淀粉/羧甲基纤维素/甘油可降解复合膜的制备及性能研究

doi:10.3969/j.issn.0253-2417.2024.02.013

Abstract

Abstract:

Starch/carboxymethyl cellulose(CMC)/glycerol composite film was fabricated with a casting method by mixing starch CMC and glycerol used as a plasticizer. The structure of the composite film was characterized by SEM, XRD, and FT-IR, and the mechanics, light transmittance, water absorption, and degradation properties of the composite film were studied. The effect of different glycerol addition levels(based on the total dry mass of starch and CMC, 0-30%) on the structure and properties of the composite film were mainly investigated. The results showed that starch, CMC, and glycerol were physically blended, and the addition of glycerol improved the compatibility of the system. The more glycerol added, the smoother fracture surface of the composite film was achieved. As the glycerol addition increased, the elongation at break of the composite film significantly increased. When the addition increased from 0 to 30%, the elongation at break increased from 3.39% to 46.23%, which was an increase of 12.6 times. The transmittance, water absorption, and water vapor permeability(WVP) of the composite film increased with increase of glycerol addition. When the addition was 20%, the maximum transmittance at 600 nm reached 79.42%, and the WVP and water absorption were 5.14×10^-11 g/(m · s · Pa) and 25.46%, respectively. The increase of glycerol addition in the system could also accelerate the degradation rate of the composite film. When the glycerol addition was 20%, the composite film almost completely degraded within 9 days. The results showed that the mechanical, optical and degradable properties of starch/CMC/glycerol composite film were better when the glycerol content was 20%, which could meet the performance requirements of food packaging film.

Key words: starch, carboxymethyl cellulose, glycerol, barrier properties, biodegradability

CLC Number:

TQ35

Dongyang JIANG, Nannan LI, Haiyuan HUANG, Zeguang ZHOU, Yanyue LU, Lei ZHONG. Preparation and Properties of Starch/Carboxymethyl Cellulose/Glycerol Degradable Composite Films[J]. Chemistry and Industry of Forest Products, 2024, 44(2): 94-102.

