毛竹水解渣木质素氢解制备芳香化学品

doi:10.3969/j.issn.0253-2417.2021.01.009

Abstract

Abstract:

Two kinds of lignin were extracted from moso bamboo(Phyllostachys heterocycla) hydrolysis residue by hydrogen peroxide method and methanol method. The process of catalytic reductive hydrogenolysis was investigated. The results of two kinds of lignin conversion and product distribution were compared at the same reaction temperature and reaction time. Meanwhile, the optimal conditions of hydrogen peroxide lignin conversion were optimized. When the reaction temperature was 220 ℃, the reaction time was 60 min, lignin extracted by hydrogen peroxide could be converted entirely into soluble substance, and the monomer yield was 14.85%. The soluble substance yield of lignin extracted by methanol method was 96.8%, the monomer yield was 7.13%. The results showed that the conversion efficiency of hydrogen peroxide lignin to aromatic chemicals was higher than that of methanol lignin at reductive hydrogenolysis. The reductive hydrogenolysis process restored the benzoquinone of hydrogen peroxide lignin to the aromatic structure. The side chains in the product were mainly carbonyl, carboxyl, aldehyde, and alkane groups.

Key words: moso bamboo hydrolysis residues, hydrogen peroxide, methanol, reductive hydrogenolysis, aromatic chemicals

CLC Number:

TQ35
O643.38

Yi CHENG, Yixin QU, Sheng YANG, Kang ZHUANG, Jidong WANG. Aromatic Chemicals Produced by Hydrogenolysis of Lignin Extracted from Phyllostachys heterocycla Hydrolysis Residues[J]. Chemistry and Industry of Forest Products, 2021, 41(1): 60-66.

Figures/Tables 4

References 20

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反应时间/min reaction time	反应温度/℃ reaction temperature	可溶物收率/% yeild of soluble matter	单体总产率/% total yeild of monomer	单体产率 yeild of monomer¹⁾/%
反应时间/min reaction time	反应温度/℃ reaction temperature	可溶物收率/% yeild of soluble matter	单体总产率/% total yeild of monomer	1	2	3	4	5	6	7	8
30	220	93.7	15.04	1.34	0.69	4.29	3.24	2.25	1.59	0.36	1.28
60	220	94.4	14.85	1.04	0.59	3.84	1.98	3.30	2.25	0.72	1.13
90	220	84.4	6.46	0.39	0.38	0.71	0.77	2.04	0.77	0.90	0.50
120	220	93.0	4.23	0.09	0.27	0.26	0.50	0.78	0.72	1.26	0.35
60	180	100	5.68	0.14	0.30	0.81	0.93	2.10	0.65	0.42	0.33
60	200	100	11.60	0.50	0.78	2.39	2.24	2.93	1.14	0.78	0.84
60	240	99.5	12.92	0.99	0.41	2.67	1.56	3.78	2.55	0.45	0.51
60	260	95.7	9.58	0.09	0.09	0.36	0.71	4.59	2.69	0.54	0.51

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Aromatic Chemicals Produced by Hydrogenolysis of Lignin Extracted from Phyllostachys heterocycla Hydrolysis Residues

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