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STUDY ON BIOACTIVE CONSTITUENTS IN ALCOHOLIC FRACTIONS OF MONTAN RESINS FROM BROWN COAL WAXES
LI Bao-cai;ZHANG Hui-fen;BI Li;XIN Xiao-yan;BU Yi-sun
2004, 24 (3):
73-77.
To explore the possibilities of utilizing montan resins as a Chinese medicine,the alcoholic fractions of montan resins isolated from brown coal waxes which were extracted from Liaohu,Xundian(Yunnan) and Shulan(Jilin) brown coals were studied by gas chromatography-spectrometry.The experimental results show that alcoholic fractions in montan resins mainly consist of normal long chain alcohols of carbon number C15-C30(C22,C24,C26 as major constituents for the series),long chain ketones of carbon number C18,C23,C25,C27,C29 and 15-hentriacotanone,sterols,pentacyclic triterpene alcohols and pentacyclic triterpene ketones.Alcoholic fractions from Xundian and Liaohu contain 24-methyl-5β(H)-cholestane-3β-ol(C28H50O,MW 402), 24-ethyl-cholest-5,22-dien-3β-ol(C29H48O,MW 412),24-ethyl-5α(H)-cholestane-3β-ol(C29H52O,MW 416), 23,24-dimethyl-cholest-5-en-3β-ol(C29H50O,MW 414),C29-5β(H),3β(OH)-sterol(C29H52O,MW 416), 24-isopropyl-cholest-5,24(28)E-dien-3β-ol(C30H50O,MW 426),etc.,at a relatively abundant amount.However sterols are almost absent or in very trace amount in Shulan montan resin.Based on their chemical constituents Xundian and Liaohu brown coal resins would be probably a resource as Chinese medicine.
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