N掺杂炭气凝胶的水热制备及其金属离子吸附性能

doi:10.3969/j.issn.0253-2417.2018.04.004

Abstract

Abstract: Nitrogen-doped carbon aerogel (NCA) was prepared via hydrothermal carbonization with microcrystalline cellulose(MCC) as precursor and ovalbumin (OVA) as dopant. Here, ovalbumin acted double roles:One was the donor of nitrogen source, the other was the structural directing agent. Morphology, pore structure, crystal structure and surface chemical properties of NCA were characterized by scanning electron microscope (SEM), nitrogen adsorption-desorptiom, X-ray diffraction(XRD), Fourier transform infrared-spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS). Pb²⁺ and Cr⁶⁺ were used as adsorption substrates to explore the adsorption properties of NCA in the aqueous phase. Adsorption equilibria and kinetic behaviour of Pb²⁺ and Cr⁶⁺ were assessed by altering parameters such as agitation time and metal ions' concentration through implementing batch experiments. The results showed that the NCA was amorphous with three-dimensional network structure; specific surface area of NCA was 134.48 m²/g; average pore diameter was 12.28 nm; total pore volume was 0.413 0 m³/g. NCA was mainly composed of element of C, N, O. C=O, -COOH and C-N functional groups were detected on the surface of NCA. N was mainly existed in the form of nitrosyl, amino, pyridine and quaternary ammonium. The adsorption process of Pb²⁺ and Cr⁶⁺ on NCA followed Langmuir model and the pseudo-second-order kinetic model better. NCA exhibited higher adsorption capacity and faster kinetics than CA. The maximum adsorption capacities of Pb²⁺ and Cr⁶⁺ on NCA at 25℃ achieved 223.98 mg/g, 35.12 mg/g, respectively and the correspondind capacities on CA were 65.78 and 16.65 mg/g.

Key words: biomass, hydrothermal, nitrogen-doped, carbon aerogel, adsorption

CLC Number:

TQ35

SUN Jiaming, E Lei, MA Chunhui, LI Wei, LIU Shouxin. Preparation and Metal Ion Adsorption Performance for Heavy Metals of Nitrogen-doped Carbon Aerogels Prepared from Cellulose via Hydrothermal Carbonization Method[J]. Chemistry and Industry of Forest Products, 2018, 38(4): 20-28.

