木质素模型化合物与松柏醇-β-D-葡萄糖苷-[α-13C]的聚合反应的研究

›› 2009, Vol. 29 ›› Issue (1): 1-6.

• 研究报告 • Next Articles

Study on Co-polymerization of Coniferin with Model Compound of Lignin

ZHAO Fang^1,2, XIE Yi-min¹, WANG Song^1,3, WANG Peng⁴

1. Key Lab of Paper Science and Technology of Education Ministry, Shandong Institute of Light Industry, Jinan 250353, China;2. Shandong Paper Industry Research & Design Institute, Jinan 250100, China;3. Shandong Bohui Paper Industrial Co.Ltd.Zibo 256405 China;4. Putian City Product Quality Supervision & Inspection Institute, Putian 351100, China

Received:2008-01-22 Revised:1900-01-01 Online:2009-02-28 Published:2009-02-28

Abstract

Abstract: In order to explore the mechanism of polymerization between lignin from effluent of pulping process and lignin precursors, the method and mechanism of co-polymerization of coniferin with model compound of β-O-4 type lignin were investigated. The characteristics of polymerization product were analyzed by FT-IR, ¹³CNMRand gel permeation chromatography(GPC). Polarized microscopy was applied to observe the products. Moreover, GPC was used to determine mumber-average molecular mass (Mn) of the polymerization product. The results showed that coniferin could completely polymerize with model compound of β-O-4 type lignin to form lignin macromolecule. The Mn of the polymerized product was much higher than the starting materials. There was no crystalline starting material in the obtained polymer. These results could be the basis of waste-water treatment using coniferin and enzymes.

Key words: lignin, coniferin, model compound of lignin, polymerization

CLC Number:

TQ351.013

ZHAO Fang;XIE Yi-min;WANG Song;WANG Peng. Study on Co-polymerization of Coniferin with Model Compound of Lignin[J]. , 2009, 29(1): 1-6.

[1]	ZHANG Qingtong, YUN Xiaojing, YAN Depeng, LI Mingfu, WANG Shuangfei, MIN Douyong. Preparation of Sliver Nanoparticles by Lignin Under Solar Light Irradiation [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 35-41.
[2]	SUN Yongchang, ZHANG Bingqing, LIU Liming, LIU Xiaonan, SHI Zhengjun. Preparation of Lignin-based Carbon Material and Adsorption Mechanism of Cr(VI) from Wastewater [J]. Chemistry and Industry of Forest Products, 2019, 39(4): 120-128.
[3]	CHEN Chao, WANG Ao, SUN Kang, LU Xincheng, XU Wei, JIANG Jianchun. Graphitization of Biomass Catalyzed by Ni [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 94-100.
[4]	CHENG Zenghui, ZHANG Daihui, WANG Jifu, WANG Chunpeng, CHU Fuxiang, XU Feng. Preparation of Monodisperse Rosin-based Polymer Microspheres by Dispersion Polymerization [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 39-45.
[5]	ZHAO Cunyi, YING Wenjun, SHI Zhengjun, YANG Haiyan, ZHENG Zhifeng, YANG Jing. Preparation of Hydroxypropylated Alkali Lignin and Its Effect on Hydrolysis Efficiency of Cellulase [J]. Chemistry and Industry of Forest Products, 2019, 39(2): 109-114.
[6]	XU Lina, YANG Xiaohua, DING Haiyang, LI Mei, XIA Jianling. Synthesis and Properties of Oxidative Modified Satium Lignosulfonate/Graphene Quantum Dots Composites [J]. Chemistry and Industry of Forest Products, 2019, 39(1): 29-34.
[7]	LI Jihui, SUN Kang, SONG Yaoguang, WANG Ao, JIANG Jianchun. Preparation of Lignin-based Carbon Nanosheet and Its Electrochemical Property [J]. Chemistry and Industry of Forest Products, 2019, 39(1): 67-74.
[8]	WANG Guangbin, CHEN Jiabao, GU Limin, WANG Chunpeng, XU Yuzhi. Synthesis and Characterization of Lignin Based Chain Transfer Agent Used for RAFT Polymerization [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 75-80.
[9]	ZHOU Fanglang, ZHENG Zhifeng, YANG Jing, YANG Haiyan, DENG Jia, SHI Zhengjun. Preparation and Characterization of Lignin Based Phenolic Foam [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 103-109.
[10]	JIA Zhuan, WAN Guangcong, LI Mingfu, LUO Bin, WANG Shuangfei, MIN Douyong. Fractionation and Characterization of Sugarcane Bagasse Kraft Lignin [J]. Chemistry and Industry of Forest Products, 2018, 38(5): 107-114.
[11]	YANG Xiaohui, SHANG Qianqian, JIA Puyou, ZHOU Yonghong. Properties of Phenolic Foam Modified by Lignin Depolymerized in Molten Salt Hydrate [J]. Chemistry and Industry of Forest Products, 2018, 38(5): 115-121.
[12]	FENG Nianjie, WANG Jiming, XIE Yimin, YANG Xin, LIU Da'an. Regulating Effect of P-factor on Lignin Mass Concentration in Prehydrolysis Liquor of Triploid Poplar [J]. Chemistry and Industry of Forest Products, 2018, 38(4): 35-40.
[13]	YE Jiewang, JIANG Jianchun, JIN Zhenfu, ZHANG Weigang, ZHANG Xiaochun. Depolymerization of Lignin Catalyzed by Complex Metal Oxide in Supercritical Methanol [J]. Chemistry and Industry of Forest Products, 2018, 38(4): 52-60.
[14]	YANG Sheng, WANG Jun, LI Gaiyun, FAN Dongbin. Molecular Structure and Curing Characteristics of Lignin-phenol-formaldehyde Resin Prepared with the Use of Magnesian Ion as Catalyst [J]. Chemistry and Industry of Forest Products, 2018, 38(4): 74-78.
[15]	YE Jiewang, JIANG Jianchun, MA Zhongqing, ZHANG Weigang, LU Fengzhu. Directional Liquefaction of Bamboo Catalyzed by Cu Doped Porous Metal Oxide [J]. Chemistry and Industry of Forest Products, 2018, 38(3): 48-54.

Study on Co-polymerization of Coniferin with Model Compound of Lignin

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments