Chemistry and Industry of Forest Products ›› 2022, Vol. 42 ›› Issue (2): 80-86.doi: 10.3969/j.issn.0253-2417.2022.02.011
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Xiuqiang CHEN, Xixin DUAN, Junyou SHI()
Received:
2021-02-24
Online:
2022-04-28
Published:
2022-05-06
Contact:
Junyou SHI
E-mail:bhsjy@163.com
CLC Number:
Xiuqiang CHEN, Xixin DUAN, Junyou SHI. Investigation on Degradation of Cellulose to Formic Acid Catalyzed by Molybdenum-vanadium Polyoxometalates[J]. Chemistry and Industry of Forest Products, 2022, 42(2): 80-86.
Table 1
Performance comparison of formic acid preparation from biomass catalyzed by different polyacids"
序号 No. | 原料 raw material | 催化剂/g catalyst | 时间/h time | 温度/℃ temp. | O2压力/MPa O2 pressure | 转化率/% conversion | FA产率/% FA yield | 文献 document |
1 | 木糖 xylose | 0.1 g Na6[α-Mo6V2O26] | 0.5 | 140 | 1 | 100 | 63 | 本研究 this study |
2 | 葡萄糖 glucose | 0.1 g Na6[α-Mo6V2O26] | 0.5 | 140 | 1 | 100 | 60 | 本研究 this study |
3 | 对甲苯磺酸 p-toluene sulfonic acid | 0.1 g Na6[α-Mo6V2O26] | 4 | 140 | 1 | 0 | 0 | 本研究 this study |
4 | 纤维素 cellulose | 0.1 g Na6[α-Mo6V2O26] | 3 | 140 | 1 | 52 | 8.6 | 本研究 this study |
5 | 纤维素 cellulose | 0.1 g Na6[α-Mo6V2O26]+ 0.15 g对甲苯磺酸 p-toluene sulfonic acid | 3 | 140 | 1 | 98 | 47 | 本研究 this study |
6 | 纤维素 cellucosse | 0.4 g H5PV2Mo10O40 | 9 | 170 | 空气air | 100 | 34 | [ |
7 | 纤维素 cellucose | 1.82 g H8PV5Mo7O40 | 24 | 90 | 3 | 76 | 28 | [ |
8 | 纤维素 cellucose | 0.05 g NH4VO3/ZSM-5 | 8 | 180 | 3 | — | 19 | [ |
9 | 纤维素 cellucose | 0.02 g VOSO4 | 2 | 160 | 2 | — | 39 | [ |
10 | 杨木木屑 poplar | 0.07 g H5PV2Mo10O40 | 26 | 80 | 3 | — | 11 | [ |
11 | 榉木 beech | 0.12 g K5V3W3O19 | 72 | 115 | 5 | 50 | 12.5 | [ |
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