References

[1] SITTING M. Handbook of Toxic and Hazardous Chemicals and Carcinogens[M]. 2nd ed. Marshall:Noyes,1985:229-244.
[2] HAUGEN A,HARRIS C. Asbestos Carcinogenesis:Asbestos Interactions and Epithelial Lesions in Cultured Human Tracheobronchial Tissues and Cells[M]. Berlin:Springer Berlin Heidelberg,1982:32-42.
[3] SUN X L,ZENG Q X,FENG C G. Adsorption kinetics of chromium (VI) onto an anion exchange fiber containing polyamine[J]. Acta Physico-chimica Sinica,2009,25(10):1951-1957.
[4] MAVROS P,DANⅡLIDOU A C,LAZARIDIS N K,et al. Color removal from aqueous solutions. Part I. Flotation. Environ technol[J]. Environmental Technology,1994,15(7):601-616.
[5] RENGARAH S,YEON K H,KANG S Y,et al. Studies on adsorptive removal of Co(Ⅱ),Cr(Ⅲ) and Ni(Ⅱ) by IRN77 cation-exchange resin[J]. Journal of Hazardous Materials,2002,92(2):185-98.
[6] MOBASHERPOUR I,SALAHI E,PAZOUKI M. Removal of divalent cadmium cations by means of synthetic nano crystallite hydroxyapatite[J]. Desalination,2011,266(1/2/3):142-148.
[7] BHATNAGARA,SILLANPÄÄ M. Utilization of agro-industrial and municipal waste materials as potential adsorbents for water treatment:A review[J]. Chemical Engineering Journal,2010,157(2):277-296.
[8] SHEN H,WANG Y T. Biological reduction of chromium by E. coli[J]. Journal of Environmental Engineering,1994,120(3):560-572.
[9] KURNIAWAN T A,CHAN G Y,LO W H,et al. Comparisons of low-cost adsorbents for treating wastewaters laden with heavy metals[J]. Science of the Total Environment,2006,366(2/3):409-426.
[10] FU F L,WANG Q. Removal of heavy metal ions from wastewaters:A review[J]. Journal of Environmental Management,2011,92(3):407-418.
[11] 罗学刚. 生物质基重金属吸附材料的制备与应用[M]. 北京:科学出版社,2012:26-30. LUO X G. Preparation and Application of Biomass-based Heavy Metal Adsorption Materials[M]. Beijing:Science Press,2012:26-30.
[12] WOHLGEMUTH S A,WHITE R J,WILLINGER M G,et al. A one-pot hydrothermal synthesis of sulfur and nitrogen doped carbon aerogels with enhanced electrocatalytic activity in the oxygen reduction reaction[J]. Green Chemistry,2012,14(5):1515-1523.
[13] WHITE R J,BRUN N,BUDARIN V L,et al. Always look on the "light" side of life:Sustainable carbon aerogels[J]. ChemSusChem,2014,7(3):670-689.
[14] BI H C,YIN Z Y,CAO X H,et al. Carbon fiber aerogel made from raw cotton:A novel,efficient and recyclable sorbent for oils and organic solvents[J]. Advanced Materials,2013,25(41):5916-5921.
[15] DANG Z,LIU L B,LI Y,et al. In situ and ex situ pH-responsive coatings with switchable wettability for controllable oil/water separation[J]. ACS Applied Materials & Interfaces,2016,45(8):31281-31288.
[16] BRUN N,SAKAUSHI K,YU L,et al. Hydrothermal carbon-based nanostructured hollow spheres as electrode materials for high-power lithium-sulfur batteries[J]. Physical Chemistry Chemical Physics,2013,15(16):6080-6087.
[17] 郭晓娜. 氮掺杂活性炭材料的制备及性能研究[D]. 贵阳:贵州大学硕士学位论文,2016. GUO X N. Preparation and properties of nitrogen-doped activated carbon materials[D]. Guiyang:Master Degree Thesis of Guizhou University,2016.
[18] WHITE R J,YOSHIZAWA N,ANTONIETTI M,et al. A sustainable synthesis of nitrogen-doped carbon aerogels[J]. Green Chemistry,2011,13(9):2428-2434.
[19] TRESSL R,WONDRAK G T,KRVGER R P,et al. New melanoidin-like maillard polymers from 2-deoxypentoses[J]. Journal of Agricultural & Food Chemistry,1998,46(1):104-110.
[20] BACCILE N,ANTONIRTTI M,TITIRICI M M. One-step hydrothermal synthesis of nitrogen-doped nanocarbons:Albumine directing the carbonization of glucose[J]. ChemSusChem,2010,3(2):246-253.
