微水固相法皂荚多糖胶羧甲基化改性

doi:10.3969/j.issn.0253-2417.2017.04.007

林产化学与工业 ›› 2017, Vol. 37 ›› Issue (4): 45-50.doi: 10.3969/j.issn.0253-2417.2017.04.007

微水固相法皂荚多糖胶羧甲基化改性

刘彦涛¹, 张威伟¹, 章伟岸¹, 王堃¹, 孙达峰², 蒋建新¹

1. 北京林业大学材料科学与技术学院, 林业生物质材料与能源教育部工程研究中心, 北京 100083;
2. 南京野生植物综合利用研究院, 江苏南京 210042

收稿日期:2016-11-08 出版日期:2017-08-25 发布日期:2017-09-02
通讯作者: 蒋建新,博士生导师,研究领域为林产化工及生物质能源;E-mail:jiangjx@bjfu.edu.cn E-mail:jiangjx@bjfu.edu.cn
作者简介:刘彦涛(1991-),男,河南鹤壁人,硕士生,主要从事多糖利用研究工作
基金资助:
国家重点研发计划课题（2016YFD0600803）；国家自然科学基金资助项目（31670579）

A Micro Water Solid Phase Method for Carboxylmethylation of Gleditsia sinensis Lam. Galactomannan Gum

LIU Yantao¹, ZHANG Weiwei¹, ZHANG Wei'an¹, WANG Kun¹, SUN Dafeng², JIANG Jianxin¹

1. College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, China;
2. Nanjing Institute for Comprehensive Utilization of Wild Plants, Nanjing 210042, China

Received:2016-11-08 Online:2017-08-25 Published:2017-09-02

摘要/Abstract

摘要： 以氯乙酸（MAC）为醚化试剂，NaOH为碱化试剂，采用微水固相法对皂荚多糖胶（GSG）进行羧甲基化改性，比较了不同NaOH加入量对羧甲基化皂荚多糖胶（CMGSG）取代度、相对分子质量和黏度的影响，并研究了CMGSG对生活污水的絮凝效果。结果表明：当n（GSG）：n（NaOH）：n（MAC）1：1：1，60℃下反应12 h时，CMGSG取代度（Ds）0.16，相对分子质量1.385×10⁶，此改性多糖胶液用于处理人工模拟生活污水，具有较好的絮凝能力，处理后的污水的最小浊度为20.2 NTU。微水固相法羧甲基化改性可以在无溶剂体系和较少反应试剂条件下达到改性效果。

关键词: 皂荚多糖胶, 羧甲基化, 微水固相改性, 絮凝能力

Abstract: In this study, the micro water solid phase method was used in the carboxymethylation of Gleditsia sinensis Lam. galactomannan (GSG). monochloroacetic acid(MAC) and NaOH were used as the chemical modification reagents to prepare the carboxymethylated G. sinensis galactomannan (CMGSG). The degree of substitution(Ds), Flocculation performance, molecular weight (M_w), viscosity of CMGSG treat with different concentrations of NaOH were investigated. The results showed that when n(GSG):n(NaOH):n(MAC)=1:1:1, the reaction temperature 60℃ and reaction time 12 h,the Ds of the product reached 0.16,with the molecular weight of 1.385×10⁶. CMGSG purified the synthetic wastewater with the minimum turbidity of 20.2 NTU, indicating of a better flocculation performance. The micro water solid phase method had a positive effect on modification of GSG in solvent free system and less reaction reagent.

Key words: Gleditsia sinensis Lam.galactomannan, carboxymethylation, microwater solid phase modification, flocculation performance

中图分类号:

TQ35

刘彦涛, 张威伟, 章伟岸, 王堃, 孙达峰, 蒋建新. 微水固相法皂荚多糖胶羧甲基化改性[J]. 林产化学与工业, 2017, 37(4): 45-50.

LIU Yantao, ZHANG Weiwei, ZHANG Wei'an, WANG Kun, SUN Dafeng, JIANG Jianxin. A Micro Water Solid Phase Method for Carboxylmethylation of Gleditsia sinensis Lam. Galactomannan Gum[J]. Chemistry and Industry of Forest Products, 2017, 37(4): 45-50.

