脱氢枞胺-壳聚糖阳离子表面活性剂的合成及性能研究

doi:10.3969/j.issn.0253-2417.2014.05.008

Abstract

Abstract: In this paper, the new chitosan derivatives, i.e., dehydroabietylamine-chitosan cationic surfactants(a, b and c), were synthesized with chitosan (1 000, 1 500, 3 000) and dehydroabietylamine as starting material. The cationic surfactants were characterized by FT-IR and ¹H NMR , respectively. The surface activities, emulsifying properties and antibacterial properties of the products were also investigated. The results showed that the critical micelle concentrations (CMC) of a, b and c are 3.98×10^-4, 2.51×10^-3 and 5.01×10^-3 mol/L at 25 ℃, respectively. The γ_cmc of a, b and c are 38.6, 36.8 and 36.6 mN/m, respectively. The emulsifying time of these three surfactants are 44, 71 and 148s, respectively. The antibacterial properties of the target products were tested with the minimum inhibitory concentration method. The preliminary result indicated that those compounds have some antibacterial activity. In particular, the antibacterial activities of the compounds a, b and c against Escherichia aerogenesare are superior to the commercially available fungicides bromogeramine and ampicillin sodium and their minimum inhibitory concentration are 2, 2 and 4 mg/L, respectively. The antibacterial activities of products would be enhanced with the increase of the D_S and would be decreased with the increase of the chitosan molecular weight.

Key words: chitosan, dehydroabietylamine, surface activity, antibacterial activity

CLC Number:

TQ35

PEI Li-jun, CAI Zhao-sheng, SHANG Shi-bin, SONG Zhan-qian. Synthesis and Performance of Dehydroabietylamine-chitosan Cationic Surfactants[J]. Chemistry and Industry of Forest Products, 2014, 34(5): 47-52.

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Synthesis and Performance of Dehydroabietylamine-chitosan Cationic Surfactants

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