戊内酯/水体系中磷钨酸铝催化葡萄糖转化制备5-HMF

doi:10.3969/j.issn.0253-2417.2022.01.004

Abstract

Abstract:

Aluminum phosphor tungstate(AlPW₁₂O₄₀) catalyst was prepared by ionexchange technique andcharacterized by FT-IR, XRD, potentiometric titration and ICP.The AlPW₁₂O₄₀ was used to catalyze the conversion of glucose to 5-hydroxymethylfurfural(5-HMF) under hydrothermal condition.The effects of reaction temperature, reaction time, amount of catalyst and volumeratio of solvent on the yield of 5-HMF were investigated.The research results showed that the yield of 5-HMF reached 19.18% at 200℃for 1.5 h with 80 mg AlPW₁₂O₄₀in the solvent system of γ-valerolactone (GVL) and water with the volumeratio of 0.10.AlPW₁₂O₄₀ had strong acidity, and Al³⁺ contributed to the isomerization of glucose into fructose.The solvent system of γ-valerolactone and water (volume ratio 0.10) inhibited the isomerization of glucose and promoted the direct dehydration of fructose.The yield of 5-HMF was enhanced via the synergistic effect of AlPW₁₂O₄₀ catalyst and solvent system.

Key words: aluminum phosphor tungstate, glucose, 5-hydroxymethylfurfural, hydrothermal, isomerization

CLC Number:

TQ35

Zhanshuo ZHANG, Yu YIN, Chunhui MA, Wei LI, Sha LUO, Shouxin LIU. Preparation of 5-Hydroxymethylfurfural from Glucose Catalyzed by Aluminum Phosphor Tungstate in Valerolactone/Water System[J]. Chemistry and Industry of Forest Products, 2022, 42(1): 29-35.

Figures/Tables 7

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References 32

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Preparation of 5-Hydroxymethylfurfural from Glucose Catalyzed by Aluminum Phosphor Tungstate in Valerolactone/Water System

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