Chemistry and Industry of Forest Products ›› 2021, Vol. 41 ›› Issue (6): 43-50.doi: 10.3969/j.issn.0253-2417.2021.06.006
Previous Articles Next Articles
Lu LUO1, Lingcong LUO1, Jianping DENG1, Tingting CHEN1, Mizi FAN1,2, Guanben DU3, Weigang ZHAO1,*()
Received:
2020-09-04
Online:
2021-12-28
Published:
2021-12-31
Contact:
Weigang ZHAO
E-mail:weigang-zhao@fafu.edu.cn
CLC Number:
Lu LUO, Lingcong LUO, Jianping DENG, Tingting CHEN, Mizi FAN, Guanben DU, Weigang ZHAO. Preparation of Boron and Nitrogen Co-doped Porous Carbon Derived from Sword Bean Shell and Its Electrochemical Performance[J]. Chemistry and Industry of Forest Products, 2021, 41(6): 43-50.
Table 1
Specific surface area, pore structure parameters and element content of samples"
样品1) sample | 比表面积/(m2·g-1) specific surface area | 总孔容/(cm3·g-1) total pore volume | 微孔孔容/(cm3·g-1) micropore volume | 介孔孔容/(cm3·g-1) mesopore volume | N/% | B/% |
DAC | 2280 | 1.12 | 0.72 | 0.4 | — | — |
BNC2-190-30 | 2365 | 1.12 | 0.78 | 0.34 | 2.20 | 1.04 |
BNC4-190-30 | 2619 | 1.23 | 0.83 | 0.40 | 2.35 | 1.82 |
BNC6-190-30 | 2859 | 1.34 | 0.99 | 0.35 | 2.53 | 3.12 |
BNC8-190-30 | 2347 | 1.11 | 0.79 | 0.32 | 2.56 | 3.20 |
BNC6-180-30 | 2090 | 1.00 | 0.76 | 0.24 | 2.20 | 2.56 |
BNC6-190-30 | 2859 | 1.34 | 0.99 | 0.35 | 2.53 | 3.12 |
BNC6-200-30 | 2698 | 1.30 | 0.89 | 0.41 | 2.52 | 3.27 |
BNC6-190-10 | 2176 | 1.08 | 0.76 | 0.32 | 2.33 | 1.13 |
BNC6-190-20 | 2184 | 1.06 | 0.73 | 0.33 | 2.55 | 2.31 |
BNC6-190-30 | 2859 | 1.34 | 0.99 | 0.35 | 2.53 | 3.12 |
BNC6-190-40 | 2614 | 1.30 | 0.86 | 0.44 | 2.60 | 3.18 |
Table 2
Specific capacitance of all samples under different current densities"
样品 sample | 不同电流密度下的比电容specific capacitance at different current densities/(F·g-1) | 倍率性能/% rate performance | ||||
1 A/g | 2 A/g | 5 A/g | 10 A/g | 20 A/g | ||
DAC | 274 | 224 | 203 | 190 | 180 | 65.7 |
BNC2-190-30 | 232 | 196 | 180 | 170 | 160 | 69.0 |
BNC4-190-30 | 311 | 258 | 235 | 220 | 200 | 64.3 |
BNC6-190-30 | 369 | 314 | 285 | 270 | 240 | 65.0 |
BNC8-190-30 | 232 | 188 | 175 | 160 | 140 | 60.3 |
BNC6-190-10 | 175 | 160 | 140 | 130 | 120 | 64.9 |
BNC6-190-20 | 302 | 244 | 223 | 210 | 200 | 66.2 |
BNC6-190-30 | 369 | 314 | 285 | 270 | 240 | 65.0 |
BNC6-190-40 | 211 | 176 | 160 | 150 | 140 | 66.4 |
BNC6-180-30 | 307 | 242 | 225 | 210 | 200 | 65.1 |
BNC6-190-30 | 369 | 314 | 285 | 270 | 240 | 65.0 |
BNC6-200-30 | 263 | 214 | 195 | 190 | 180 | 68.4 |
1 | LUO L, ZHOU Y, YAN W, et al. Two-step synthesis of B and N co-doped porous carbon composites by microwave-assisted hydrothermal and pyrolysis process for supercapacitor application[J/OL]. Electrochimica Acta, 2020, 360: 1-11[2020-03-03]. https://doi.org/10.1016/j.electacta.2020.137010. |
2 |
HAO J , WANG J , QIN S , et al. B/N co-doped carbon nanosphere frameworks as high-performance electrodes for supercapacitors[J]. Journal of Materials Chemistry A, 2018, 6, 8053- 8058.
