氢化萜烯酯型环氧树脂固化反应表征与机械性能研究

›› 2007, Vol. 27 ›› Issue (04): 21-26.

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Study on Curing Reaction and Mechanical Properties of Epoxy Resin from Hydrogenated Terpinene-maleic Anhydride

WU Guo-min¹, KONG Zhen-wu¹, CHU Fu-xiang¹, LU Ji-rong²

1. Institute of Chemical Industry of Forest Products, CAF;Key and Open Lab.on Forest Chemical Engineering, SFA, Nanjing 210042, China;2. Jilin Petrochemical Co., Ltd., Petrochina, Jilin 132021, China

Received:2007-02-08 Revised:1900-01-01 Online:2007-08-30 Published:2007-08-30

Abstract

Abstract: Hydrogenated terpinene-maleic ester type epoxy resin(HTME) is a type of epoxy resin synthesized from hydrogenated terpinene-maleic anhydride.The activity of curing reaction of HTME/methyl hexahydrophthalic anhydride (MeHHPA) system was investigated by means of DSC and gelation time determination.The curing behaviors of HTME/MeHHPA system were studied by qualitative analysis of FT-IR spectrum and quantitative analysis of curing degree determination.The mechanical properties of HTME cured with MeHHPA were compared with those of terpinene-maleic ester type epoxy resin (TME) andepoxy resin 6101 under the same condition. The results show that the reaction between HTME and MeHHPA was an exothermic one with reaction heat of 153.5 J/g and peak temperature at 157.9℃, and the HTME/MeHHPA system could be cured completely at 110℃ for 8 h with 0.5% benzyldimethylamine (BDMA) by weight of HTME as accelerant. The mechanic properties of the three kinds of cured epoxy products were about the same.

Key words: hydrogenated terpinene-maleic anhydride, epoxy resin, curing reaction, mechanical property

CLC Number:

TQ323.5

WU Guo-min;KONG Zhen-wu;CHU Fu-xiang;LU Ji-rong. Study on Curing Reaction and Mechanical Properties of Epoxy Resin from Hydrogenated Terpinene-maleic Anhydride[J]. , 2007, 27(04): 21-26.

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Study on Curing Reaction and Mechanical Properties of Epoxy Resin from Hydrogenated Terpinene-maleic Anhydride

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