Figures/Tables 7

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Table 1

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Table 3

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References 31

1	杨晖, 马良, 韩霜, 等.甘油添加量对兔皮明胶膜性能与结构的影响[J].食品科学,2016,37(17):14-18.
	YANG H , MA L , HAN S , et al.Effect of glycerol content on properties and structure of rabbit skin gelatin film[J].Food Science,2016,37(17):14-18.
2	赵郁聪, 靳刘萍, 陈满儒, 等.甘油对壳聚糖-淀粉复合可食性膜力学性能的影响[J].包装工程,2019,40(21):68-73.
	ZHAO Y C , JIN L P , CHEN M R , et al.Effect of glycerol on mechanical properties of chitosan-starch composite edible film[J].Packaging Engineering,2019,40(21):68-73.
3	李倩文, 杜聪.纳米二氧化硅改性聚乙烯醇/淀粉复合膜的制备及性能研究[J].食品科技,2018,43(3):74-79.
	LI Q W , DU C .Preparation and properties of nano-SiO₂ modified PVA/starch composite membrane[J].Food Science and Technology,2018,43(3):74-79.
4	DE PAOLA M G, PALETTA R, LOPRESTO C G, et al. Stability of film-forming dispersions: Affects the morphology and optical properties of polymeric films[J/OL]. Polymers, 2021, 13(9): 1464[2023-01-15]. https://doi.org/10.3390/polym13091464.
5	杨旋, 唐丽荣, 林凤采, 等.纳米纤维素/壳聚糖/明胶复合膜的制备及其性能研究[J].生物质化学工程,2018,52(1):17-22.
	YANG X , TANG L R , LIN F C , et al.Preparation and properties of nanocellulose/chitosan/gelatin composite films[J].Biomass Chemical Engineering,2018,52(1):17-22.
6	EZATI P, RIAHI Z, RHIM J. CMC-based functional film incorporated with copper-doped TiO₂ to prevent banana browning[J/OL]. Food Hydrocolloids, 2022, 122: 107104[2023-01-15]. https://doi.org/10.1016/j.foodhyd.2021.107104.
7	TARIQUE J, SAPUAN S M, KHALINA A. Effect of glycerol plasticizer loading on the physical, mechanical, thermal, and barrier properties of arrowroot(Maranta arundinacea) starch biopolymers[J/OL]. Scientific Reports, 2021, 11(1): 13900[2023-01-15]. https://doi.org/10.1038/s41598-021-93094-y.
8	贾超, 王利强, 卢立新, 等.增塑剂对马铃薯淀粉基复合膜物理机械性能的影响[J].包装工程,2012,33(13):48-52, 127.
	JIA C , WANG L Q , LU L X , et al.Effect of plasticizers on physical and mechanical properties of potato starch-based composite films[J].Packaging Engineering,2012,33(13):48-52, 127.
9	SABBAH M , DI PIERRO P , CAMMAROTA M , et al.Development and properties of new chitosan-based films plasticized with spermidine and/or glycerol[J].Food hydrocolloids,2019,87,245-252. doi: 10.1016/j.foodhyd.2018.08.008
10	LI N N, ZHOU Z G, WU F Q, et al. Development of pH-indicative and antimicrobial films based on polyvinyl alcohol/starch incorporated with ethyl lauroyl arginate and mulberry anthocyanin for active packaging[J/OL]. Coatings, 2022, 12(10): 1392[2023-01-15]. https://doi.org/10.3390/coatings12101392.
11	WU F Q , ZHOU Z G , LI N N , et al.Development of poly(vinyl alcohol)/starch/ethyl lauroyl arginate blend films with enhanced antimicrobial and physical properties for active packaging[J].International Journal of Biological Macromolecules,2021,192,389-397. doi: 10.1016/j.ijbiomac.2021.09.208
12	DEWI R, KRISMAN K, ZULKARNAIN Z, et al. Characterization of optical properties of thin film Ba_1-xSr_xTiO₃(x=0, 70;x=0, 75;and x=0, 80) using ultraviolet visible spectroscopy[C/OL]// The 8th National Physics Seminar 2019. Jakarta: AIP Publishing, 2019, 2169(1): 060002[2023-01-15]. https://doi.org/10.1063/1.5132680.
13	ABRAL H , BASRI A , MUHAMMAD F , et al.A simple method for improving the properties of the sago starch films prepared by using ultrasonication treatment[J].Food Hydrocolloids,2019,93,276-283. doi: 10.1016/j.foodhyd.2019.02.012
14	CEBALLOS R L, VON BILDERLING C, GUZ L, et al. Effect of greenly synthetized silver nanoparticles on the properties of active starch films obtained by extrusion and compression molding[J/OL]. Carbohydrate Polymers, 2021, 261: 117871[2023-01-15]. https://doi.org/10.1016/j.carbpol.2021.117871.
15	SANYANG M L , SAPUAN S M , JAWAID M , et al.Effect of plasticizer type and concentration on physical properties of biodegradable films based on sugar palm(Arenga pinnata) starch for food packaging[J].Journal of Food Science and Technology,2016,53(1):326-336. doi: 10.1007/s13197-015-2009-7
16	SUDERMAN N , ISA M I N , SARBON N M .The effect of plasticizers on the functional properties of biodegradable gelatin-based film: A review[J].Food Bioscience,2018,24,111-119. doi: 10.1016/j.fbio.2018.06.006
17	TAVARES K M, CAMPOS A D, MITSUYUKI M C, et al. Corn and cassava starch with carboxymethyl cellulose films and its mechanical and hydrophobic properties[J/OL]. Carbohydrate Polymers, 2019, 223: 115055[2023-01-15]. https://doi.org/10.1016/j.carbpol.2019.115055.
18	FARAHNAKY A , SABERI B , MAJZOOBI M .Effect of glycerol on physical and mechanical properties of wheat starch edible films[J].Journal of Texture Studies,2013,44(3):176-186. doi: 10.1111/jtxs.12007
19	LU Y S , WENG L H , ZHANG L N .Morphology and properties of soy protein isolate thermoplastics reinforced with chitin whiskers[J].Biomacromolecules,2004,5(3):1046-1051. doi: 10.1021/bm034516x
20	WILHELM H M , SIERAKOWSKI M R , SOUZA G P , et al.Starch films reinforced with mineral clay[J].Carbohydrate polymers,2003,52(2):101-110. doi: 10.1016/S0144-8617(02)00239-4
21	GHADIRI A N , SALMASI S , ALMASI H .Tomato seed mucilage as a new source of biodegradable film-forming material: Effect of glycerol and cellulose nanofibers on the characteristics of resultant films[J].Food and Bioprocess Technology,2021,14,2380-2400. doi: 10.1007/s11947-021-02734-8
22	NOSHIRVANI N , GHANBARZADEH B , MOKARRAM R R , et al.Preparation and characterization of active emulsified films based on chitosan-carboxymethyl cellulose containing zinc oxide nano particles[J].International Journal of Biological Macromolecules,2017,99,530-538. doi: 10.1016/j.ijbiomac.2017.03.007
23	QIN Y , LIU Y P , YONG H M , et al.Preparation and characterization of active and intelligent packaging films based on cassava starch and anthocyanins from Lycium ruthenicum Murr[J].International Journal of Biological Macromolecules,2019,134,80-90. doi: 10.1016/j.ijbiomac.2019.05.029
24	刘鹏飞, 孙圣麟, 王文涛, 等.增塑剂甘油对甘薯淀粉膜性能的影响研究[J].中国粮油学报,2015,30(10):15-20.
	LIU P F , SUN S L , WANG W T , et al.Effect of glycerol plasticizer on the properties of sweet potato starch-based films[J].Journal of the Chinese Cereals and Oils Association,2015,30(10):15-20.
25	左迎峰, 顾继友, 杨龙, 等.甘油用量对淀粉/聚乳酸复合材料性能的影响[J].功能材料,2014,45(5):5087-5091. doi: 10.3969/j.issn.1001-9731.2014.05.020
	ZUO Y F , GU J Y , YANG L , et al.Effect of glycerol content on the properties of starch/polylactic acid composite[J].Journal of Functional Materials,2014,45(5):5087-5091. doi: 10.3969/j.issn.1001-9731.2014.05.020
26	TAVARES K M, DE CAMPOS A, LUCHESI B R, et al. Effect of carboxymethyl cellulose concentration on mechanical and water vapor barrier properties of corn starch films[J/OL]. Carbohydrate Polymers, 2020, 246: 116521[2023-01-15]. https://doi.org/10.1016/j.carbpol.2020.116521.
27	李佳睿.增塑剂对壳聚糖-PVA共混膜性能的影响[J].内蒙古民族大学学报(自然科学版),2013,28(1):25-27.
	LI J R .Effects of plasticizer on the properties of chitosan-PVA blend films[J].Journal of Inner Mongolia University for Nationalities(Natural Sciences),2013,28(1):25-27.
28	YAN Q Q , HOU H X , GUO P , et al.Effects of extrusion and glycerol content on properties of oxidized and acetylated corn starch-based films[J].Carbohydrate Polymers,2012,87(1):707-712. doi: 10.1016/j.carbpol.2011.08.048
29	BALLESTEROS-MÁRTINEZ L , PÉREZ-CERVERA C , ANDRADE-PIZARRO R .Effect of glycerol and sorbitol concentrations on mechanical, optical, and barrier properties of sweet potato starch film[J].NFS Journal,2020,20,1-9. doi: 10.1016/j.nfs.2020.06.002
30	马璟, 李蔚然, 王丽杰, 等.柠檬汁纳米银抗菌复合膜的制备工艺优化及性能研究[J].食品工业科技,2022,43(8):31-40.
	MA J , LI W R , WANG L J , et al.Preparation process optimization and performance research of lemon juice nano silver antimicrobial composite membrane[J].Science and Technology of Food Industry,2022,43(8):31-40.
31	SURIYATEM R , AURAS R A , RACHTANAPUN P .Utilization of carboxymethyl cellulose from durian rind agricultural waste to improve physical properties and stability of rice starch-based film[J].Journal of Polymers and the Environment,2019,27(2):286-298.

甘油添加量/% glycerin addition	拉伸强度/MPa tensile strength	断裂伸长率/% elongation at break	厚度/mm thickness
0	33.74±5.24a	3.39±0.26a	0.134±0.002a
5	21.80±4.95b	5.99±0.57a	0.134±0.002a
10	20.79±2.45b	8.44±0.95a	0.142±0.003b
15	14.62±3.97bc	16.84±4.49b	0.147±0.008b
20	13.76±5.18bc	18.94±2.99b	0.138±0.016ab
25	8.20±4.11c	33.17±2.59c	0.147±0.011b
30	8.07±6.58c	46.23±3.70d	0.167±0.003c

组分 component	拉伸强度/MPa tensile strength	断裂伸长率/% elongation at break	WVP/ (g·m^-1·s^-1·Pa^-1)	参考文献 reference
CMC/壳聚糖CMC/chitosan	7.34±0.8	13.14±5.27	—	[22]
竹芋淀粉arrowroot starch	9.34	2.41	(5.94±0.4)×10^-9	[7]
CMC/木薯淀粉CMC/tapioca starch	30.40±1.4	5.10±0.3	1.70×10^-8	[17]
CMC/玉米淀粉CMC/cornstarch	5.50±0.8	60.80±4.3	(2.40±0.56)×10^-8	[26]
木薯淀粉tapioca starch	12.08±0.46	3.87±0.33	(1.54±0.14)×10^-10	[23]

甘油添加量/% glycerin addition	600 nm透光率/% light transmittance at 600 nm	不透明度 opacity	WVP(24 h)/ (g·m^-1·s^-1·Pa^-1)	吸水率/% water absorption
0	69.09	1.26	3.65×10^-11±1.48×10^-12a	12.45±0.5a
5	74.20	1.04	3.97×10^-11±1.62×10^-12b	25.40±0.1d
10	74.33	1.01	4.51×10^-11±1.43×10^-12bc	21.83±0.3b
15	75.74	0.98	4.13×10^-11±1.58×10^-12bc	23.70±1.6c
20	79.42	0.95	5.14×10^-11±1.09×10^-11c	25.46±0.3d
25	76.60	1.14	5.71×10^-11±6.47×10^-12cd	27.95±0.5e
30	74.10	0.99	7.12×10^-11±1.63×10^-11d	32.43±0.4f

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Preparation and Properties of Starch/Carboxymethyl Cellulose/Glycerol Degradable Composite Films

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