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›› 2006, Vol. 26 ›› Issue (1): 15-18.

• 研究报告 • Previous Articles     Next Articles

Study on Application of Urushiol-metal Polymer for Catalytic Synthesis of Isoamyl Acetate

LI Guo-xiang1,2, DAN You-meng1, YANG Chun-hai1, SHI Bo-an1   

  1. 1. School of Chemistry and Environmental Engineering, Hubei Institute for Nationalities, Enshi 445000, China;2. School of life, Yunnan Normal University, Kunming 650092, China
  • Received:2004-09-13 Revised:1900-01-01 Online:2006-03-30 Published:2006-03-30

Abstract: A series of urushiol-metal polymers were synthesized and their properties were characterized by IR method,in which urushiol-Fe-C polymer was used as catalyst to synthesize isoamyl acetate. Factors affecting esterification yield such as material ratio,time of reaction and catalyst have been studied. The optimum conditions are as follows: material ratio of isoamyl alcohol to glacial acetic 0.6:1; dosage of catalyst 2.3%-3.4% of isoamyl alcohol; reaction time 3 h; yield of isoamyl acetate(IA) 88%.The purity of product is 99.5%. This catalyst has the advantage of less corrosion and can be reused.

Key words: urushiol-metal polymer, isoamyl acetate, catalytic synthesis

CLC Number: