Chemistry and Industry of Forest Products ›› 2022, Vol. 42 ›› Issue (6): 55-63.doi: 10.3969/j.issn.0253-2417.2022.06.008
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Ningxin WEI, Xixin DUAN, Wenbiao XU, Junyou SHI()
Received:
2021-11-08
Online:
2022-12-28
Published:
2023-01-07
Contact:
Junyou SHI
E-mail:bhsjy64@163.com
CLC Number:
Ningxin WEI, Xixin DUAN, Wenbiao XU, Junyou SHI. Degradation of Lignin to Phenolic Compounds by Polyacid/H2O2 System[J]. Chemistry and Industry of Forest Products, 2022, 42(6): 55-63.
Table 2
Effect of H2O2 dosage on lignin degradation rate(wL), bio-oil yield(wO) and product distribution"
催化剂 catalyst | H2O2/mL | wL/% | wO/% | 香草醛/% vanillin | 香草乙酮/% acetovanill- one | 香草酸/% vanillic acid | 丁香醛/% syringal dehyde | 乙酰丁香酮/% acetosyring- one | 对羟基苯甲醛/% p-hydroxyben- zald ehyde | 对羟基苯乙酮/% p-hydroxyphen- yl ketone |
0.5 | 72.95 | 42.12 | 0.29 | 0.03 | 0.13 | 0.09 | 0.08 | 0.10 | 0.07 | |
1.0 | 81.52 | 54.60 | 0.42 | 0.08 | 0.26 | 0.17 | 0.17 | 0.22 | 0.13 | |
HPW | 1.5 | 83.45 | 47.35 | 0.26 | 0.07 | 0.29 | 0.14 | 0.16 | 0.23 | 0.08 |
2.0 | 85.50 | 35.92 | 0.25 | 0.04 | 0.32 | 0.10 | 0.15 | 0.25 | 0.10 | |
2.5 | 87.80 | 30.78 | 0.19 | 0.02 | 0.25 | 0.07 | 0.14 | 0.19 | 0.05 | |
0.5 | 69.00 | 38.68 | 0.90 | 0.03 | 0.40 | 0.50 | 0.09 | 1.00 | 0.10 | |
1.0 | 72.85 | 55.24 | 1.02 | 0.05 | 0.55 | 0.63 | 0.13 | 1.66 | 0.26 | |
PMoV2 | 1.5 | 74.34 | 57.25 | 1.30 | 0.08 | 0.30 | 0.70 | 0.15 | 1.74 | 0.34 |
2.0 | 77.45 | 60.96 | 1.45 | 0.10 | 0.20 | 0.91 | 0.19 | 1.80 | 0.39 | |
2.5 | 79.74 | 58.28 | 1.40 | 0.07 | 0.10 | 0.89 | 0.10 | 1.60 | 0.30 |
Table 3
Effect of reaction time on lignin degradation rate(wL), bio-oil yield(wO) and product distribution"
催化剂 catalyst | 时间/min time | wL/% | wO/% | 香草醛/% vanillin | 香草乙酮/% acetovanill- one | 香草酸/% vanillic acid | 丁香醛/% syringal dehyde | 乙酰丁香酮/% acetosyring- one | 对羟基苯甲醛/% p-hydroxyben- zald ehyde | 对羟基苯乙酮/% p-hydroxyphen- yl ketone |
30 | 65.00 | 44.88 | 0.34 | 0.04 | 0.09 | 0.06 | 0.09 | 0.14 | 0.07 | |
60 | 81.52 | 54.60 | 0.42 | 0.05 | 0.26 | 0.17 | 0.17 | 0.22 | 0.13 | |
HPW | 90 | 82.56 | 47.89 | 0.39 | 0.06 | 0.14 | 0.15 | 0.11 | 0.17 | 0.08 |
120 | 79.80 | 34.08 | 0.33 | 0.03 | 0.10 | 0.08 | 0.09 | 0.10 | 0.07 | |
150 | 77.40 | 28.74 | 0.22 | 0.04 | 0.03 | 0.07 | 0.07 | 0.06 | 0.04 | |
30 | 59.92 | 40.74 | 0.63 | 0.05 | 0.10 | 0.70 | 0.10 | 1.90 | 0.30 | |
60 | 77.45 | 60.96 | 1.45 | 0.10 | 0.20 | 0.91 | 0.19 | 1.80 | 0.39 | |
PMoV2 | 90 | 74.44 | 55.44 | 1.44 | 0.09 | 0.25 | 0.97 | 0.18 | 1.40 | 0.38 |
120 | 75.41 | 47.23 | 1.20 | 0.07 | 0.26 | 1.00 | 0.17 | 1.22 | 0.37 | |
150 | 63.44 | 30.76 | 1.10 | 0.06 | 0.27 | 0.95 | 0.16 | 0.90 | 0.35 |
Table 4
