木质素模板法制备纳米花状炭负载Ag-ZnO及其光催化CO2转化

doi:10.3969/j.issn.0253-2417.2024.02.003

Abstract

Abstract:

Using lignin(AL) as a template, nanoscale lignin-loaded zinc oxide(ZnO/AL) composite materials were prepared. Silver nanoparticles(AgNPs) were loaded onto this base material, and a nano-flower-shaped carbon loaded silver-zinc oxide(Ag-ZnO/C) composite material was prepared through high-temperature calcination. The composite materials were characterized using scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), and X-ray photoelectron spectroscopy(XPS), and their ability for photocatalytic conversion of CO₂ was evaluated. The research results showed that when using lignin as a template, ZnO/AL could maintain the nano-flower morphology and structure during the subsequent calcination processes, and lignin could reduce silver ions in situ to AgNPs, uniformly loading them on the ZnO petal layers. Energy-dispersive X-ray spectroscopy(EDX) results showed that Ag-ZnO/C composite material was mainly composed of C(14.7%), O(14.4%), Zn(34.1%) and Ag(18.0%) elements. Combined with TEM, XRD, and XPS analysis, the successful preparation of the Ag-ZnO/C composite material was confirmed. The ability of photocatalytic CO₂ conversion of the composite materials with different Ag⁺/Zn²⁺ ratios of 1∶2(Ag_0.1-ZnO_0.2/C) and 1∶10(Ag_0.1-ZnO_1.0/C) was compared. Photocurrent response and impedance spectroscopy test results indicated that Ag_0.1-ZnO_1.0/C had higher photocurrent intensity, lower resistance, and superior photocatalytic activity. The photocatalytic CO₂ conversion by Ag_0.1-ZnO_1.0/C showed consistently low CH₄ production, and the CO yield could reach 114.9 μmol/g after 10 hours of reaction.

Key words: lignin, Ag-ZnO nanoflower, CO₂ conversion

CLC Number:

TQ35
TS79

Bihui AN, Haojie CHEN, Lili ZHANG, Jinxia MA, Zhiguo WANG. Preparation of Nano-flower-shaped Carbon Loaded Ag-ZnO Using Lignin Template Method and Its Photocatalytic CO₂ Conversion[J]. Chemistry and Industry of Forest Products, 2024, 44(2): 20-26.

Figures/Tables 7

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References 19

1	LIANG J, WU Q, HUANG Y B, et al. Reticular frameworks and their derived materials for CO₂ conversion by thermo-catalysis[J/OL]. EnergyChem, 2021, 3(6): 100064[2023-02-16]. https://doi.org/10.1016/j.enchem.2021.100064.
2	LUO W, ZHANG Q, ZHANG J, et al. Electrochemical reconstruction of ZnO for selective reduction of CO₂ to CO[J/OL]. Applied Catalysis B: Environmental, 2020, 273: 119060[2023-02-16]. https://doi.org/10.1016/j.apcatb.2020.119060.
3	WANG W , DENG C Y , XIE S J , et al. Photocatalytic C—C coupling from carbon dioxide reduction on copper oxide with mixed-valence copper(Ⅰ)/copper(Ⅱ)[J]. Journal of the American Chemical Society, 2021, 143 (7): 2984- 2993. doi: 10.1021/jacs.1c00206
4	ZHANG L L, SHI C, LU H L, et al. Porous cellulose gel-regulated flower-like ZnO-Cu nanoparticles for enhancing interfacial catalysis activity and recyclability in environmental catalysis[J/OL]. Applied Surface Science, 2022, 597: 153737[2023-02-16]. https://doi.org/10.1016/j.apsusc.2022.153737.
5	AHMAD I, AKHTAR M S, AHMED E, et al. Highly efficient visible light driven photocatalytic activity of graphene and CNTs based Mg doped ZnO photocatalysts: A comparative study[J/OL]. Separation and Purification Technology, 2020, 245: 116892[2023-02-16]. https://doi.org/10.1016/j.seppur.2020.116892.
6	BHARATHI P , HARISH S , ARCHANA J , et al. Enhanced charge transfer and separation of hierarchical CuO/ZnO composites: The synergistic effect of photocatalysis for the mineralization of organic pollutant in water[J]. Applied Surface Science, 2019, 484, 884- 891. doi: 10.1016/j.apsusc.2019.03.131
7	陈林, 彭国良, 宋杰光, 等. Ce³⁺掺杂纳米ZnO的制备及其可见光光催化性能研究[J]. 化工新型材料, 2020, 48 (1): 200- 206.
	CHEN L , PENG G L , SONG J G , et al. Study on preparation and visible photocatalytic performance of Zn_1-xCe_xO[J]. New Chemical Materials, 2020, 48 (1): 200- 206.
8	SHI C , ZHANG L L , SHI Z J , et al. Mechanistic investigation of cellulose regulating the morphology and photocatalytic activity of Al-doped ZnO[J]. International Journal of Biological Macromolecules, 2023, 228, 435- 444. doi: 10.1016/j.ijbiomac.2022.12.222
9	LI H W, ZHANG L L, LU H L, et al. Macro-/nanoporous Al-doped ZnO/cellulose composites based on tunable cellulose fiber sizes for enhancing photocatalytic properties[J/OL]. Carbohydrate Polymers, 2020, 250: 116873[2023-02-16]. https://doi.org/10.1016/j.carbpol.2020.116873.
10	井立强, 蔡伟民, 孙晓君, 等. Pd/ZnO和Ag/ZnO复合纳米粒子的制备、表征及光催化活性[J]. 催化学报, 2002, 23 (4): 336- 340. doi: 10.3321/j.issn:0253-9837.2002.04.013
	JING L Q , CAI W M , SUN X J , et al. Preparation and characterization of Pd/ZnO and Ag/ZnO composite nanoparticles and their photocatalytic activity[J]. Chinese Journal of Catalysis, 2002, 23 (4): 336- 340. doi: 10.3321/j.issn:0253-9837.2002.04.013
11	XU R Y, LI M, ZHANG Q. Collaborative optimization for the performance of ZnO/biochar composites on persulfate activation through plant enrichment-pyrolysis method[J/OL]. Chemical Engineering Journal, 2022, 429: 132294[2023-02-16]. https://doi.org/10.1016/j.cej.2021.132294.
12	ZEVALLORS TORRES L A, WOICIECHOWSKI A L, DE ANDRADE TANOBE V O, et al. Lignin as a potential source of high-added value compounds: A review[J/OL]. Journal of Cleaner Production, 2020, 263: 121499[2023-02-16]. https://doi.org/10.1016/j.jclepro.2020.121499.
13	KAUR R, BHARDWAJ S K, CHANDNA S, et al. Lignin-based metal oxide nanocomposites for UV protection applications: A review[J/OL]. Journal of Cleaner Production, 2021, 317: 128300[2023-02-16]. https://doi.org/10.1016/j.jclepro.2021.128300.
14	FU F B , YANG D J , WANG H , et al. Three-dimensional porous framework lignin-derived carbon/ZnO composite fabricated by a facile electrostatic self-assembly showing good stability for high-performance supercapacitors[J]. ACS Sustainable Chemistry & Engineering, 2019, 7 (19): 16419- 16427.
15	WANG H , QIU X Q , LIU W F , et al. Facile preparation of well-combined lignin-based carbon/ZnO hybrid composite with excellent photocatalytic activity[J]. Applied Surface Science, 2017, 426, 206- 216. doi: 10.1016/j.apsusc.2017.07.112
16	COCCIA F , TONUCCI L , BOSCO D , et al. One-pot synthesis of lignin-stabilised platinum and palladium nanoparticles and their catalytic behaviour in oxidation and reduction reactions[J]. Green Chemistry, 2012, 14 (4): 1073- 1078. doi: 10.1039/c2gc16524d
17	ZHANG L L, AN B H, CHEN H J, et al. Botryoidal nanolignin channel stabilized ultrasmall PdNP incorporating with filter membrane for enhanced removal of Cr(VI) via synergetic filtration and catalysis[J/OL]. Separation and Purification Technology, 2022, 296: 121409[2023-02-16]. https://doi.org/10.1016/j.seppur.2022.121409.
18	ZHANG L L , LU H L , CHU J J , et al. Lignin-directed control of silver nanoparticles with tunable size in porous lignocellulose hydrogels and their application in catalytic reduction[J]. ACS Sustainable Chemistry & Engineering, 2020, 8 (33): 12655- 12663.
19	QI Y H, JIANG J W, LIANG X C, et al. Fabrication of black In₂O₃ with dense oxygen vacancy through dual functional carbon doping for enhancing photothermal CO₂ hydrogenation[J/OL]. Advanced Functional Materials, 2021, 31(22): 2100908[2023-02-16]. https://doi.org/10.1002/adfm.202100908.

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Preparation of Nano-flower-shaped Carbon Loaded Ag-ZnO Using Lignin Template Method and Its Photocatalytic CO₂ Conversion

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Preparation of Nano-flower-shaped Carbon Loaded Ag-ZnO Using Lignin Template Method and Its Photocatalytic CO2 Conversion

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Preparation of Nano-flower-shaped Carbon Loaded Ag-ZnO Using Lignin Template Method and Its Photocatalytic CO₂ Conversion