N,N-二甲基脱氢枞基氧化叔胺的制备及其性能

doi:10.3969/j.issn.0253-2417.2014.01.008

Abstract

Abstract: A new dehydroabietylamine derivative, i.e., N,N-dimethyl dehydroabietylamine oxide, was synthesized from dehydroabietylamine (99 %) via alkylation and oxidation. Its structure was identified by FT-IR and ¹H NMR spectra. The oxidation conditions were optimized by the L₁₆(4⁵) orthogonal test. The results showed that suitable synthesis reaction conditions of the titled compound were as follows: N,N-dimethyl dehydroabietylamine oxide and H₂O₂ molar ratio of 1.5:1, reaction time of 12 h, EDTA of 1.5 % and reaction temperature of 80 ℃. The GC content of the tertiary amine oxide were above 70 % in repetitive experiments. The surfactivity experiment showed that the critical micelle concentration(CMC) can be as low as 0.2 g/L, and the surface tension is 22.75 mN/m. And a new type of adsorbent prepared from amine oxide-modified zeolite has better adsorption effect on a certain concentration of humic acid and Congo red. When the initial concentration of 40 mg/L reached equilibrium, the removal rates were 51.1% and 91.0 %, respectively.

Key words: dehydroabietylamine, tertiary amine oxide, surface activity, adsorption performance

CLC Number:

TQ35

DING Yu-qiu, LIU Shao-gang, LI Long, DING Yu-bo, DIAO Kai-sheng. The Synthesis of N,N-Dimethyl Dehydroabietylamine Oxide and Its Properties[J]. Chemistry and Industry of Forest Products, 2014, 34(1): 43-48.

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The Synthesis of N,N-Dimethyl Dehydroabietylamine Oxide and Its Properties

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