Chemistry and Industry of Forest Products ›› 2021, Vol. 41 ›› Issue (6): 10-18.doi: 10.3969/j.issn.0253-2417.2021.06.002
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Kainan JIN1, Songlin ZUO1,*(), Youcai GUI1, Baoshou SHEN2,3,*(), Shanshan WANG1, Xin HU1
Received:
2021-07-14
Online:
2021-12-28
Published:
2021-12-31
Contact:
Songlin ZUO,Baoshou SHEN
E-mail:zslnl@njfu.edu.cn;bsshen@nwu.edu.cn
CLC Number:
Kainan JIN, Songlin ZUO, Youcai GUI, Baoshou SHEN, Shanshan WANG, Xin HU. Studies on Lignin-based Carbon Materials as Electrocatalysts of Fuel Cells Cathode Ⅱ: Evolution of Chemical Structure of Lignin Derived Chars[J]. Chemistry and Industry of Forest Products, 2021, 41(6): 10-18.
Table 1
The contents of functional group in lignin-based carbon calculated by XPS C1s and O1s spectra %"
样品 sample | C1s | O1s | |||||||
CⅠ | CⅡ | CⅢ | CⅣ | OⅠ | OⅡ | OⅢ | OⅣ | ||
L-300 | 55.2 | 26.1 | 13.0 | 5.7 | 6.7 | 19.8 | 51.1 | 20.4 | |
L-400 | 65.4 | 20.7 | 8.9 | 3.0 | 9.0 | 22.5 | 43.6 | 24.9 | |
L-500 | 70.8 | 18.4 | 8.5 | 2.3 | 14.3 | 21.1 | 37.6 | 27.0 | |
L-600 | 71.5 | 17.5 | 8.4 | 2.6 | 16.7 | 15.4 | 40.7 | 25.6 | |
L-700 | 73.6 | 15.7 | 8.5 | 2.2 | 18.3 | 12.5 | 47.2 | 22.0 | |
L-800 | 74.9 | 14.2 | 8.5 | 2.4 | 20.1 | 8.7 | 53.7 | 17.5 | |
L-900 | 79.7 | 12.7 | 6.9 | 0.7 | 16.8 | 5.5 | 70.9 | 6.8 | |
L-U-300 | 49.1 | 22.1 | 24.9 | 3.9 | 57.6 | 13.5 | 13.2 | 15.7 | |
L-U-400 | 63.8 | 20.1 | 12.8 | 3.3 | 30.0 | 20.4 | 25.4 | 24.2 | |
L-U-500 | 68.2 | 19.6 | 9.2 | 3.0 | 25.5 | 19.4 | 41.0 | 14.1 | |
L-U-600 | 72.4 | 16.5 | 9.5 | 1.6 | 19.2 | 10.0 | 52.1 | 18.7 | |
L-U-700 | 74.6 | 14.8 | 9.3 | 1.2 | 13.9 | 9.1 | 66.7 | 10.3 | |
L-U-800 | 76.2 | 13.7 | 9.0 | 1.1 | 11.8 | 8.6 | 69.7 | 9.9 | |
L-U-900 | 80.3 | 13.6 | 5.9 | 0.2 | 10.5 | 3.6 | 77.8 | 8.1 | |
L-M-300 | 51.9 | 24.5 | 20.8 | 2.8 | 8.0 | 16.8 | 49.6 | 25.6 | |
L-M-400 | 56.9 | 21.0 | 19.2 | 2.9 | 10.8 | 19.0 | 46.2 | 24.0 | |
L-M-500 | 56.1 | 31.3 | 7.5 | 5.1 | 16.3 | 24.1 | 41.4 | 18.2 | |
L-M-600 | 62.4 | 25.9 | 7.7 | 4.0 | 16.6 | 13.1 | 54.5 | 17.9 | |
L-M-700 | 66.7 | 22.5 | 7.6 | 3.2 | 16.2 | 10.8 | 57.3 | 16.0 | |
L-M-800 | 68.1 | 21.8 | 7.2 | 2.9 | 12.5 | 9.2 | 65.0 | 12.3 | |
L-M-900 | 75.2 | 17.3 | 5.9 | 1.6 | 10.1 | 4.4 | 78.5 | 7.0 |
Table 2
The contents of nitrogen-containing groups in lignin-based carbon obtained by XPS N1s spectra %"
样品 sample | N1s | ||||
N-6 | N-5 | N-Q | —NH2 | N-X | |
L-U-300 | 30.1 | 55.9 | 0 | 14.1 | 0 |
L-U-400 | 31.6 | 66.5 | 0 | 0 | 1.9 |
L-U-500 | 24.2 | 73.3 | 0 | 0 | 2.5 |
L-U-600 | 45.3 | 49.0 | 0 | 0 | 5.7 |
L-U-700 | 46.2 | 13.9 | 32.8 | 0 | 7.0 |
L-U-800 | 41.4 | 12.9 | 42.3 | 0 | 3.4 |
L-U-900 | 34.8 | 11.0 | 51.3 | 0 | 2.8 |
L-M-300 | 25.6 | 69.8 | 0 | 4.6 | 0 |
L-M-400 | 41.2 | 54.4 | 0 | 4.4 | 0 |
L-M-500 | 40.2 | 55.6 | 0 | 0 | 4.2 |
L-M-600 | 40.6 | 56.9 | 0 | 0 | 2.6 |
L-M-700 | 54.6 | 15.4 | 24.9 | 0 | 5.0 |
L-M-800 | 48.6 | 13.4 | 38.0 | 0 | 0 |
L-M-900 | 42.5 | 2.6 | 54.9 | 0 | 0 |
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