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林产化学与工业 ›› 2008, Vol. 28 ›› Issue (3): 81-85.

• 论文 • 上一篇    下一篇

麦草纤维孔隙结构在回用过程中的变化规律研究

吴微微, 万金泉, 马邕文, 王艳   

  1. 华南理工大学环境科学与工程学院, 广东, 广州, 510640
  • 收稿日期:2007-09-11 修回日期:1900-01-01 出版日期:2008-06-30 发布日期:2008-06-30

Investigation on the Variation Pattern of Pore Structure of Wheat Straw Fiber during Recycling Process

WU Wei-wei, WAN Jin-quan, MA Yong-wen, WANG Yan   

  1. College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510640, China
  • Received:2007-09-11 Revised:1900-01-01 Online:2008-06-30 Published:2008-06-30

摘要: 采用低温氮吸附法、透射电镜对不同回用次数下麦草纤维细胞壁孔隙结构进行了研究.结果表明,麦草纤维有发达的微孔,分布较宽的中孔,而大孔相对较少.麦草浆回用1次后微孔孔容下降3.2×10-5 cm-3/g,中孔孔容下降1.67×10-5 cm-3/g;2次和1次回用相比微孔孔容下降9.2×10-5 cm-3/g,中孔孔容下降2.77×10-5 cm-3/g;3次回用时微孔分布消失,与2次回用相比中孔孔容下降.81×10-5 cm-3/g,但在3次回用后孔隙分布变化很小.孔隙平均孔径和BET比表面积在回用中总体呈下降趋势.从电镜照片上看出,纤维在回用再润湿后发生不可恢复的塌陷变形,细胞壁上出现褶皱,从而改变了纤维孔隙大小和形状.

关键词: 麦草纤维, 孔隙结构, 麦草浆, 回用, 孔隙形态结构

Abstract: Variation pattern of pore structure of wheat straw fiber during recycling process with N2 adsorption-desorption method under low temperature was investigated with transmission electron microscopy during different recycling times. The results showed that the pore size distribution of wheat straw fiber was complicated with numerous micropores and middle-size pores except large pores. After the first recycle, the pore volumes of micropores was decreased 3.2×10-5cm3/g and the average pore volume of middle-size pore was reduced 1.67×10-5cm3/g. After the second recycle, the pore volumes of micropores and middle-size pores were decreased 9.2×10-5cm3/gand 2.77×10-5cm3/gseparately compared with the first recycle. After the third recycle, the average pore volumes of middled-size pore decreased 5.81×10-5cm3/g compared with the second recycle, but the micropores disappeared, while pore distribution was changed insignificently.The average pore size and the surface area of fiber had a trend of drop during the recycling process. It was also found that after recycling and remoistening, the lumen of fiber had irreversible collapse and distortion, and there was lots of pleats that changed the shape and size of pores.

Key words: wheat straw fiber, pore structure, wheat straw pulp, recycling, configuration of pores

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