Effect of reaction temperature on lignin degradation rate(wL), bio-oil yield(wO) and product distribution"
催化剂 catalyst | 温度/℃ temp. | wL/% | wO/% | 香草醛/% vanillin | 香草乙酮/% acetovanill- one | 香草酸/% vanillic acid | 丁香醛/% syringal dehyde | 乙酰丁香酮/% acetosyring- one | 对羟基苯甲醛/% p-hydroxyben- zald ehyde | 对羟基苯乙酮/% p-hydroxyphen- yl ketone |
80 | 68.41 | 37.56 | 0.08 | 0.01 | 0.04 | 0.03 | 0.03 | 0.05 | 0.03 | |
100 | 72.36. | 40.38 | 0.10 | 0.03 | 0.09 | 0.05 | 0.07 | 0.09 | 0.04 | |
HPW | 120 | 74.08 | 44.64 | 0.19 | 0.06 | 0.15 | 0.09 | 0.10 | 0.11 | 0.09 |
140 | 81.52 | 54.60 | 0.42 | 0.08 | 0.26 | 0.17 | 0.17 | 0.22 | 0.13 | |
160 | 85.24 | 31.04 | 0.30 | 0.06 | 0.19 | 0.12 | 0.14 | 0.12 | 0.10 | |
80 | 52.10 | 30.78 | 0.40 | 0.03 | 0.05 | 0.30 | 0.05 | 1.00 | 0.10 | |
100 | 54.94 | 37.95 | 0.70 | 0.06 | 0.06 | 0.40 | 0.06 | 1.20 | 0.20 | |
PMoV2 | 120 | 59.35 | 45.84 | 0.90 | 0.07 | 0.10 | 0.60 | 0.07 | 1.30 | 0.23 |
140 | 77.45 | 60.96 | 1.45 | 0.10 | 0.20 | 0.91 | 0.19 | 1.80 | 0.39 | |
160 | 79.75 | 37.48 | 1.30 | 0.09 | 0.15 | 0.70 | 0.09 | 1.40 | 0.30 |
Table 5
Effect of catalyst dosage on lignin degradation rate(wL), bio-oil yield(wO) and product distribution"
催化剂 catalyst | 用量/g dasage | wL/% | wO/% | 香草醛/% vanillin | 香草乙酮/% acetovanill- one | 香草酸/% vanillic acid | 丁香醛/% syringal dehyde | 乙酰丁香酮/% acetosyring- one | 对羟基苯甲醛/% p-hydroxyben- zald ehyde | 对羟基苯乙酮/% p-hydroxyphen- yl ketone |
无催化剂without catalyst | 0 | 64.00 | 31.59 | 0.07 | 0.02 | 0.55 | 0.05 | 0.07 | 0.05 | 0.06 |
HPW | 0.125 | 80.25 | 41.52 | 0.19 | 0.06 | 0.35 | 0.09 | 0.10 | 0.18 | 0.07 |
0.250 | 81.52 | 54.60 | 0.42 | 0.08 | 0.26 | 0.17 | 0.17 | 0.22 | 0.13 | |
0.375 | 81.36 | 44.72 | 0.14 | 0.07 | 0.09 | 0.07 | 0.05 | 0.17 | 0.10 | |
0.500 | 82.56 | 34.56 | 0.13 | 0.06 | 0.17 | 0.08 | 0.07 | 0.10 | 0.09 | |
PMoV2 | 0.125 | 72.85 | 35.48 | 1.20 | 0.07 | 0.27 | 0.50 | 0.17 | 1.20 | 0.27 |
0.250 | 77.45 | 60.96 | 1.45 | 0.10 | 0.20 | 0.91 | 0.19 | 1.80 | 0.39 | |
0.375 | 75.65 | 45.39 | 1.48 | 0.08 | 0.18 | 0.83 | 0.17 | 1.60 | 0.38 | |
0.500 | 78.46 | 30.76 | 1.50 | 0.09 | 0.19 | 0.78 | 0.15 | 1.50 | 0.37 |
Table 6
Retention time and yield of the product"
保留时间/min retention time | 化合物 compound | 不同催化剂催化木质素降解后产物得率/% product yield of lignin degradation catalyzed by different catalysts | |
HPW | PMoV2 | ||
13.012 | 对羟基苯甲醛p-hydroxybenzaldehyde | 0.22 | 1.80 |
13.741 | 香草醛vanillin | 0.42 | 1.45 |
14.438 | 对羟基苯乙酮p-hydroxyphenyl ketone | 0.13 | 0.39 |
15.890 | 香草乙酮acetovanillone | 0.08 | 0.10 |
17.016 | 香草酸vanillic acid | 0.26 | 0.20 |
18.260 | 丁香醛syringaldehyde | 0.17 | 0.91 |
19.007 | 乙酰丁香酮acetosyringone | 0.17 | 0.19 |
21.963 | 对香豆酸乙酯p-coumaric acid ethyl ester | 2.90 | 3.66 |
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