桉树生物质制备高邻位酚醛树脂纤维的研究

doi:10.3969/j.issn.0253-2417.2020.06.009

Abstract

Abstract:

Biomass-based high-ortho phenolic resin fibers were prepared from eucalyptus bark, tree stem, and lignin. FT-IR, TG, DSC and mechanical properties as well as the measurement of free phenol, were used to evaluate the properties of different biomass-based thermoplastic phenolic resins. The influence of the amount of the same kind of biomass on phenolic resins, and the mixing process on mechanical properties of bio-based phenolic resins fiber were alse investigated. The results showed that the composition of lignin-based resin was uniform, the structure was stable, and the thermal stability was the best. The bio-based phenolic resins with three lignin ratios had similar ortho-position(O/P) ratios, and the ortho-position reaction ratios were all greater than the para-position. When the ratio of lignin and phenol was 1:4, the obtained resin had uniform composition and best performance. The internal mixing process could homogenize the resin and avoid overheating, which caused by internal heat generation. Combined with mechanical properties, the optimal conditions of mixing process of bio-based fibers were internal mixing for 15 min, rotation speed of 45 r/min, and internal mixing temperature of 135 ℃. The maximum strength was 168.6 MPa and the elongation at break was 2.1%.

Key words: eucalyptus residue, high-ortho, phenolic resin, fiber

CLC Number:

TQ35

Can LIU, Yu REN, Xin LI, Jianxiang LIU, Zhengjun SHI, Zhifeng ZHENG. Preparation of High-ortho Phenolic Resin Fiber from Eucalyptus Residue[J]. Chemistry and Industry of Forest Products, 2020, 40(6): 70-76.

