生物油模型化合物加氢脱氧催化剂的研究进展

doi:10.3969/j.issn.0253-2417.2021.02.017

Abstract

Abstract:

Hydrodeoxygenation(HDO) process of phenolic compound is an important process for upgrading and refining bio-oil to high value-added chemicals and high-quality liquid fuel, in which the catalyst plays a vital role. Research on the catalytic process of hydrodeoxygenation of bio-oil model compound phenols has important reference significance for bio-oil upgrading and refining. Phenolic compound hydrodeoxygenation catalysts mainly include precious metal catalysts, non-precious metal catalysts and bimetallic catalysts. This paper summarized the advantages and disadvantages of various catalysts, and briefly described the mechanism of various catalysts in the process of phenol hydrodeoxygenation. And the catalyst was evaluated for substrate conversion, product selectivity, and catalyst stability.

Key words: bio-oil, phenolic compounds, hydrodeoxygenation, catalyst

CLC Number:

TQ35

Le TONG, Le ZHANG, Hui PAN, Huimin ZHU, Junfeng FENG. Research Progress of Hydrodeoxygenation Catalysts for Bio-oil Model Compounds[J]. Chemistry and Industry of Forest Products, 2021, 41(2): 130-140.

Figures/Tables 5

Table 1

Typical catalysts and performance of biodiesel model compound HDO reaction"

催化剂种类catalyst type	反应物reactant	催化剂catalyst	温度/℃temp.	压力/MPapressure	转化率/%conversion	主要产物(选择性)products(selectivity)	参考文献reference
贵金属负载型supported precious metal	愈创木酚guaiacol	Ru/TiO₂	260	1	100	环己烷(91.3%)cyclohexane	^[20]
	愈创木酚guaiacol	Ru/TiO₂-ZrO₂	220	3	94	环己醇(40%)cyclohexanol	^[21]
	甲酚cresol	Ru/Nb₂O₅	250	0.5	56.8	C7-C9芳烃(88%)C7-C9 aromatics	^[22]
非贵金属负载型supported non-precious metals	苯酚phenol	Ni/γ-Al₂O₃	300	5	99	环己烷(90%)cyclohexane	^[23]
	愈创木酚guaiacol	Ni/SZ-3	300	5	100	烃类(100%)hydrocarbons	^[24]
	苯酚phenol	Mo₂C/TiO₂	350	2.5	100	苯(90%)benzene	^[25]
两种非贵金属non-precious/non-precious metal	愈创木酚guaiacol	Ni₅Cu/SZ-3	300	5	100	环己烷(80.8%)cyclohexane	^[26]
	愈创木酚guaiacol	CoMoS	300	4	100	苯和甲苯(98%)benzene and toluene	^[27]
	愈创木酚guaiacol	NiCo/γ-Al₂O₃	200	5	96	环己醇(70%)cyclohexanol	^[28]
两种贵金属precious/precious metal	4-丙基苯酚4-propylphenol	Pt-Ru/HZSM-5	110	0.1	100	丙基环己烷(100%)propyl cyclohexane	^[29]
两种贵金属precious/precious metal	4-丙基苯酚4-propylphenol	Pt-Re/ZrO₂	300	2	67	4-丙基苯(80%)4-propylbenzene	^[30]
贵金属+非贵金属precious/non-precious metal	愈创木酚guaiacol	Pt-Mo/TiO₂	285	4	94	环己烷(57.7%)cyclohexane	^[31]
贵金属+非贵金属precious/non-precious metal	4-丙基苯酚4-propylphenol	Re-Ni/ZrO₂	300	4	90	正丙基苯(54%)n-propylbenzene	^[32]
复合催化剂composite catalyst	愈创木酚guaiacol	Pt/C+HZSM-5	250	4	90	环己烷(45.28%)cyclohexane	^[33]
	4-丙基苯酚4-propylphenol	Raney Ni+ Nafion/SiO₂	110	0.1	100	丙基环己烷(100%)propyl cyclohexane	^[34]
	苯酚phenol	Pd/C+La-BEA	200	6	100	环己烷(98%)cyclohexane	^[35]
其他催化剂others	苯酚phenol	PdCu/ZrO₂	300	0.1	13.54	环己酮(74.91%)cyclohexanone	^[36]
其他催化剂others	苯酚phenol	Ni-Fe/MCSs	250	5	100	环己烷(93.8%)cyclohexane	^[37]

Table 1

Fig.1

Fig.2

Fig.3

Fig.4

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Research Progress of Hydrodeoxygenation Catalysts for Bio-oil Model Compounds

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