松香改性腰果酚漆膜性能的研究

doi:10.3969/j.issn.0253-2417.2022.05.008

Abstract

Abstract:

The coatings was prepared using the modification of cardanol by rosin, and its performance was studied. The mechanism of rosin modified cardanol and effect of rosin dosage on curing rate of coating were analyzed by FT-IR. The results showed that the phenolic hydroxyl of cardanol and the carboxylic acid of rosin were esterified during the heating process, and the unsaturated rosin structure and the unsaturated side chain of cardanol were oxidized crosslinking reaction. With the increase of rosin dosage, the curing rate of cardanol was increased. When the rosin dosage(by cardanol quality) was 10%, the bio-based rosin modified cardanol coating with high gloss and good comprehensive properties could be obtained by curing at 150 ℃ after 24 h with 5% cobalt naphthenate as catalyst. Its gloss was 115, adhesion level was 1, pencil hardness was 2H, the impact strength was 35 kg/cm, and the flexibility was 1 mm.

Key words: cardanol, rosin, bio-based coating

CLC Number:

TQ351

Yaocang LI, Jiawei SHAO, Hongxia MA. Properties of Rosin-modified Cardanol Coatings[J]. Chemistry and Industry of Forest Products, 2022, 42(5): 56-60.

Figures/Tables 4

References 17

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Properties of Rosin-modified Cardanol Coatings

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References 17

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松香用量/% rosin dosage	表干时间/h surface drying time	光泽度 glossiness	铅笔硬度 pencil hardness	附着力/级 adhesion	冲击强度/(kg·cm^-1) impact strength	柔韧性/mm toughness
0	5	108	B	3	20	1.5
5	4	112	H	2	25	1.0
10	3	115	2H	1	35	1.0
15	2	116	2H	1	35	1.0
20	2	105	2H	2	30	1.5