Figures/Tables 5

References 23

1	MARLIANA M M , HASSANA A , YUZIAH M Y N , et al. Flame retardancy, thermal and mechanical properties of Kenaf fiber reinforced unsaturated polyester/phenolic composite[J]. Fibers and Polymers, 2016, 17 (6): 902- 909.
2	焦明立, 杨凯, 刘红燕, 等. 酚醛纤维的制备及改性研究进展[J]. 合成纤维工业, 2013, 36 (6): 33- 36.
	JIAO M L , YANG K , LIU H Y , et al. Research progress in preparation and modification of phenolic fibers[J]. China Synthetic Fiber Industry, 2013, 36 (6): 33- 36.
3	任东雪, 焦明立, 郑瑾, 等. 酚醛基活性炭纤维的研究进展[J]. 合成纤维工业, 2017, 40 (5): 62- 67.
	REN D X , JIAO M L , ZHENG J , et al. Research progress of phenolic resin-based activated carbon fibers[J]. China Synthetic Fiber Industry, 2017, 40 (5): 62- 67.
4	YANG L J , WANG M G . Synthesis and property of solid resol phenolic resins with high molecular weight[J]. Polymer Materials Science & Engineering, 2012, 28 (12): 24- 28.
5	LI C , BU Z Y , SUN J P , et al. New insights into high-ortho phenolic novolac:Elucidating dependence between molecular structure, curing kinetics and thermal stability[J]. Thermo Chemical Acta, 2013, 557 (7): 77- 86.
6	HAN Z Q , QI S L , LIU W , et al. Surface-modified polyimide fiber-filled ethylenepropylenediene monomer insulations for a solid rocket motor:Processing, morphology, and properties[J]. Industrial & Engineering Chemistry Research, 2013, 52, 1284- 1290.
7	马小丰, 李建华, 吴剑吴, 等. 酚醛短切纤维对EPDM绝热材料性能的影响[J]. 塑料工业, 2019, 47 (7): 31- 36.
	MA X F , LI J H , WU J W , et al. Effects of phenolic short fibers on properties of EPDM insulations[J]. China Plastics Industry, 2019, 47 (7): 31- 36.
8	陈滨.改性热塑性酚醛树脂的制备及其成纤性能研究[D].上海: 东华大学, 2016.
	CHEN B.Study on the preparation and spinnability of modified phenolic resin[D]. Shanghai: Donghua University, 2016.
9	李改云, 任海青, 秦特夫, 等. 木材液化产物制备热塑性树脂的研究[J]. 林产化学与工业, 2008, 28 (4): 23- 28.
	LI G Y , REN H Q , QIN T F , et al. Preparation of novolak-type phenolic resin from phenolated wood[J]. Chemistry and Industry of Forest Products, 2008, 28 (4): 23- 28.
10	陈玉竹, 邵慧娟, 李竞, 等. 温度和pH值对预固化脲醛树脂固化影响的评价[J]. 热固性树脂, 2017, (3): 54- 59.
	CHEN Y Z , SHAO H J , LI J , et al. Evaluation of the effects of temperature and pH on the curing of pre-curing urea-formaldehyde resins[J]. Thermosetting Resin, 2017, (3): 54- 59.
11	刘春玲, 郭全贵, 史景利, 等. 用固化反应法制备酚醛纤维[J]. 材料研究学报, 2005, 19 (1): 28- 34.
	LIU C L , GUO G Q , SHI J L , et al. The curing reaction of phenolic fibers[J]. Chinese Journal of Materials Research, 2005, 19 (1): 28- 34.
12	CHEN B , YU J R , ZHOU Y S , et al. Preparation structure and properties of boron modified high-ortho phenolic fibers[J]. Fibers and Polymers, 2016, 17 (5): 678- 686.
13	张伟. 生物炼制木质素基酚醛树脂的制备与应用(摘要)[J]. 生物质化学工程, 2014, 48 (4): 57- 58.
	ZHANG W . Preparation and application of the biorefinery lignin-based phenolic resin(Abstract)[J]. Biomass Chemical Engineering, 2014, 48 (4): 57- 58.
14	卢宇晗, 黄元波, 李欣, 等. 生物质基高邻位热塑性酚醛树脂作为树脂纤维前驱体的研究[J]. 西北林学院学报, 2018, 33 (3): 1- 7.
	LU Y H , HUANG Y B , LI X , et al. Preparation of biobased high ortho novolak resin[J]. Journal of Northwest Forestry College, 2018, 33 (3): 1- 7.
15	李欣, 卢宇晗, 黄元波, 等. 木质素基碳纤维力学性能的研究进展[J]. 西南林业大学学报(自然科学版), 2019, 39 (3): 176- 182.
	LI X , LU Y H , HUANG Y B , et al. Research progress on mechanical properties of lignin-based carbon fibers[J]. Journal of Southwest Forestry University(Natural Science), 2019, 39 (3): 176- 182.
16	卢宇晗, 黄元波, 杨晓琴, 等. 核桃壳液化物合成高邻位热塑性酚醛树脂的研究[J]. 材料导报, 2018, 32 (9): 3244- 3248.
	LU Y H , HUANG Y B , YANG X Q , et al. Synthesis of high-ortho novolak resin from liquefied products of walnut shell[J]. Material Reports, 2018, 32 (9): 3244- 3248.
17	戴燕, 谭卫红, 胡立红, 等. TG-DSC-MS联用研究不同气氛下腰果壳油改性热朔性酚醛树脂的热裂解特性[J]. 分析测试学报, 2014, 33 (4): 387- 394.
	DAI Y , TAN W H , HU L H , et al. Investigation on thermal decomposition behaviors of cashew nut shell liquid modified thermos plastic phenolic resin by TG-DSC-MS coupling techniques at different atmospheres[J]. Journal of Instrumental Analysis, 2014, 33 (4): 387- 394.
18	HUSKIĆ M , ANŽLOVAR A , ŽIGON M . Montmoril-lonite-phenolic resin nanocomposites prepared by one-step in-situ intercalative polymerization[J]. Applied Clay Science, 2014, 101, 484- 489.
19	阮胜军, 左小华, 张世磊, 等. 改性热塑性酚醛树脂的制备及残炭率的影响因素[J]. 中国胶黏剂, 2012, 21 (12): 33- 36.
	RUAN S J , ZUO X H , ZHANG S L , et al. Preparation of modified thermoplastic phenol-formaldehyde resin and influence factors of residual carbon[J]. China Adhesives, 2012, 21 (12): 33- 36.
20	陈滨, 于俊荣, 王彦, 等. 钼改性高邻位酚醛纤维的制备及性能[J]. 东华大学学报(自然科学版), 2016, 42 (6): 787- 792.
	CHEN B , YU J R , WANG Y , et al. Preparation of molybdenum modified high-ortho-phenolic fibers and its properties[J]. Journal of Donghua University(Natural Science), 2016, 42 (6): 787- 792.
21	卢宇晗.核桃壳液化树脂化产物制备碳纤维的研究[D].昆明: 西南林业大学, 2018.
	LU Y H.Preparation of carbon fiber by liquefying resin from walnut shell[D]. Kunming: Southwest Forestry University, 2018.
22	徐旭东.氯化钯催化下低共熔离子液活化木质素改性酚醛树脂的研究[D].南京: 南京林业大学, 2016.
	XU X D.Study on the modification of phenolic resin using eutectic ionic liquid activated lignin catalysed under palladium chloride[D]. Nanjing: Nanjing Forestry University, 2016.
23	GAO S , TANG G , HUA D , et al. Stimuli-responsive bio-based polymeric systems and their applications[J]. Journal of Materials Chemistry B, 2019, 7 (5): 709- 729.

[1]	Xiaojie BAI,Xiuchun DENG,Zuyou ZHUO,Yandan CHEN. Recent Progress on Surface Modification and High Value-added Utilization of Kapok Fiber [J]. Chemistry and Industry of Forest Products, 2020, 40(2): 16-24.
[2]	Hua ZHU,Ting WU,Guigan FANG,Long LIANG,Beiping ZHU,Guanghui SHE. Performance Evaluation of Chemi-mechanical Pulping Obtained from Five Kinds of Common Fast-growing Pulpwood in Hainan Province [J]. Chemistry and Industry of Forest Products, 2020, 40(2): 63-68.
[3]	Hongliang MA,Jian CHEN,Jian JIAO,Yongjun DENG,Zhenwu KONG,Guigan FANG. Effects of Poplar Wood Fiber (PWF) Size on Mechanical Properties of PWF/Epoxy Resin Composites [J]. Chemistry and Industry of Forest Products, 2020, 40(2): 104-108.
[4]	Shun YAN,Luping XU,Zewei WEN,Jixing XIE,Jianzhong XU. Synergistic Effect of Inorganic Hydroxide/Boric Acid in Flame Retardant Reed Fiberboard [J]. Chemistry and Industry of Forest Products, 2020, 40(1): 101-105.
[5]	Lulu WEI,Zhenyu YAN,Yongjun DENG,Shanming HAN,Long LIANG,Guigan FANG. Effect of Extrusion Pretreatment on Fiber Morphology and Pulping Properties of Poplar APMP Pulp [J]. Chemistry and Industry of Forest Products, 2019, 39(6): 109-114.
[6]	ZHANG Haonan, WEI Jiahui, ZHAO Hui, LI Dan, REN Hao. Preparation and Application of Enteromorpha prolifera Fibers of Polyacrylic Acid-based Absorbent Resins [J]. Chemistry and Industry of Forest Products, 2019, 39(5): 101-107.
[7]	Shuang SHI,Fang HU,Zechao MIAO,Hetian CAI,Dezhao LI. Recent Advances in Ultrasonic Treatment of Waste Paper Fibers [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 17-24.
[8]	Hongliang MA,Jian CHEN,Jian JIAO,Yongjun DENG,Zhenwu KONG,Guigan FANG. Preparation and Characterization of Long-chain Silanes Modified Poplar Wood Fiber [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 25-33.
[9]	Manjun ZHAN,Zhilin CHEN,Fuxiang CHU. Effect of Hybrid Flame Retardant on Properties of Formaldehyde-free Ultra-low Density Fiberboard [J]. Chemistry and Industry of Forest Products, 2019, 39(3): 87-93.
[10]	Na ZHANG,Lihong HU,Yajun GUO,Yonghong ZHOU. Characterization of Phenolic Foam Modified by Silanized Nano-SiO₂ [J]. Chemistry and Industry of Forest Products, 2019, 39(1): 53-60.
[11]	MA Hongliang, CHEN Jian, JIAO Jian, DENG Yongjun, KONG Zhenwu, FANG Guigan. Preparation and Characterization of Organosiloxane Modified Poplar Wood Fiber [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 20-26.
[12]	ZHANG Xiaozhou, LIANG Meng, YANG Yan, JIA Hongge. Preparation of Rice Husk Based Super Absorbent Polymer and Its Effect on Growth and Development of Elymus nutans Seed [J]. Chemistry and Industry of Forest Products, 2018, 38(6): 124-128.
[13]	YANG Xiaohui, SHANG Qianqian, JIA Puyou, ZHOU Yonghong. Properties of Phenolic Foam Modified by Lignin Depolymerized in Molten Salt Hydrate [J]. Chemistry and Industry of Forest Products, 2018, 38(5): 115-121.
[14]	YU Mudan, QIAN Xueren, ZHOU Wanpeng. Photocatalytic Activity of CdS@Polyaniline/Cellulose Fibers Composite [J]. Chemistry and Industry of Forest Products, 2018, 38(3): 115-121.
[15]	WANG Rongxing, ZHANG Zuxin, CHEN Riqing, ZHAO Linwu, WANG Chunpeng, CHU Fuxiang. Synthesis of Phenol-urea-formaldehyde Resin and Its Reaction Mechanism [J]. Chemistry and Industry of Forest Products, 2018, 38(1): 101-109.

Preparation of High-ortho Phenolic Resin Fiber from Eucalyptus Residue

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 5

References 23

Related Articles 15

Recommended Articles

Metrics

Comments