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›› 2000, Vol. 20 ›› Issue (2): 13-17.

• 研究报告 • Previous Articles     Next Articles

RESEARCH ON REACTION KINETICS OF α-PINENE ISOMERIZATION CATALYZED BY HMC-60

WANG Ya-ming1, YANG Xian-wan2   

  1. 1. Department of Environmental and Chemical Engineering, Kunming University of Science and Technology, Kunming 650093, China;2. Department of Metallurgy, Kunming University of Science and Technology, Kunming 650093, China
  • Received:1999-04-12 Revised:1900-01-01 Online:2000-06-30 Published:2000-06-30

Abstract: In this paper,the reaction of α-pinene isomerization on HMC-60 catalyst was studied,and the effects of reaction temperature,reaction time and amount of catalyst were investigated.It was found that the reaction was of the first order at 140~156℃.Reaction rate constant was 4.41×10 -4,4.69×10-4,5.11×10-4 at 140,150 and 156℃ respectively.Apparent activation energy was 1.75 kJ/mol,frequency factor was 5.314×10-4.The rate equation and the correlated relation between reaction rate constant and temperature were established.

Key words: HMC-60 catalyst, α-pinene isomerization, reaction order, apparent activation energy

CLC Number: