松香基聚氧乙烯胺型双子表面活性剂的合成及性能研究

doi:10.3969/j.issn.0253-2417.2014.05.018

Abstract

Abstract: Four rosin-based polyoxyethylene amine gemini surfactants N,N'-methoxypolyethylene glycols-N,N'-dehydroabietylamine-α,ω-promethylene diamine (RPG550, RPG1000, RPG2000, and RPG5000) with different molecular weights, were synthesized from dehydroabietylamine through N-alkylation reactions. The structures of these compounds were confirmed by FT-IR and ¹H NMR, and their surface activities were investigated and analyzed. The results showed the CMC and γ_cmc values of these four compounds were lower than that of commercial TX-10. The CMC values of RPG550, RPG1000, RPG2000, RPG5000 and TX-10 were 1.00×10^-3, 9.75×10^-4, 5.25×10^-4, 1.90×10^-4, and 2.03×10^-3 mol/L, respectively. The γ_cmc values of these surfactants were 26.4, 27.5, 22.8, 22.2, and 31.6 mN/m, respectively. These compounds have excellent emulsifiability in the turpentine/water system and the liquid paraffin/water system. They also have good foam inhibition and defoaming power properties, and the foam inhibition property of RPG is significantly better than that of TX-10.

Key words: rosin, synthesis, polyoxyethylene amine, gemini surfactant, surface activities

CLC Number:

TQ35

WANG Juan, WANG Dan, SHANG Shi-bin, SHEN Ming-gui, QI Fan. Synthesis and Properties of Rosin-based Polyoxyethylene Amine Gemini Surfactants[J]. Chemistry and Industry of Forest Products, 2014, 34(5): 109-114.

References

[1] 董国君,苏玉,王桂香.表面活性剂化学[M] .北京:北京理工大学出版社,2009.
[2] 岳治杰,李文岩.水中壬基酚聚氧乙烯醚的测定及去除方法研究进展[J] .黑龙江环境通报,2010,36(1):35-38.
[3] 盛毅,周述琼,章骅,等.烷基酚聚氧乙烯醚的环境危害及检测方法评价[J] .现代科学仪器,2009(4):141-145.
[4] 李晓瑄,李星纬.阳离子化松香的研究[J] .化学通报,2000(1):33-35.
[5] 任天瑞,李永红.松香化学及其应用[M] .北京:化学工业出版社,2006.
[6] ZANA R,XIA Ji-ding.Gemini Surfactants:Synthesis,Interfacial and Solution-Phase Behavior and Applications[M] .New York:Marcel Dekker,2003:56.
[7] 唐善法,刘忠运,胡晓东.双子表面活性剂研究与应用[M] .北京:化学工业出版社,2011.
[8] 赵剑曦.新一代表面活性剂:Gemini[J] .化学进展,1999,11(4):348-357.
[9] 贾卫红,宋湛谦,饶小平,等.松香基双子阳离子表面活性剂的抑菌性能研究[J] .林产化学与工业, 2010,30(1):1-4.
[10] 曾华辉,蒋福宾,杨正业,等.松香基季铵盐Gemini表面活性剂的合成与应用[C] //第21次全国工业表面活性剂发展研讨会论文集.南宁,2008.
[11] 贾卫红,宋湛谦,饶小平,等.松香基磺酸盐Gemini表面活性剂的合成及性能[J] .石油化工,2009,38(6):651-655.
[12] 岑波, 段文贵, 任云,等.松香-蔗糖基双子表面活性剂的合成研究[J] .兰州理工大学学报, 2005, 31(6):65-69.
[13] 贾卫红.松香基双子表面活性剂的合成及性能研究[D] .北京:中国林业科学研究院硕士学位论文,2009:46.
[14] 庞重军,刘宝生,陈剑民,等.表面修饰粉末消泡剂的制备及评定[J] .茂名学院学报,2003,13(3):15-17,21.
[15] 高燕,蹇锡高.¹H NMR 法测定多苯基取代联苯型聚醚酮的分子量[J] .高分子材料科学与工程,1999,15(12):167-168,172.
[16] 潘祖仁.表面活性剂化学[M] .北京:化学工业出版社,2009:6.
[17] 赵国玺,朱步瑶.表面活性剂作用原理[M] .北京:中国轻工业出版社,2003.

Synthesis and Properties of Rosin-based Polyoxyethylene Amine Gemini Surfactants

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