-2·d^-1·Pa^-1) gas permeation rate	气体透过系数/ (cm³·cm·m^-2·s^-1·Pa^-1) gas permeation coefficient	厚度/mm thickness
FG₀	2514466	22931.930	0.0912
FG_0.25	492	6.002	0.1220
FG_0.5	430	3.793	0.0882
FG_0.75	571	4.619	0.0809
FG₁	752	9.490	0.1262

[1]	JI Dexian, LIN Zhaoyun, XIA Yuanyuan, YANG Guihua, CHEN Jiachuan. Preparation of NCC Assisted NaClO Oxidized Starch and Its Influence on the Properties ofComposite Film [J]. Chemistry and Industry of Forest Products, 2019, 39(5): 33-40.
[2]	XIA Yuantao, YANG Meihong, SUN Huijie, GAO Yating, ZHOU Gui. Preparation of Aspergillus niger Mycelium-chitosan Biosorbent and Its Cu²⁺ Adsorption Mechanism [J]. Chemistry and Industry of Forest Products, 2018, 38(4): 117-123.
[3]	LIU Zhiming, WU Peng. Preparation of Chitosan/Cellulose Aerogel Beads and Its Formaldehyde Gas Adsorption Performance [J]. Chemistry and Industry of Forest Products, 2017, 37(1): 27-35.
[4]	YANG Lei, LI Xin, YU Shi-yuan, YONG Qiang. Preparation of Chitosan from Waste Biomass of Rhizopus oryzae and its Membrane Characteristics [J]. Chemistry and Industry of Forest Products, 2015, 35(4): 35-40.
[5]	PEI Li-jun, CAI Zhao-sheng, SHANG Shi-bin, SONG Zhan-qian. Synthesis and Performance of Dehydroabietylamine-chitosan Cationic Surfactants [J]. Chemistry and Industry of Forest Products, 2014, 34(5): 47-52.
[6]	GUO Dou-dou, PANG Hao, LIU Hai-lu, XU Li-li, ZHENG Jing-xin, LIAO Bing. Preparation of Chitosan Composite Hydrogels and Its Effective Adsorption of Copper (Ⅱ) Ions from Aqueous Solutions [J]. Chemistry and Industry of Forest Products, 2014, 34(1): 8-12.
[7]	WANG Chun-hai;AI Qing;ZHAO Yin-feng;BEI Ying;FANG Gui-zhen. Adsorption of Copper Ions by Sodium Lignosulfonate-chitosan Polyelectrolyte Complex [J]. , 2012, 32(1): 29-34.
[8]	ZHANG Rui;FANG Gui-zhen;MA Ying-mei;MA Yan-li. Characterization of Chitosan-carboxymethyl Cellulose Blended Membrane [J]. , 2010, 30(1): 43-48.
[9]	ZHANG Rui;CHEN Zhen-ning;FANG Gui-zhen;MA Ying-mei;DAI Xiao-feng. Immobilization of β-Galactosidase on Carboxymethyl Cellulose-chitosan Polyelectrolyte Complex [J]. , 2009, 29(S1): 138-142,.
[10]	WANG Dan;LIU He;SHANG Shi-bin;SONG Zhan-qian. Preparation and Properties of Nanocomposite Films Composed of Cellulose Nanocrystals and Polyvinyl Alcohol [J]. , 2009, 29(S1): 43-46.
[11]	ZHU Jun-jun;JIANG Xiao-hua;YONG Qiang;YU Shi-yuan . Immobilization of β-glucosidase on Chitosan Beads [J]. , 2007, 27(2): 16-20.
[12]	CAI Zhao-sheng;SONG Zhan-qian;YANG Chun-sheng;WANG Jin-tang;XU Qi. Preparation of Amphoteric Chitosan and Characterization of Its Structure [J]. , 2007, 27(2): 123-126.
[13]	LIU Wen-bo;SONG Zhan-qian;YU Gang. STUDY ON PREPARATION OF ULTRAFINE CAPSULES WITH CHITOSAN BY MONOPHASIC COAGULATION [J]. , 2005, 25(3): 115-119.
[14]	HE Dong-bao;SHI Xiao-ming;SHI Yi;ZHAN Dong-feng. STUDY ON GELATION PROPERTIES OF MIXED GEL OF CHITOSAN AND CARBOXYL METHYL KONJAC GLUCOMANNAN GUM [J]. , 2002, 22(2): 70-74.
[15]	LEI Fei-hou . STUDY ON IMMOBILIZATION OF POLYPHENOL OXIDASES ON COORDINATED CHITOSAN Cu²⁺ [J]. , 2000, 20(2): 23-26.

Preparation and Characterization of Carboxymethyl Hemicelluloses/Chitosan/Graphene Oxide Composite Film

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 10

References 26

Related Articles 15

Recommended Articles

Metrics

Comments