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林产化学与工业

林产化学与工业 ›› 2023, Vol. 43 ›› Issue (1): 113-119.doi: 10.3969/j.issn.0253-2417.2023.01.014

• 研究报告 • 上一篇    下一篇

三酸复合体系催化α-蒎烯合成松油醇研究

孟中磊1,2, 胡亿明3, 温如斯1, 秦荣秀1, 周永红2,*()   

  1. 1. 广西壮族自治区林业科学研究院/广西优良用材林资源培育重点实验室，广西 南宁 530002
    2. 中国林业科学研究院 林产化学工业研究所，江苏 南京 210042
    3. 贵州中医药大学，贵州 贵阳 550025
  • 收稿日期:2021-11-11 出版日期:2023-02-28 发布日期:2023-02-28
  • 通讯作者: 周永红 E-mail:zyh@icifp.cn
  • 作者简介:周永红，研究员，博士生导师，研究领域为生物基高分子材料、油脂化学利用；E-mail: zyh@icifp.cn
    孟中磊(1980—)，男，河南平顶山人，高级工程师，博士生，研究方向为林产品加工利用
  • 基金资助:
    国家自然科学基金资助项目(31860239);广西优良用材林资源培育重点实验室课题(2020-A-01-04);自治区林业科技推广示范项目(gl2020kt11)

Synthesis of Terpineol from α-Pinene Catalyzed by Triple Acid Composite System

Zhonglei MENG1,2, Yiming HU3, Rusi WEN1, Rongxiu QIN1, Yonghong ZHOU2,*()   

  1. 1. Guangxi Forestry Research Institute/Guangxi Key Laboratory of Superior Timber Trees Resource Cultivation, Nanning 530002, China
    2. Institute of Chemical Industry of Forest Products, CAF, Nanjing 210042, China
    3. Guizhou University of Traditional Chinese Medicine, Guiyang 550025, China
  • Received:2021-11-11 Online:2023-02-28 Published:2023-02-28
  • Contact: Yonghong ZHOU E-mail:zyh@icifp.cn

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摘要：

以柠檬酸为代表的α-羟基羧酸与磷酸和以丙酸为代表的低碳链脂肪酸组成三酸复合催化体系，应用于α-蒎烯的催化水合制备松油醇。考察了溶剂种类、脂肪酸链长、α-羟基酸种类、催化剂用量、水用量、反应温度和反应时间对水合反应的影响。结果表明：在α-蒎烯、水、丙酸、柠檬酸、磷酸的质量比为1∶1∶2∶0.05∶0.1和反应温度70 ℃、反应时间24 h的反应条件下，α-蒎烯转化率、松油醇GC含量和选择性可分别达到99.0%、53.3%和54.9%。在同样条件下将α-蒎烯水合时产生的单环单萜烯类副产物加入起始原料一起反应，可以提高目标产物松油醇的选择性，当加入量为40%时，松油醇选择性可提高到76%。产物组成分析发现：产物中总松油醇GC含量为53.3%，总水合产物GC含量为57.1%，总丙酸酯GC含量为8.1%。

关键词: α-蒎烯, 松油醇, α-羟基羧酸, 三酸复合体系

Abstract:

The triple acid catalyst system composed of α-hydroxycarboxylic acid represented by citric acid, phosphoric acid and low carbon chain fatty acid represented by propionic acid was applied to the catalytic hydration of α-pinene to synthesize terpineol. The effects of solvent type, fatty acid chain length, α-hydroxycarboxylic acid type, catalyst amount, water amount, reaction temperature and reaction time on the hydration reaction were investigated. The results showed that under the reaction conditions of the mass ratio of α-pinene, water, propionic acid, citric acid and phosphoric acid of 1∶1∶2∶0.05∶0.1, reaction temperature of 70 ℃ and reaction time of 24 h, the conversion of α-pinene, the GC content of terpineol and the product selectivity could reach 99.0%, 53.3% and 54.9%, respectively. Under the same conditions, the selectivity of the target product terpineol could be improved by adding the monocyclic monoterpene by-products generated during the hydration of α-pinene to the starting material. When the addition amount was 40%, the selectivity of terpineol could be increased to 76%. The product composition analysis showed that the total GC content of terpineol in the product was 53.3%, the total GC content of hydrate was 57.1%, and the total content of propionate was 8.1%.

Key words: α-pinene, terpineol, α-hydroxycarboxylic acid, triple acid composite system

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