单宁和纳米SiO2改性大豆基胶黏剂的制备及其性能

doi:10.3969/j.issn.0253-2417.2022.01.005

Abstract

Abstract:

In order to prepare a formaldehyde-free environmentally friendly biomass-based wood adhesive, a soybean-based adhesive was developed via using tannin and nano-SiO₂ to modify the defatted soybean flour(DSF), and the performance of the modified soybean-based adhesive was analyzed. The results showed that the combination of tannin and nano-SiO₂ to modify the soybean-based adhesive(DSF-T-SiO₂) could form a stable cross-linking structure after curing. TG analysis showed that the modification with tannin and nano-SiO₂ significantly improved the thermal stability of the soybean-based adhesive. Tannin-modification could improve the dry and wet bonding properties of the soybean-based adhesives. Nano-SiO₂ was helpful to improve the dry bonding properties of the adhesive, whereas the effect on the wet bonding properties was not obviously. When the formula of the developed adhesive was 25 g defatted soybean flour, 5 g tannin, 0.1 g nano-SiO₂, and 70 g deionized water, the modified adhesive DSF-T-SiO₂-2 was obtained. The initial viscosity of DSF-T-SiO₂-2 was 79.58% lower than that of the unmodified DSF. And the water solubility of DSF-T-SiO₂-2 was(27.5±0.05)%, which was 28.4 percentage points lower than that of DSF.In addition, the plywood prepared with DSF-T-SiO₂-2 had the maximum dry and wet bonding strengths of 2.55 and 0.95 MPa, respectively, which met the requirements of the Chinese national standard GB/T 9846-2015 for interior plywood.

Key words: soybean-based adhesive, tannin, bonding properties, environmentally friendly, plywood

CLC Number:

TQ35

Erbing ZHANG, Yijing TU, Manyu YE, Zhiqiang ZHU, Nairong CHEN. Preparation and Performance of Tannin and Nano SiO₂ Modified Soy-based Adhesives[J]. Chemistry and Industry of Forest Products, 2022, 42(1): 36-42.

Figures/Tables 8

Table 1

Fig.1

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Table 2

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Table 3

Fig.5

References 28

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样品 sample	水溶解率/% water dissolution rate	透光率/% luminouseness
DSF	55.9±0.05	13.2±0.2
DSF-SiO₂-2	38.9±0.06	28.5±0.1
DSF-T	31.1±0.03	35.4±0.2
DSF-T-SiO₂-2	27.5±0.05	40.1±0.3

样品 sample	干态胶合强度/MPa dry strength	湿态胶合强度/MPa wet strength
DSF	2.09±0.05	0
DSF-T	2.21±0.07	0.72±0.04
DSF-SiO₂-1	2.22±0.09	0
DSF-SiO₂-2	2.24±0.08	0
DSF-T-SiO₂-1	2.25±0.12	0.63±0.08
DSF-T-SiO₂-2	2.55±0.03	0.95±0.05
DSF-T-SiO₂-3	2.46±0.08	0.85±0.05
DSF-T-SiO₂-4	2.14±0.11	0.84±0.09

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Preparation and Performance of Tannin and Nano SiO₂ Modified Soy-based Adhesives

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样品¹⁾ sample	脱脂豆粉/g defatted soybean flour	单宁/g tannin	纳米二氧化硅/g nano-SiO₂
DSF	30	0	0
DSF-T	25	5	0
DSF-SiO₂-1	30	0	0.05
DSF-SiO₂-2	30	0	0.10
DSF-T-SiO₂-1	27.5	2.5	0.1
DSF-T-SiO₂-2	25.0	5.0	0.1
DSF-T-SiO₂-3	22.5	7.5	0.1
DSF-T-SiO₂-4	20.0	10.0	0.1

Preparation and Performance of Tannin and Nano SiO2 Modified Soy-based Adhesives

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Preparation and Performance of Tannin and Nano SiO₂ Modified Soy-based Adhesives