脱氢枞酸与二甲亚砜反应产物表征及反应机理研究

doi:10.3969/j.issn.0253-2417.2013.06.005

›› 2013, Vol. 33 ›› Issue (6): 25-28.doi: 10.3969/j.issn.0253-2417.2013.06.005

• 1研究报告 • Previous Articles Next Articles

Structural Characterization of Reaction Product of Dehydroabietic Acid and DMSO and Its Reaction Mechanism

NIE Yuan-mei¹, WANG Ying¹, SHEN Li-qun¹, YAO Xing-dong^1,2

1. School of Chemistry & Chemical Engineering, Guangxi University for Nationalities, Nanning 530006, China;2. Key Laboratory of Forest Chemistry & Engineering of Guangxi, Guangxi University for Nationalities, Nanning 530006, China

Received:2012-12-24 Revised:1900-01-01 Online:2013-12-30 Published:2013-12-30

Abstract

Abstract: The reaction of dehydroabietic acid and DMSO produced a new compound when they were heated to 215 ℃ for 3 h in the presence of KOH catalyst. The structure of the reaction product has been characterized by UV, IR, NMR and MS analysis to be methylthiomethyl dehydroabietate. The possible reaction mechanism has been proposed based on the reaction between DMSO and acetic acid or acetic anhydride. The acid was firstly dehydrated to form acid anhydride. Then it reacted with DMSO to produce the ester via. Pummerer rearrangement.

Key words: dehydroabietic acid, DMSO, characterization

CLC Number:

TQ35
O621.3

NIE Yuan-mei;WANG Ying;SHEN Li-qun;YAO Xing-dong;. Structural Characterization of Reaction Product of Dehydroabietic Acid and DMSO and Its Reaction Mechanism[J]. , 2013, 33(6): 25-28.

[1]	CHEN Yan, WANG Zixin, LI Qizhen, XIA Jianyu, LIU Zhulan, CAO Yunfeng. Synthesis and Characterization of Lignocellulose Oil-absorbing Aerogels [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 49-55.
[2]	LU Yanju, ZHAO Zhendong, WANG Jing, XU Shichao, BI Liangwu, CHEN Yuxiang. Synthesis and Biological Activity of Isopimaric Furfural Acylhydrazone Derivatives [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 43-48.
[3]	LUO Yunlong, SHEN Minggui, CAI Zhaosheng, SHANG Shibin, SONG Zhanqian. Synthesis and Antiviral Activity Evaluation of Dehydroabietic Acid Amide Derived 3,4-Dihydropyrimidinthiones [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 46-52.
[4]	TAN Guanni, GAO Yanan, GAO Hong, SHANG Shibin, SONG Zhanqian. Synthesis and Spectra Performance of Dehydroabietic Acid-based Triarylamine with Double Naphthalenes [J]. Chemistry and Industry of Forest Products, 2019, 39(1): 61-66.
[5]	ZHOU Fanglang, ZHENG Zhifeng, YANG Jing, YANG Haiyan, DENG Jia, SHI Zhengjun. Preparation and Characterization of Lignin Based Phenolic Foam [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 103-109.
[6]	HUANG Jing, BAO Han, ZHANG Xia, MO Yue, LUO Jinyue, LIU Zuguang. Synthesis and Characterization of 3'-(3,3-Dimethylbicyclo[2.2.1] hept-2-ylidene)-5'-phenyl-isoxazoline [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 110-116.
[7]	QI Zhiwen, WANG Chengzhang, JIANG Jianxin. Synthesis and Anticancer Activity of Dehydroabietyl Primary Amine Derivatives [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 117-123.
[8]	SHI Chun, LI Tiancheng, YANG Jing, YANG Haiyan, DENG Jia, SHI Zhengjun. Preparation and Characterization of Cellulose Acetate Films Derived from Bamboo [J]. Chemistry and Industry of Forest Products, 2018, 38(5): 70-76.
[9]	LIU Dandan, HAN Weifan, JIANG Jianxin, ZHU Liwei. Technology of Microwave-assisted Extraction of Sapindus Peel Polysaccharide and Its Antioxidant Activity [J]. Chemistry and Industry of Forest Products, 2018, 38(4): 109-116.
[10]	WANG Xuan, LIU Zhu, ZHANG Yaoli, PAN Biao. Characterization Methods of Wood Ultrastructure and Its Research Progress [J]. Chemistry and Industry of Forest Products, 2018, 38(2): 1-10.
[11]	LI Qiaoguang, LIU He, LI Jianfang, SHANG Shibin, SONG Zhanqian. Synthesis of Rosin Based Crosslinking Agent and Its Effect on Properties of Cured Silicone Rubber [J]. Chemistry and Industry of Forest Products, 2018, 38(2): 87-93.
[12]	LU Chuanwei, LIU Shaofeng, WANG Chunpeng, CHU Fuxiang, WANG Jifu. Synthesis and Characterization of Thermoplastic Materials Derived from Cellulose, Furfural and Grease [J]. Chemistry and Industry of Forest Products, 2017, 37(6): 43-48.
[13]	WANG Peng, QIN Ying, FU Yingjuan, WANG Zhaojiang, ZHANG Fengshan. Structural Character of Dissolved and Colloidal Lignin in Hydrolysate from Poplar Woodchips Autohydrolysis [J]. Chemistry and Industry of Forest Products, 2017, 37(4): 59-66.
[14]	LIU Shaofeng, LU Chuanwei, WANG Chunpeng, CHU Fuxiang, WANG Jifu. Synthesis and Characterization of 2-Methacryloyloxyisopro-panol Ester of Dehydroabietic Acid [J]. Chemistry and Industry of Forest Products, 2017, 37(4): 89-94.
[15]	BO Caiying, HU Lihong, YANG Xiaohui, ZHENG Minrui, ZHANG Meng, ZHOU Yonghong. Preparation and Characterization of Phenolic Foams Modified by Lignin-based Polyurethane Prepolymers [J]. Chemistry and Industry of Forest Products, 2017, 37(1): 63-72.

Structural Characterization of Reaction Product of Dehydroabietic Acid and DMSO and Its Reaction Mechanism

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments