传统拖染施胶工艺下骨胶用量对宣纸物理性能的影响

doi:10.3969/j.issn.0253-2417.2023.03.008

Abstract

Abstract:

In the production process of PiMade Xuan paper, the sizing agent had a significant impact on the performance of Xuan paper. Based on the traditional drag-dye sizing technology, the bone glue with the mass fractions of 0.5%-2.5% was used as agent for surface sizing of raw Xuan paper, and the effects of sizing agent dosage on the appearance, sizing degree, structure and mechanical properties of Xuan paper were investigated. The experimental results showed that the D65 brightness of the PiMade Xuan paper was negatively correlated with the mass fraction of bone glue. This indicated that the yellowish color of the bone glue and the increasing gradient of the bone glue mass fraction were the dominant factors affecting the optical properties and appearance of the PiMade Xuan paper. The total color difference(ΔE) of the Xuan paper before and after surface sizing increased with the bone glue mass fraction increase, and a slight visible color difference was produced when the mass fraction of bone glue was ≥1.5%. Bone glue sizing could effectively inhibit the water absorption of raw Xuan paper to meet the practical needs of PiMade Xuan paper, and the hydrophobic property of PiMade Xuan paper was greatly enhanced after the mass fraction of bone glue >1.5%. The significant increase in thickness and grammage of PiMade Xuan paper was observed with the increase of bone glue mass fraction, and the decrease of its tightness decreased showed the effectiveness of the sizing, which indicated that the coverage of the bone glue directly led to the changes in the thickness and the grammage of Xuan paper. In addition, various stresses such as the immersion of the paper in the bone glue water, free drying, the water absorption expansion and drying contraction of the bone glue molecules also influenced the three-dimensional structure and size of Xuan paper during the sizing process. When the mass fraction of bone glue was less than 2.0%, the bone glue could fill the fiber pores of Xuan paper, in which the PiMade Xuan paper exhibited higher strength, elasticity and flexibility when the mass fraction of bone glue increased. This effect came from the more effective bonding and higher bond strength brought by the fiber-bone glue system within Xuan paper. Continuing to increase the mass fraction of bone glue, the effective filling of the internal pore structure of Xuan paper had reached saturation, and the improvement effect of sizing on the mechanical properties of Xuan paper weakened. Therefore, the mass fraction of bone glue should not exceed 2.0% in the actual processing of PiMade rice paper, which could achieve effective enhancement and change of the physical properties of Xuan paper.

Key words: Xuan paper, bone glue, color difference, sizing value, porosity structure, tensile properties

CLC Number:

TQ35
TS727.5

Yujing LU, Jing TAN, Xiaohang FU, Jing HUANG, Yanwei DING, Biao CHEN. Effect of Bone Glue Concentration on the Physical Properties of Xuan Paper under Traditional Drag-dye Sizing Technology[J]. Chemistry and Industry of Forest Products, 2023, 43(3): 61-69.

Figures/Tables 6

Fig.1

Table 1

Table 2

Fig.2

Table 3

Fig.3

References 34

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骨胶质量分数¹⁾/%bone glue mass fraction	明度(L^*)lightness	红绿色品(a^*)red and green chromaticity	黄蓝色品(b^*)yellow and blue chromaticity	总色差(ΔE)total color differences	毛细吸液高度/(s·mm^-1)capillary suction height
0	91.88	0.91	10.65	0	6
0.5	91.67	0.95	10.67	0.21	7
1.0	91.73	1.03	10.47	0.26	8
1.5	91.26	1.45	10.30	0.89	9
2.0	91.15	1.19	10.63	0.78	200
2.5	90.81	1.62	10.33	1.32	—

骨胶质量分数/% bone glue mass fraction	定量/(g·m^-2)grammage	定量增加率/% increase rate of grammage	厚度/μm thickness	厚度增加率/% increase rate of thickness	Δ¹⁾	紧度/(g·cm^-3)tightness
0	26.9		69.6			0.39
0.5	28.6	6.32	77.5	11.35	5.03	0.37
1.0	28.9	7.43	83.9	20.55	13.12	0.34
1.5	28.3	5.20	81.8	19.25	14.05	0.35
2.0	29.6	10.04	83.8	20.40	10.36	0.35
2.5	31.8	18.22	89.2	28.16	9.94	0.36

骨胶质量分数/% bone glue mass fraction	抗张强度/(kN·m^-1)tensile strength	抗张指数/(N·m·g^-1)tensile index	断裂伸长率/% elongation at break	抗张能量吸收/(J·m^-2)tensile energy absorption	抗张能量吸收指数/(J·kg^-1)tensile energy absorption index
0	0.768±0.03	28.6	2.4±0.16	11.6±1.02	435
0.5	1.401±0.03	49.0	4.0±0.13	34.4±1.91	1 203
1.0	1.595±0.08	55.1	4.1±0.19	33.6±3.26	1 160
1.5	2.039±0.09	72.2	4.2±0.16	50.1±2.68	1 773
2.0	2.288±0.14	77.2	4.8±0.36	59.9±8.96	2 022
2.5	2.392±0.13	75.2	5.1±0.19	64.8±4.35	2 035

Effect of Bone Glue Concentration on the Physical Properties of Xuan Paper under Traditional Drag-dye Sizing Technology

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