过渡金属基催化剂催化5-羟甲基糠醛合成2, 5-呋喃二甲醛研究进展

doi:10.3969/j.issn.0253-2417.2021.05.015

Abstract

Abstract:

This article reviews the recent research progress of preparation of 2, 5-furandiformaldehyde(DFF) by the oxidation of 5-hydroxymethylfurfural(HMF) with transition metal-based catalysts. The application of manganese-based, copper-based, vanadium-based, iron/cobalt-based and other catalytic systems in the preparation of DFF by HMF oxidation is mainly introduced. The effects of different reaction conditions on the catalytic performance of the catalyst are analyzed in detail, the reaction mechanism of different catalysts is explained, and the advantages and disadvantages of different catalysts are summarized. In addition, based on the analysis of the existed problems in the current catalyst catalysis process, the development prospects of the transition metal-based catalysts catalyzed by HMF oxidation to prepare DFF are also prospected.

Key words: 5-hydroxymethylfurfural, 2, 5-furandiformaldehyde, catalytic oxidation

CLC Number:

TQ35
O643.36

Jifeng BAI, Yu YANG, Zhixin JIANG, Manfang CHENG, Lin ZHANG, Jingyun WANG. Research Advance in Preparation of 2, 5-Furanedioic Acid by Oxidation of 5-Hydroxymethylfurfural over Transition Metal-based Catalysts[J]. Chemistry and Industry of Forest Products, 2021, 41(5): 100-112.

Figures/Tables 10

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Research Advance in Preparation of 2, 5-Furanedioic Acid by Oxidation of 5-Hydroxymethylfurfural over Transition Metal-based Catalysts

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