[21] WHITE R J,YOSHIZAWA N,ANTONIETTI M,et al. A sustainable synthesis of nitrogen-doped carbon aerogels[J]. Green Chemistry,2011,13(9):2428-2434.
[22] 袁英杰,李如燕,孙可伟,等. 柠檬酸交联纤维素气凝胶的制备及其网络结构的表征[J]. 材料导报,2016,30(14):72-75. YUAN Y J,LI R Y,SIN K W,et al. Preparation of citric acid cross-linked cellulose aerogel and characterization of its network structure[J]. Material Guide,2016,30(14):72-75.
[23] RENKEMA J M,GRUPPEN H,VAN V T. Influence of pH and ionic strength on heat-induced formation and rheological properties of soy protein gels in relation to denaturation and their protein compositions[J]. Journal of Agricultural & Food Chemistry, 2002, 50(21):6064-6071.
[24] ALATALO S M,QIU K,PREUSS K,et al. Soy protein directed hydrothermal synthesis of porous carbon aerogels for electrocatalytic oxygen reduction[J]. Carbon,2016,96:622-630.
[25] GORGULHO H F,GONALVES F,PEREIRA M F R,et al. Synthesis and characterization of nitrogen-doped carbon xerogels[J]. Carbon,2009,47(8):2032-2039.
[26] XIN X D,WEI Q,YANG J,et al. Highly efficient removal of heavy metal ions by amines-functionalized mesoporous Fe₃O₄ nanoparticles[J]. Chemical Engineering Journal,2012,184:132-140.
[27] GORGULHO H F,GON A F,PEREIRA M F R,et al. Synthesis and characterization of nitrogen-doped carbon xerogels[J]. Microporous and Mesoporous Materials,2011,138(1/2/3):149-156.
[28] 马欢欢,马叶,周建斌. 载铁改性活性炭对溶液中六价铬[Cr(Ⅵ)] 的吸附研究[J]. 科学技术与工程,2017,17(9):91-96. MA H H,MA Y,ZHOU J B. Adsorption of hexavalent chromium[Cr(VI)] in solution by activated carbon loaded with iron[J]. Science Technology and Engineering,2017,17(9):91-96.
[29] 朱小涛,毛磊,杨宝滋,等. 硫化钠改性活性炭对Pb(Ⅱ)的吸附性能研究[J]. 离子交换与吸附,2016,32(3):222-233. ZHU X T,MAO L,YANG B Z,et al. Adsorption of Pb(Ⅱ) on activated carbon modified by sodium sulfide[J]. Ion Exchange and Adsorption,2016,32(3):222-233.
[30] 刘宏燕. 椰壳基活性炭改性及其对Pb²⁺的吸附性能研究[D]. 长沙:中南大学硕士学位论文,2010. LIU H Y. Modification of coconut-based activated carbon and study of its adsorption property for Pb²⁺[D]. Changsha:Master Degree Thesis of Central South University,2010.
[31] 袁晓玲. 氮掺杂多孔炭材料的制备、表征及性能研究[D]. 吉林:吉林大学博士学位论文,2012. YUAN X L. Preparation,characterization and properties of nitrogen-doped porous carbon materials[D]. Jilin:Doctoral Dissertation of Jinlin University,2012.
[32] NAMASIVAYAM S,SALMAN K,MITTAL P K,et al. Hypervascular hepatic focal lesions:Spectrum of imaging features.[J]. Curr Probl Diagn Radiol,2007,36(3):107-123.
[33] MACÍAS C,HARO M,PARRA J B,et al. Carbon black directed synthesis of ultrahigh mesoporous carbon aerogels[J]. Carbon,2013,63:487-497.
[34] RASINES G,LAVELA P,MACÍAS C,et al. N-doped monolithic carbon aerogel electrodes with optimized features for the electrosorption of ions[J]. Carbon,2015,83:262-274.
[35] 万才超,卢芸,孙庆丰,等. 新型木质纤维素气凝胶的制备、表征及疏水吸油性能[J]. 科技导报,2014,32(4/5):79-85. WAN C C,LU Y,SUN Q F,et al. Preparation and characterization of novel lignocellulose aerogel with hydrophobicity and oil absorption properties[J]. Science Technology Review,2014,32(4/5):79-85.
[36] ZHANG X F,WANG B,YU J,et al. Three-dimensional honeycomb-like porous carbon derived from corncob for the removal of heavy metals from water by capacitive deionization[J]. RSC Advances,2018,8:1159-1167.

Preparation and Metal Ion Adsorption Performance for Heavy Metals of Nitrogen-doped Carbon Aerogels Prepared from Cellulose via Hydrothermal Carbonization Method

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