参考文献

[1] JIANG J X,JIAN H L,CRISTHIAN C,et al.Structural and thermal characterization of galactomannans from genus Gleditsia,seeds as potential food gum substitutes[J].Journal of the Science of Food & Agriculture,2011,91(4):732-737.
[2] 蒋建新,菅红磊,朱莉伟,等.功能性多糖胶开发与应用[M].中国轻工业出版社,2013. JIANG J X,JIAN H L,ZHU L W,et al.The Development and Application of Functional Polysaccharide[M].Beijing:China Light Industry Press,2013.
[3] JIAN H L,CRISTHIAN C,ZHANG W M,et al.Influence of dehulling pretreatment on physicochemical properties of Gleditsia sinensis Lam.gum[J].Food Hydrocolloids,2011,25(5):1337-1343.
[4] 蒋建新,朱莉伟,王磊,等.皂荚多糖胶α-半乳糖苷酶修饰及产物性能研究[J].林产化学与工业,2007,27(5):44-48. JAING J X,ZHU L W,WANG L,et al.Studies om modification of polysaccharide gum from Gleditsia sinensis Lam.seeds with α-galactosidase[J].Chemistry and Industry of Forest Products,2007,27(5):44-48.
[5] 章伟岸,段久芳,孙达峰,等.微水固相法氧化改性皂荚多糖胶[J].林产化学与工业,2014,34(6):44-48. ZHANG W A,DUAN J F,SUN D F,et al.A micro water solid phase method for oxidation of Gleditsia sinensis Lam.galactomannan gum[J].Chemistry and Industry of Forest Products,2014,34(6):44-48.
[6] 蒋建新,菅红磊,朱莉伟,等.植物多糖胶研究应用新进展[J].林产化学与工业,2009,29(4):121-126. JIANG J X,JIAN H L,ZHU L W,et al.Research and application progress of plant galactomannan gum[J].Chemistry and Industry of Forest Products,2009,29(4):121-126.
[7] 姜绍通,黄静,潘丽军.糯玉米淀粉羧甲基化变性及其在食品中的应用研究[J].食品科学,2003,24(10):23-25. JIANG S T,HUANG J,PAN L J.Carboxymethyl modification of waxy corn starch and its application in study on the application of food[J].Food Science,2003,24(10):23-25.
[8] 尚晓培,陈灵磑,丁世忠,等.微波辐射法在多糖接枝共聚中的应用[J].广州化工,2014,42(18):32-34. SHANG X P,CHEN L G,DING S Z,et al.Application of microwave irradiation in the grafting copolymerization of polysaccharides[J].Guangzhou Chemical Industry,2014,42(18):32-34.
[9] 万小芳,李友明,周雪松,等.瓜尔胶接枝高吸水性树脂的微波法合成[J].高分子材料科学与工程,2010,26(2):26-28. WAN X F,LI M Y,ZHOU X S,et al.Synthesis of super absorbant resin grafted by guar gum under microwave irradiation[J].Polymer Materials Science and Engineering,2010,26(2):26-28.
[10] 章伟岸.皂荚多糖胶分级纯化表征及微水固相法改性研究[D].北京:北京林业大学硕士学位论文,2015. ZHANG W A.Fractional precipitation behavior,modification in micro-water-solid-phase of Gleditsia sinensis gums[D].Beijing:Master Degree Thesis of Beijing Forestry University,2015.
[11] 蒋建新,朱莉伟,安鑫南,等.NMR法研究我国主要植物胶资源的多糖化学结构[J].林产化学与工业,2006,26(1):41-44. JIANG J X,ZHU L W,AN X N,et al.NMR studies on chemical structures of polysaccharides of the main plant-gum resources in China[J].Chemistry and Industry of Forest Products,2006,26(1):41-44.
[12] STOJANOVIC' Ž,JEREMIC' K,JOVANOVIC' S,et al.A comparison of some methods for the determination of the degree of substitution of carboxymethyl starch[J].Starch-Stärke,2005,57(2):79-83.
[13] 彭赵旭,彭永臻,刘旭亮,等.实际污水与模拟污水活性污泥系统的特性差异[J].环境工程学报,2012,6(3):749-754. PENG Z X,PENG Y Z,LIU X L,et al.Characteristic differences of activated sludge systems between real wastewater and simulated wastewater[J].Chinese Journal of Environmental Engineering,2012,6(3):749-754.
[14] TSUNEDA S,OHNO T,SOEJIMA K,et al.Simultaneous nitrogen and phosphorus removal using denitrifying phosphate-accumulating organisms in a sequencing batch reactor[J].Biochemical Engineering Journal,2006,27(3):191-196.
[15] 中华人民共和国国家环境保护局.GB/T 13200-1991水质-浊度的测定[S].北京:中国标准出版社,1991. Ministry of Environmental Protection of the People's Republic of China.GB/T 13200-1991 Water quality-determination of turbidity[S].Beijing:Standards Press of China,1991.
[16] 施建军,丁明.壳聚糖羧甲基化改性的制备研究[J].安徽化工,1998(4):26-28. SHI J J,DING M.Study on the preparation of carboxymethyl chitosan[J].Anhui Chemical Industry,1998(4):26-28.
[17] GAO W X,LIN X Q,LIN X P,et al.Preparation of nanosized flake carboxymethyl cassava starch under ultrasonic irradiation[J].Carbohydrate Polymers,2011,84(4):1413-1418.
[18] 孙兰萍,张斌,赵大庆,等.甘薯淀粉羧甲基化影响因素的研究[J].粮食与饲料工业,2007(7):22-24. SUN L P,ZHANG B,ZHAO D Q,et al.A study on effective factors for carboxymethylation of sweet potato starch[J].Cereal and Feed Industry,2007(7):22-24.
[19] 申林卉,刘丽侠,陈冠,等.苦豆子多糖羧甲基化修饰及其抗氧化活性的研究[J].天津中医药大学学报,2014,33(3):157-160. SHEN L R,LIU L X,CHEN G,et al.Carboxymethyl modification and antioxidant activity of sophora alopecuroides polysaccharide[J].Journal of Tianjin University of Traditional Chinese Medicine,2014,33(3):157-160
[20] 焦中高,刘杰超,王思新,等.羧甲基化红枣多糖制备及其活性[J].食品科学,2011,32(17):176-180. JIAO Z G,LIU J C,WANG S X,et al.Carboxymethylation of polysaccharide from Zizyphus jujuba fruits and its activity[J].Food Science,2011,32(17):176-180.
[21] HUANG Y H,YU H Q,XIAO C B.Effects of Ca²⁺,crosslinking on structure and properties of waterborne polyurethane-carboxymethylated guar gum films[J].Carbohydrate Polymers,2006,66(4):500-513.
[22] WANG L F,PAN S Y,HU H,et al.Synthesis and properties of carboxymethyl kudzu root starch[J].Carbohydrate Polymers,2010,80:174-179.
[23] 赵霞,冯辉霞,雒和明,等.半干法羧甲基瓜尔胶的快速制备及其絮凝性能[J].兰州理工大学学报,2007,33(6):65-68. ZHAO X,FENG H X,LUO H M,et al.Rapid preparation of carboxyl methyl guar with semidry processing and its flocculating property[J].Journal of Lanzhou University of Technology,2007,33(6):65-68.
[24] 钟碧疆.可溶性大豆多糖絮凝性及机理研究[D].广州:华南理工大学硕士学位论文,2011. ZHONG B J.Study on the flocculating activity and mechanisms of soluble soybean polysaccharides[D].Guangzhou:Master Degree Thesis of South China University of Technology,2011.