doi: 10.1039/C8TA00683K |
3 |
LI H L , HE Y , PAVLINEK V , et al. MnO2 nanoflake/polyaniline nanorod hybrid nanostructures on graphene paper for high-performance flexible supercapacitor electrodes[J]. Journal of Materials Chemistry A, 2015, 3 (33): 17165- 17171.
doi: 10.1039/C5TA04008F |
4 | 季张林, 徐永华. 超级电容器在新能源汽车中的运用[J]. 电子技术与软件工程, 2018, 143 (21): 224. |
JI Z L , XU Y H . Application of supercapacitors in new energy vehicles[J]. Electronic Technology and Software Engineering, 2018, 143 (21): 224. | |
5 | 余稀, 但涛. 超级电容器在电动汽车中的应用[J]. 电子元件与材料, 2014, 33 (1): 81- 82. |
YU X , DAN T . Application of supercapacitors in electric vehicles[J]. Electronic Components and Materials, 2014, 33 (1): 81- 82. | |
6 |
CHEN H , XIONG H , YU T , et al. Boron and nitrogen co-doped porous carbon with a high concentration of boron and its superior capacitive behavior[J]. Carbon, 2017, 113, 266- 273.
doi: 10.1016/j.carbon.2016.11.035 |
7 |
许升, 吕宗泽, 易雪亭, 等. 纸基炭电极材料的制备及其电化学性能研究[J]. 林产化学与工业, 2018, 38 (6): 42- 50.
doi: 10.3969/j.issn.0253-2417.2018.06.006 |
XU S , LYU Z Z , YI X T , et al. Preparation and electrochemical properties of paper-based carbon electrode materials[J]. Chemistry and Industry of Forest Products, 2018, 38 (6): 42- 50.
doi: 10.3969/j.issn.0253-2417.2018.06.006 |
|
8 |
南静娅, 张盖同, 王利军, 等. 离子液体基凝胶电解质的制备及其在超级电容器中的应用[J]. 林产化学与工业, 2020, 40 (4): 17- 23.
doi: 10.3969/j.issn.0253-2417.2020.04.003 |
NAN J Y , ZHANG G T , WANG L J , et al. Preparation of ionic liquid based gel electrolyte and its supercapacitors application[J]. Chemistry and Industry of Forest Products, 2020, 40 (4): 17- 23.
doi: 10.3969/j.issn.0253-2417.2020.04.003 |
|
9 |
ZHAO W , LUO L , WU X , et al. Facile and low-cost heteroatom-doped activated biocarbons derived from fir bark for electrochemical capacitors[J]. Wood Science and Technology, 2019, 53, 227- 248.
doi: 10.1007/s00226-018-1065-3 |
10 |
ZOU X , WU D , MU Y , et al. Boron and nitrogen co-doped holey graphene aerogels with rich BeN motifs for flexible supercapacitors[J]. Carbon, 2020, 159, 94- 101.
doi: 10.1016/j.carbon.2019.12.018 |
11 |
吴登鹏, 姚路, 林烨, 等. 氮掺杂活性炭的制备及其性能研究[J]. 电源技术, 2019, 43 (9): 1478- 1481.
doi: 10.3969/j.issn.1002-087X.2019.09.019 |
WU D P , YAO L , LIN Y , et al. Preparation and properties of nitrogen-doped activated carbon[J]. Chinese Power of Power Sources, 2019, 43 (9): 1478- 1481.
doi: 10.3969/j.issn.1002-087X.2019.09.019 |
|
12 |
LI Z , LI Y F , WANG L , et al. Assembling nitrogen and oxygen co-doped graphene quantum dots onto hierarchical carbon networks for all-solid-state flexible supercapacitors[J]. Electrochimica Acta, 2017, 235, 561- 569.
doi: 10.1016/j.electacta.2017.03.147 |
13 |
CHABAN V , PREZHDO O V . Boron doping of graphene-pushing the limit[J]. Nanoscale, 2016, 8 (34): 15521- 15528.
doi: 10.1039/C6NR05309B |
14 |
LI S , WANG Z , JIANG H , et al. Plasmainduced highly efficient synthesis of boron doped reduced graphene oxide for supercapacitors[J]. Chemical Communications, 2016, 52 (73): 10988- 10991.
doi: 10.1039/C6CC04052G |
15 | ZHOU Y, YAN W, YU X, et al. Boron and nitrogen co-doped porous carbon for supercapacitors: A comparison between a microwave-assisted and a conventional hydrothermal process[J/OL]. Journal of Energy Storage, 2020, 32: 1-9[2020-03-03]. https://doi.org/10.1016/j.est.2020.101706. |
16 |
KANNAN A , SAMUTHIRAPANDIAN A , KIM D . Electric double layer capacitors employing nitrogen and sulfur co-doped, hierarchically porous graphene electrodes with synergistically enhanced performance[J]. Journal of Power Sources, 2017, 337, 65- 72.
doi: 10.1016/j.jpowsour.2016.10.109 |
17 |
RUNAUER S , EMMET P H , TELLER E . Adsorption of gases in multimolecular layers[J]. Journal of the American Chemical Society, 1938, 60 (2): 309- 319.
doi: 10.1021/ja01269a023 |
18 | TARAZONA P . Solid-fluid transition and interfaces with density functional approaches[J]. Surface Science, 1995, 331, 989- 994. |
19 | ZHOU Y, JIA Z, SHI L, et al. Pressure difference-induced synthesis of P-doped carbon nanobowls for high-performance supercapacitors[J/OL]. Chemical Engineering Journal, 2020, 385: 1-11[2020-03-03]. https://doi.org/10.1016/j.cej.2019.123858. |
20 | CHEN T, ZHOU Y, LUO L, et al. Preparation and characterization of heteroatom self-doped activated biocarbons as hydrogen storage and supercapacitor electrode materials[J/OL]. Electrochimica Acta, 2019, 325: 1-10[2020-03-03]. https://doi.org/10.1016/j.electacta.2019.134941. |
21 |
LI Y , WANG G , WEI T , et al. Nitrogen and sulfur co-doped porous carbon nanosheets derived from willow catkin for supercapacitors[J]. Nano Energy, 2016, 19, 165- 175.
doi: 10.1016/j.nanoen.2015.10.038 |
22 | LU Y, LI Z, BAI Z, et al. High energy-power Zn-ion hybrid supercapacitors enabled by layered B/N co-doped carbon cathode[J/OL]. Nano Energy, 2019, 66: 1-9[2020-03-03]. https://doi.org/10.1016/j.nanoen.2019.104132. |
23 |
GENG Q , HUANG G , LIU Y , et al. Facile synthesis of B/N co-doped 2D porous carbon nanosheets derived from ammonium humate for supercapacitor electrodes[J]. Electrochimica Acta, 2019, 298, 1- 13.
doi: 10.1016/j.electacta.2018.12.038 |
24 | XU L, LI X Y, LI X. Large-sized and ultrathin biomass-derived hierarchically porous carbon nanosheets prepared by a facile way for high-performance supercapacitors[J/OL]. Applied Surface Science, 2020, 526: 1-11[2020-03-03]. https://doi.org/10.1016/j.apsusc.2020.146770. |
25 |
GONG Y , LI D , LUO C , et al. Highly porous graphitic biomass carbon as advanced electrode materials for supercapacitors[J]. Green Chemistry, 2017, 19 (17): 4132- 4140.
doi: 10.1039/C7GC01681F |
26 |
GUO H , GAO Q . Boron and nitrogen co-doped porous carbon and its enhanced properties as supercapacitor[J]. Journal of Power Sources, 2009, 186, 551- 556.
doi: 10.1016/j.jpowsour.2008.10.024 |
[1] | Kainan JIN, Songlin ZUO, Youcai GUI, Baoshou SHEN, Shanshan WANG, Nannan CUI. Studies on Lignin-based Carbon Materials as Electrocatalysts of Fuel Cells Cathode Ⅳ: Preparation and Electrocatalytic Properties for Oxygen Reduction Reaction [J]. Chemistry and Industry of Forest Products, 2021, 41(6): 27-35. |
[2] | JIAN Xiaopeng, HOU Xinglong, XU Wei, LIU Shicai. Effect of Pore Structure of Activated Carbon on Adsorption and Desorption of CS2 [J]. Chemistry and Industry of Forest Products, 2021, 41(6): 90-96. |
[3] | Youqi HAN, Jiaxin NI, Xiaolin HUANG, Yudong LI, Guiquan JIANG, Shiyan HAN. Preparation and Photocatalytic Performance of CQDs/TiO2 [J]. Chemistry and Industry of Forest Products, 2021, 41(5): 58-64. |
[4] | Haonan CHEN, Ting YU, Yali ZHOU, Xiping LEI, Xiaolin GUAN. Research Progress on Electrode Materials from Activated Carbon-based Supercapacitors [J]. Chemistry and Industry of Forest Products, 2021, 41(5): 113-125. |
[5] | Qiong WANG, Xuan YANG, Zhenghan CAI, Yandan CHEN, Biao HUANG, Guanfeng LIN. Preparation of Multi-doped Activated Carbon Based on Alkali/Thiourea Synergistic Activation [J]. Chemistry and Industry of Forest Products, 2021, 41(4): 77-84. |
[6] | Lu LUO, Lingcong LUO, Jianping DENG, Mizi FAN, Guanben DU, Weigang ZHAO. Preparation of Activated Carbons from Palm Shell by Response Surface Optimization Design and Its Hydrogen Storage Performance [J]. Chemistry and Industry of Forest Products, 2021, 41(4): 92-100. |
[7] | Xuan YANG, Xinyu ZHENG, Jianhua LYU, Hao YING, Biao HUANG, Guanfeng LIN. Preparation of Nitrogen-doped Activated Carbon from Alkali/Urea Dissolution System and Its Electrochemical Properties [J]. Chemistry and Industry of Forest Products, 2021, 41(2): 10-16. |
[8] | Kun ZHANG,Zhou XU,Wei LI,Shouxin LIU. Preparation of Urea/Nicotinamide Modified Activated Carbon and Its Formaldehyde Adsorption Performance [J]. Chemistry and Industry of Forest Products, 2020, 40(5): 75-82. |
[9] | Wei XU,Junli LIU,Xianlun DENG,Yunjuan SUN,Yu XU,Guanghua LIU. Preparation of Formed Activated Carbon Based on Residual Carbon Powder from Biomass Gasification [J]. Chemistry and Industry of Forest Products, 2020, 40(5): 91-98. |
[10] | Tingting ZHANG,Xiuli HAN,Ying LIU,Chunling DONG,Chun CHANG. Adsorption Characteristics of Ciprofloxacin by Biomass-based Activated Carbon [J]. Chemistry and Industry of Forest Products, 2020, 40(4): 71-78. |
[11] | Hao SUN,Dali ZHAO,Yanren JIN,Yanyan LIU,Jianchun JIANG,Haoyang XING. Effect of Pore Structure on HCN Defence Performance of Activatied Carbon Supported Metallic Oxide Catalyst [J]. Chemistry and Industry of Forest Products, 2020, 40(3): 39-44. |
[12] | Xinglong HOU,Qi GUO,Xiaopeng JIAN,Dichao WU,Wei XU,Junli LIU. Optimization of Design of Lignin-based Activated Carbon Based on Response Surface Methodology [J]. Chemistry and Industry of Forest Products, 2020, 40(3): 115-122. |
[13] | Ao WANG,Kang SUN,Jianchun JIANG,Guanghua LIU. Application of Woody Activated Carbon in Refining of Rice Bran Oil [J]. Chemistry and Industry of Forest Products, 2020, 40(2): 25-32. |
[14] | Yuxuan LIU,Dipan XUAN,Jiajia LI,Shuirong LI,Haiyong TANG,Zhifeng ZHENG. Preparation of Graphene Modified Coconut Shell Activated Carbon Composite and Its Electrochemical Performance [J]. Chemistry and Industry of Forest Products, 2020, 40(1): 61-67. |
[15] | SUN Hao, SUN Kang, JIANG Jianchun, XU Wei, ZHANG Yanping. Self-activation Mechanism for Preparation of Bamboo Derived High Performance Activated Carbon Under Micro-posotive Pressure [J]. Chemistry and Industry of Forest Products, 2019, 39(5): 19-25. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||