蔗渣浆全无氯清洁漂白生产实践

doi:10.3969/j.issn.0253-2417.2014.06.011

林产化学与工业 ›› 2014, Vol. 34 ›› Issue (6): 69-74.doi: 10.3969/j.issn.0253-2417.2014.06.011

蔗渣浆全无氯清洁漂白生产实践

何水淋, 李军, 李智, 徐峻, 莫立焕

华南理工大学制浆造纸工程国家重点实验室, 广东广州 510640

收稿日期:2013-10-21 出版日期:2014-12-25 发布日期:2015-08-18
通讯作者: 徐峻,男,博士,硕士生导师,主要从事制浆造纸新技术与植物资源利用方面的研究工作;E-mail:xujun@scut.edu.cn. E-mail:xujun@scut.edu.cn
作者简介:何水淋(1987-)女,广西桂林人,硕士生,主要从事纸浆清洁生产技术的研究
基金资助:
国家重点基础研究发展计划项目(2010CB732205);华南理工大学制浆造纸工程国家重点实验室开放基金(201356)

Production Practice of Total Chlorine Free Clean Bleaching Bagasse Pulp

HE Shui-lin, LI Jun, LI Zhi, XU Jun, MO Li-huan

State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China

Received:2013-10-21 Online:2014-12-25 Published:2015-08-18

摘要/Abstract

摘要： 总结了蔗渣浆清洁漂白生产线运行全无氯(OpQPo)流程时的小试实验、流程设计及生产实践经验.结果表明:未漂蔗渣浆经强化氧脱木质素处理之后,卡伯值从14.0~15.0降至7.0~7.3,脱木质素率达到50%~51%,白度则从42%~45%(ISO,下同)提高至58%~60%,生产运行效果优于小试实验;经后续预处理和压力过氧化氢漂白之后,纸浆产品白度达到80%以上,黏度在800 mL/g以上,产品质量明显优于传统氯气漂白-碱处理-次氯酸盐漂白(CEH)漂白;漂白过程不产生有毒有害的可吸附有机卤化物(AOX),且仅螯合预处理(Q)段有废水排放,废水色度低、污染负荷轻,易处理,可达标排放;相对传统漂白,新技术的实施并不会增加运行费用,主体设备投资约为1 355万元人民币.

关键词: 蔗渣浆, 全无氯漂白, 生产实践, 可吸附有机卤化物

Abstract: The experimental research, process design and production practice of total chlorine free OpQPo bleaching bagasse pulp were introduced in this paper. The results showed that Kappa number decreased from 14.0-15.0 to 7.0-7.3 with a 50%-51% removal of residual lignin, and pulp brightness increased from 42%-45%(ISO) to 58%-60%(ISO) after a strengthened oxygen delignification. The production practice showed a better performance than that in lab. After subsequent pretreatment and pressurized hydrogen peroxide bleaching, the final pulp brightness was beyond 80% and the viscosity was over 800 mL/g. The pulp quality was much better than traditional Chlorine-Alkali Extraction-Hypochlorite(CEH) bleached pulp. Moreover, adsorbable organic halides (AOX) was not generated any more in the bleaching process. The wastewater was only discharged in chelating pretreatment (Q) stage and easily treated to meet the critical discharge standard due to its lower chromaticity and lower pollution load. In contrast to the traditional bleaching, no additional investment was needed in this new technology. Besides, the production procedure was flexible and the operation was stable. The investment of main equipments was about ￥13.55 million yuan.

Key words: bagasse pulp, OpQPo bleaching, production practice, AOX

中图分类号:

TQ35
TS745

何水淋, 李军, 李智, 徐峻, 莫立焕. 蔗渣浆全无氯清洁漂白生产实践[J]. 林产化学与工业, 2014, 34(6): 69-74.

HE Shui-lin, LI Jun, LI Zhi, XU Jun, MO Li-huan. Production Practice of Total Chlorine Free Clean Bleaching Bagasse Pulp[J]. Chemistry and Industry of Forest Products, 2014, 34(6): 69-74.

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蔗渣浆全无氯清洁漂白生产实践

Production Practice of Total Chlorine Free Clean Bleaching Bagasse Pulp

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