微水固相法皂荚多糖胶羧甲基化改性

A Micro Water Solid Phase Method for Carboxylmethylation of Gleditsia sinensis Lam. Galactomannan Gum

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 6

编辑推荐

Metrics

本文评价

关于本刊

投稿指南

在线期刊

相关单位

联系我们

[1]	郝汉, 陈保莹, 陈维韬, 郭鑫宇, 刘文君, 吴学民. 羧甲基化木质素在阿维菌素颗粒表面的吸附行为[J]. 林产化学与工业, 2015, 35(5): 45-52.
[2]	章伟岸, 段久芳, 孙达峰, 张卫明, 蒋建新. 微水固相法氧化改性皂荚多糖胶[J]. 林产化学与工业, 2014, 34(6): 44-48.
[3]	李建凤, 廖立敏, 李祥蓉, 王碧. 锆交联葡甘聚糖凝胶球的制备及吸附性能[J]. 林产化学与工业, 2014, 34(5): 97-102.
[4]	林胜任;李友明;万小芳;陆瑞江. 微波辐射法刨花楠粉F691的羧甲基化研究[J]. 林产化学与工业, 2009, 29(5): 119-121.
[5]	黄占华;方桂珍;张斌. 羧甲基落叶松单宁的合成及抑菌性能研究[J]. 林产化学与工业, 2007, 27(3): 27-32.
[6]	罗立新;冯长根. 交联羧甲基魔芋葡甘聚糖微球的制备与表征[J]. 林产化学与工业, 2004, 24(3): 83-86.