Chemistry and Industry of Forest Products ›› 2020, Vol. 40 ›› Issue (4): 71-78.doi: 10.3969/j.issn.0253-2417.2020.04.010
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Tingting ZHANG1,Xiuli HAN1,2,*(),Ying LIU1,Chunling DONG1,Chun CHANG1,2
Received:
2020-04-08
Online:
2020-08-28
Published:
2020-08-21
Contact:
Xiuli HAN
E-mail:xlhan@zzu.edu.cn
CLC Number:
Tingting ZHANG,Xiuli HAN,Ying LIU,Chunling DONG,Chun CHANG. Adsorption Characteristics of Ciprofloxacin by Biomass-based Activated Carbon[J]. Chemistry and Industry of Forest Products, 2020, 40(4): 71-78.
Table 1
Experimental design and adsorption capacity at different conditions"
编号 No. | X1 吸附时间/min adsorption time | X2 吸附剂用量/(g·L-1) adsorbent dosage | X3 pH值 pH value | 吸附量(qt)/(mg·g-1) adsorption capacity |
1 | -1(120) | -1(0.4) | 0(5.5) | 114.23 |
2 | +1(600) | -1(0.4) | 0(5.5) | 153.42 |
3 | -1(120) | +1(0.6) | 0(5.5) | 110.05 |
4 | +1(600) | +1(0.6) | 0(5.5) | 144.80 |
5 | -1(120) | 0(0.5) | -1(3) | 118.24 |
6 | +1(600) | 0(0.5) | -1(3) | 145.81 |
7 | -1(120) | 0(0.5) | +1(8) | 106.22 |
8 | +1(600) | 0(0.5) | +1(8) | 145.24 |
9 | 0(360) | -1(0.4) | -1(3) | 145.9 |
10 | 0(360) | +1(0.6) | -1(3) | 138.42 |
11 | 0(360) | -1(0.4) | +1(8) | 131.67 |
12 | 0(360) | +1(0.6) | +1(8) | 127.77 |
13 | 0(360) | 0(0.5) | 0(5.5) | 148.14 |
14 | 0(360) | 0(0.5) | 0(5.5) | 146.66 |
15 | 0(360) | 0(0.5) | 0(5.5) | 146.12 |
16 | 0(360) | 0(0.5) | 0(5.5) | 148.42 |
17 | 0(360) | 0(0.5) | 0(5.5) | 145.78 |
Table 2
The results of ANOVA analysis for adsorption of CIP"
方差来源 sources | 平方和 sum of squares | 自由度 df | 均方差 mean square | F值 F value | P值 P value | 显著性 significant |
模型model | 3682.81 | 9 | 409.20 | 90.71 | < 0.0001 | ** |
X1 | 2468.59 | 1 | 2468.59 | 547.24 | < 0.0001 | ** |
X2 | 73.08 | 1 | 73.08 | 16.20 | 0.0050 | * |
X3 | 175.50 | 1 | 175.50 | 38.91 | 0.0004 | ** |
X1X2 | 4.93 | 1 | 4.93 | 1.09 | 0.3307 | |
X1X3 | 32.78 | 1 | 32.78 | 7.27 | 0.0308 | * |
X2X3 | 3.20 | 1 | 3.20 | 0.71 | 0.4272 | |
X12 | 579.41 | 1 | 579.41 | 128.44 | < 0.0001 | ** |
X22 | 91.76 | 1 | 91.76 | 20.34 | 0.0028 | * |
X32 | 173.31 | 1 | 173.31 | 38.42 | 0.0004 | ** |
残差residual | 31.58 | 7 | 4.51 | |||
失拟项lack of fit | 25.89 | 3 | 8.63 | 6.06 | 0.0571 | |
纯误差pure error | 5.69 | 4 | 1.42 | |||
总和sum | 3714.39 | 16 |
Table 3
Parameters of adsorption isotherm for CIP onto corncob-based activated carbon (CCAC)"
模型model | 参数parameter | 298 K | 308 K | 318 K |
朗谬尔 Langmuir | qm/(mg·g-1) | 187.05 | 209.93 | 230.05 |
KL/(L·mg-1) | 0.3838 | 1.2541 | 1.5460 | |
R2 | 0.8926 | 0.8618 | 0.8474 | |
χ2 | 7.9408 | 13.6173 | 21.3988 | |
弗罗因德利希 Freundlich | KF/(mg·g-1·(L·mg-1)1/n) | 93.43 | 119.06 | 129.88 |
1/n | 0.1392 | 0.1220 | 0.1255 | |
R2 | 0.9616 | 0.9535 | 0.9602 | |
χ2 | 4.0140 | 7.2644 | 8.4017 | |
雷德利希-彼得松 Redlich-Peterson | A/(L·g-1) | 179.38 | 625.79 | 963.55 |
B | 1.5240 | 4.3665 | 6.2555 | |
g | 0.9056 | 0.9159 | 0.9098 | |
R2 | 0.9983 | 0.9934 | 0.9974 | |
χ2 | 0.1208 | 0.7573 | 0.3654 | |
Sips模型 Sips model | qms/(mg·g-1) | 238.01 | 269.23 | 299.51 |
Ks/(L·mg-1) | 0.1753 | 0.4066 | 0.4103 | |
m | 0.4092 | 0.3568 | 0.3498 | |
R2 | 0.9905 | 0.9842 | 0.9903 | |
χ2 | 0.6995 | 1.9880 | 1.5718 |
Table 4
Kinetic model parameters for CIP adsorption onto CCAC"
模型model | 298 K | 308 K | 318 K | |
准一级动力学 pseudo first-order kinetics | k1/min-1 | 0.0531 | 0.0678 | 0.0733 |
qcal/(mg·g-1) | 142.43 | 164.40 | 179.85 | |
R2 | 0.7017 | 0.6942 | 0.6960 | |
准二级动力学 pseudo second-order kinetics | k2×104/(g·mg-1·min-1) | 5.6134 | 6.2679 | 6.3000 |
qexp/(mg·g-1) | 154.92 | 178.19 | 193.68 | |
qcal/(mg·g-1) | 150.03 | 172.28 | 188.01 | |
R2 | 0.8800 | 0.8882 | 0.8966 | |
叶洛维奇方程 Elovich | α/(mg·g-1·min-1) | 32.9422 | 49.0526 | 58.9315 |
β/(g·mg-1) | 0.0515 | 0.0484 | 0.0460 | |
R2 | 0.9962 | 0.9976 | 0.9951 | |
颗粒内扩散模型 intraparticle diffusion model | 8.7392 | 10.1206 | 10.7331 | |
C1 | 48.08 | 61.76 | 71.34 | |
R | 0.9940 | 0.9678 | 0.9472 | |
2.8622 | 2.9697 | 3.0232 | ||
C2 | 93.96 | 115.23 | 130.43 | |
R | 0.9879 | 0.9915 | 0.9685 | |
1.0633 | 1.1449 | 1.3306 | ||
C3 | 129.93 | 151.50 | 162.67 | |
R | 0.9544 | 0.9562 | 0.9974 |
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